Avisos, anuncios, reclamos y publicidad en España: siglos XVIII y XIX

Este artículo analiza diversas manifestaciones publicitarias aparecidas en la prensa española de los siglos XVIII y XIX. Considerando que la publicidad moderna nace en los países primero industrializados en torno a esas fechas, esta investigación se ha planteado la hipótesis de que en España, aun con retraso, se inició un proceso similar. Para la recopilación y selección de hechos, hemos utilizado las colecciones digitalizadas de portales que recientemente ofrecen el acceso libre a sus fondos; en particular, los de la Biblioteca Nacional de España, el Archivo de Revistas Catalanas Antiguas y la Hemeroteca Municipal de Madrid.

How online applications can help to achieve integral learning

The development of transversal competencies provides an integral education. However, its practical implementation among different subjects is not a trivial task. There are several issues that should be previously solved in an optimal way to take advantage of the synergy among subjects. Main issues are: i) the need for a common space for the documents management, ii) the availability of the document everywhere and anytime, and iii) the possibility to collaborate in the documents edition tasks. It was implemented a virtual portfolio for the students which allows the assessment of all the subjects in a global way. To this goal we used the Google apps due to its free access, availability and suitability for the collaborative editing tasks.

Identificación de minerales mediante difracción de rayos X utilizando bases de datos online de libre acceso

El artículo proporciona una metodología sencilla para la identificación de minerales mediante la técnica de difracción de rayos X de polvo utilizando bases de datos mineralógicos de libre acceso y online. Las bases de datos utilizadas son la base de datos mineralógicas webmineral y la base de datos de estructuras cristalinas de la American Mineralogist Crystal Structure Database, AMS. En el presente trabajo se han elaborado 3 actividades resueltas de estudios reales y en orden creciente de dificultad. Se ha pretendido hacer hincapié en puntos donde el profesor puede interactuar con el alumno y promover la capacidad de análisis, síntesis y razonamiento crítico del alumno ante un problema de investigación en geología. Finalmente se ha elaborado un Anexo donde se recogen recomendaciones para que el profesor desarrolle sus propias actividades.

Enantioselective direct aldol reaction of α-keto esters catalyzed by (Sa)-binam-D-prolinamide under quasi solvent-free conditions

(Sa)-Binam-D-prolinamide (20 mol%), instead of (Sa)-binam-L-prolinamide, in combination with chloroacetic acid (100 mol%) is an efficient organocatalyst for the direct aldol reaction between α-keto esters as electrophiles and alkyl and α-functionalised ketones, under quasi solvent-free conditions, providing access to highly functionalised chiral quaternary γ-keto α-hydroxyesters with up to 92% ee.

Enantioselective Solvent-Free Synthesis of 3-Alkyl-3-hydroxy-2-oxoindoles Catalyzed by Binam-Prolinamides

BINAM-prolinamides are very efficient catalyst for the synthesis of non-protected and N-benzyl isatin derivatives by using an aldol reaction between ketones and isatins under solvent-free conditions. The results in terms of diastereo- and enantioselectivities are good, up to 99% de and 97% ee, and higher to those previously reported in the literature under similar reaction conditions. A high variation of the results is observed depending on the structure of the isatin and the ketone used in the process. While 90% of ee and 97% ee, respectively, is obtained by using (Ra)-BINAM-l-(bis)prolinamide as catalyst in the addition of cyclohexanone and α-methoxyacetone to free isatin, 90% ee is achieved for the reaction between N-benzyl isatin and acetone using N-tosyl BINAM-l-prolinamide as catalyst. This reaction is also carried out using a silica BINAM-l-prolinamide supported catalyst under solvent-free conditions, which can be reused up to five times giving similar results.