Red para la elaboración de materiales docentes en el análisis y tratamiento de datos geoquímicos y petrológicos

El trabajo realizado por esta red docente tiene por objetivo el desarrollo de materiales docentes específicos para el análisis y tratamiento de datos geoquímicos y petrológicos dentro de las asignaturas enmarcadas en el tercer curso del Grado en Geología: Petrología Ígnea y Metamórfica, Petrología Sedimentaria y Geoquímica y Prospección Geoquímica. El trabajo se ha centrado en la definición de las actividades a realizar por el estudiante, haciendo especial hincapié en la coordinación de los contenidos y distribución temporal entre las asignaturas anteriormente mencionadas. Los resultados obtenidos durante los cursos precedentes han mostrado la necesidad de desarrollar manuales, páginas webs y videos que permitan el autoaprendizaje del alumno. Una de las principales debilidades encontradas durante el tratamiento de datos radica en el conocimiento de los diferentes pasos intermedios que se realizan, las suposiciones que se consideran y los errores derivados de ellas. La gran parte del material y software docente existente solo proporciona el resultado final del tratamiento de los datos obtenidos en el estudio geoquímico y petrológico de las muestras naturales. Por lo tanto, el material desarrollado para solventar dichos problemas docentes incluye colecciones de problemas y prácticas, videos-tutoriales y el desarrollo de software propio o utilizando software libre.

The deterioration of Circular Mausoleum, Roman Necropolis of Carmona, Spain

The Circular Mausoleum tomb in the Roman Necropolis of Carmona was carved on a calcarenite sequence in an ancient quarry located in the town of Carmona, Southern Spain. This rock-cut tomb, representative of Roman burial practices, currently suffers from serious deterioration. A detailed survey over several years permitted the identification of the main tomb's pathologies and damaging processes, which include loss of material (scaling, flaking, granular disintegration), surface modifications (efflorescences, crusts and deposits) and extensive biological colonization. The results obtained in this study indicated that anthropogenic changes were largely responsible and enhanced the main alteration mechanisms observed in the Circular Mausoleum. Based on the deterioration diagnosis, effective corrective actions were proposed. This study shows that any conservative intervention in the interior of the tomb should be preceded by accurate in situ measurements and laboratory analyses to ascribe the source of the deterioration damages and thus designing effective treatments.

Galanet (Elche): análisis químico instrumental de los materiales de construcción

En el caso del yacimiento de Galanet sólo se han documentado 15 fragmentos de este tipo. Con estos condicionantes y a partir del análisis instrumental de tres de estos fragmentos intentaremos, dentro de los posible, responder a una serie de cuestiones que algunos autores (De Chazelles, Poupet, 1989, 10-11; Sánchez García, 1995, 350, Sánchez García, 1997, 142) han señalado como básicas para poder comprender el nivel técnico de una época o cultura y la evolución de sus técnicas constructivas, en este caso aplicadas al yacimiento de Galanet: -Determinar la procedencia del material utilizado. -Saber si la elección del material utilizado se debe a imperativos geológicos o prima en ella una decisión antrópica. -Si el material se ha usado en bruto o ha sufrido algún tratamiento previo. -Si la mayoría de las estructuras analizadas presentan una misma composición o por el contrario se utilizan diferentes composiciones en función del tipo de estructura. -Si la técnica utilizada es propia de una cronología, etapa cultural o área geográfica determinada con lo que se constituiría en un indicador cultural o por el contrario es inespecífica. -Si las soluciones técnicas empleadas son fruto del desarrollo interno de las fuerzas productivas o se deben a influencias foráneas. Es evidente que parte de estas cuestiones no se podrán contestar dado que solo contamos con unos pequeños fragmentos de material constructivo de apenas unos pocos centímetros y, sobre todo, que desconocemos cualquier detalle sobre el área de habitación del poblado de Galanet. Pero, al menos, intentaremos contribuir a conocerlo mejor.

Ultrasonic and X-ray computed tomography characterization of progressive fracture damage in low-porous carbonate rocks

This paper studies the fracturing process in low-porous rocks during uniaxial compressive tests considering the original defects and the new mechanical cracks in the material. For this purpose, five different kinds of rocks have been chosen with carbonate mineralogy and low porosity (lower than 2%). The characterization of the fracture damage is carried out using three different techniques: ultrasounds, mercury porosimetry and X-ray computed tomography. The proposed methodology allows quantifying the evolution of the porous system as well as studying the location of new cracks in the rock samples. Intercrystalline porosity (the smallest pores with pore radius < 1 μm) shows a limited development during loading, disappearing rapidly from the porosimetry curves and it is directly related to the initial plastic behaviour in the stress–strain patterns. However, the biggest pores (corresponding to the cracks) suffer a continuous enlargement until the unstable propagation of fractures. The measured crack initiation stress varies between 0.25 σp and 0.50 σp for marbles and between 0.50 σp and 0.85 σp for micrite limestone. The unstable propagation of cracks is assumed to occur very close to the peak strength. Crack propagation through the sample is completely independent of pre-existing defects (porous bands, stylolites, fractures and veins). The ultrasonic response in the time-domain is less sensitive to the fracture damage than the frequency-domain. P-wave velocity increases during loading test until the beginning of the unstable crack propagation. This increase is higher for marbles (between 15% and 30% from initial vp values) and lower for micrite limestones (between 5% and 10%). When the mechanical cracks propagate unstably, the velocity stops to increase and decreases only when rock damage is very high. Frequency analysis of the ultrasonic signals shows clear changes during the loading process. The spectrum of treated waveforms shows two main frequency peaks centred at low (~ 20 kHz) and high (~ 35 kHz) values. When new fractures appear and grow the amplitude of the high-frequency peak decreases, while that of the low-frequency peak increases. Besides, a slight frequency shift is observed towards higher frequencies.

Interpretando ambientes sedimentarios: taller de sedimentología con arenas como actividad didáctica de Ciencias de la Tierra

El proceso de aprendizaje de las Ciencias de la Tierra, en particular en las disciplinas de la sedimentología y petrología sedimentaria, requiere de la realización de actividades prácticas, tanto en el campo como en el laboratorio. En este contexto examinar mediante lupa binocular distintos tipos de arena supone, además de un placer estético, un buen punto de partida para introducir al alumnado en la interpretación de ambientes sedimentarios. En este trabajo se propone un taller de iniciación a la reconstrucción de ambientes sedimentarios mediante el análisis de sedimentos detríticos (principalmente arenas). Se presenta una guía de procedimientos en laboratorio que incluye el análisis de los siguientes parámetros: tamaño, composición y forma de los granos, selección y color. Para vertebrar la propuesta didáctica se examinan ejemplos “tipo” de sedimentos detríticos representativos de ambientes de depósito tanto fluviales como marinos y de transición (playa), todos ellos incluidos en diferentes puntos de la geografía de la provincia de Alicante (España).

Los mármoles comerciales “Marrón Imperial” y “Marrón Emperador” (S.E. España). Caracterización petrológica y criterios de exploración

Los mármoles comerciales "Marrón Imperial" y "Marrón Emperador" son dolomías brechoides que de acuerdo con la clasificación del MIA pertenece al Grupo C de mármoles comerciales. Se determinan sus parámetros petrofísicos según la norma UNE. Sus rasgos petrológicos se estudian mediante microscopio petrográfico de luz transmitida y microscopio electrónico de barrido (MEB) (en modo de electrones secundarios y electrones retrodispersados). Estas rocas son básicamente dolomías mesocristalinas con abundantes vénulas calcíticas politexturales relacionadas con procesos de brechificación y de dolomitización. Rasgos kársticos aumentan la complejidad petrológica de estas rocas ornamentales cuyo litosoma son las dolomías masivas del Cretácico Superior (¿Turoniense?) del dominio Prebético Externo. El material explotado pertenece a una alineación morfoestructural que va desde Jumilla hasta el NE de Caudete y está relacionado con la falla Jumilla-Yecla-Caudete-Font de la Figuera. La relación entre esta falla y las dolomías turonienses son el principal criterio de exploración de estas rocas ornamentales.

Colour changes by laser irradiation of reddish building limestones

We have used X-ray photoelectron spectroscopy (XPS) as a novel method to investigate the causes of colour changes in a reddish limestone under irradiation by a Q-switched Nd:YAG 1064 nm laser. We irradiated clean dry and wet surfaces of Pidramuelle Roja, a building stone frequently used in the Asturian heritage, at fluences ranging from 0.12 to 1.47 J cm−2. We measured the colour coordinates and undertook XPS analysis of the state of oxidation of iron both before and after irradiation. Visible colour changes and potential aesthetic damage occurred on dry surfaces from a fluence of 0.31 J cm−2, with the stone showing a greening effect and very intense darkening. The colour change on dry surfaces was considerably higher than on wet surfaces, which at the highest fluence (1.47 J cm−2) was also above the human visual detection threshold. The use of XPS demonstrated that the change in colour (chroma and hue) is associated with a reduction in the iron oxidation state on dry surfaces during laser irradiation. This points out to a potential routinary use of XPS to analyse causes of colour changes during laser cleaning in other types of coloured building stones.

Seguimiento del Grado en Geología (Facultad de Ciencias, UA)

La red de trabajo formada por los profesores coordinadores de semestre y de titulación del Grado en Geología (Facultad de Ciencias, Universidad de Alicante) ha tenido como objetivos principales: afianzar la implementación de las enseñanzas conforme al contenido del plan de estudios del título verificado; elaborar planes de mejora para solventar las posibles deficiencias detectadas y colaborar con los instrumentos del Sistema de Garantía Interno de Calidad (SGIC) del centro en la elaboración de los informes de autoevaluación del título. El método de trabajo se basa en reuniones en las que los miembros de la red plantearán y debatirán los parámetros e indicadores de seguimiento de la red, en la que cada investigador (coordinador) aporta una investigación individualizada del semestre del que es responsable. Ante la inminente acreditación del título el próximo curso, buena parte de las tareas se han enfocado a colaborar en los informes de auto-evaluación del título y en los planes de mejora.

Changes in the storage and sink of carbon dioxide in subsurface atmospheres controlled by climate-driven processes: the case of the Ojo Guareña karst system

A comprehensive environmental monitoring program was conducted in the Ojo Guareña cave system (Spain), one of the longest cave systems in Europe, to assess the magnitude of the spatiotemporal changes in carbon dioxide gas (CO2) in the cave–soil–atmosphere profile. The key climate-driven processes involved in gas exchange, primarily gas diffusion and cave ventilation due to advective forces, were characterized. The spatial distributions of both processes were described through measurements of CO2 and its carbon isotopic signal (δ13C[CO2]) from exterior, soil and cave air samples analyzed by cavity ring-down spectroscopy (CRDS). The trigger mechanisms of air advection (temperature or air density differences or barometric imbalances) were controlled by continuous logging systems. Radon monitoring was also used to characterize the changing airflow that results in a predictable seasonal or daily pattern of CO2 concentrations and its carbon isotopic signal. Large daily oscillations of CO2 levels, ranging from 680 to 1900 ppm day−1 on average, were registered during the daily oscillations of the exterior air temperature around the cave air temperature. These daily variations in CO2 concentration were unobservable once the outside air temperature was continuously below the cave temperature and a prevailing advective-renewal of cave air was established, such that the daily-averaged concentrations of CO2 reached minimum values close to atmospheric background. The daily pulses of CO2 and other tracer gases such as radon (222Rn) were smoothed in the inner cave locations, where fluctuation of both gases was primarily correlated with medium-term changes in air pressure. A pooled analysis of these data provided evidence that atmospheric air that is inhaled into dynamically ventilated caves can then return to the lower troposphere as CO2-rich cave air.

Infrared thermography monitoring of the NaCl crystallisation process

In this work, we describe the growth of NaCl crystals by evaporating droplets of aqueous solution while monitoring them with infrared thermography. Over the course of the evaporation experiments, variations in the recorded signal were observed and interpreted as being the result of evaporation and crystallisation. In particular, we observed sharp and transient decreases in the thermosignal during the later stages of high-concentration drop evaporation. The number of such events per experiment, referred to as “pop-cold events”, varied from 1 to over 100 and had durations from 1 to 15 s. These events are interpreted as a consequence from the top-supplied creeping (TSC) of the solution feeding the growth of efflorescence-like crystals. This phenomenon occurred when the solution was no longer macroscopically visible. In this case, efflorescence-like crystals with a spherulite shape grew around previously formed cubic crystals. Other crystal morphologies were also observed but were likely fed by mass diffusion or bottom-supplied creeping (BSC) and were not associated with “pop-cold events”; these morphologies included the cubic crystals at the centre, ring-shaped at the edge of droplets and fan-shaped crystals. After complete evaporation, an analysis of the numbers and sizes of the different types of crystals was performed using image processing. Clear differences in their sizes and distribution were observed in relation to the salt concentration. Infrared thermography permitted a level of quantification that previously was only possible using other techniques. As example, the intermittent efflorescence growth process was clearly observed and measured for the first time using infrared thermography.

El Estribo Volcanic Complex: Evolution from a shield volcano to a cinder cone, Pátzcuaro Lake, Michoacán, México

El Estribo Volcanic Complex (EVC) is located in the northern part of the Michoacán–Guanajuato Volcanic Field within the Trans-Mexican Volcanic Belt (TMVB). El Estribo is located at the southern edge of the E-W Pátzcuaro fault that belongs to the Pátzcuaro-Jarácuaro graben, a western extension of the E-W Morelia–Acambay fault system. Stratigraphy, geochronology, chemistry, and mineral assemblages suggest that the volcanic complex was constructed in two periods separated by a ~ 100 ka volcanic hiatus: a) emission of lava flows that constructed a shield volcano between 126 ka, and b) mixed phreatomagmatic to Strombolian activity that formed a cinder cone ~ 28 ka. The magmas that fed these monogenetic volcanoes were able to use the same feeding system. The cinder cone itself was constructed by Strombolian fallouts and remobilized scoria beds, followed by an erosion period, and by a mixed phreatomagmatic to magmatic phase (Strombolian fallouts ending with lava flows). Soft-sedimentary deformation of beds and impact sags, cross-bedding, as well as pitting and hydrothermal cracks found in particles support the phreatomagmatic phase. The erupted magmas through time ejected basaltic andesitic lava flows (56.21–58.88% SiO2) that built the shield volcano and then basaltic andesitic scoria (57.65–59.05% SiO2) that constructed the cinder cone. Although they used the same feeding system, the geochemical data and the mineral chemistry of the magmas indicate that the shield volcano and the cinder cone were fed by different magma batches erupted thousands of years apart. Therefore, the location of El Estribo Volcanic Complex along an E-W fault that has generated two sector collapses of the shield volcano to the north may be directly linked to this complex redistribution of the magmatic paths to the surface. Our findings show that magmatic feeding systems within monogenetic volcanic fields could be long lived, questioning the classic view of the monogenetic nature of their volcanoes and yielding information about the potential volcanic risk of these settings, usually considered risk-free.

Evolution of surface properties of ornamental granitoids exposed to high temperatures

Granite submitted to high temperatures may lead to the loss of aesthetic values even before structural damage is caused. Thirteen granitoids were exposed to target temperatures, 200 °C, 400 °C, 600 °C, 800 °C and 1000 °C. Damage characterisation, including roughness, colour and oxidation of chromogen elements by means of X-ray photoelectron spectroscopy (XPS) was assessed. Altered granitoids are more resistant to structural failure but redden rapidly. Black mica-rich granitoids turn into yellow with a maximum at 800 °C. Alkali feldspar-rich granitoids redden progressively due to iron oxidation. Roughness varies progressively in mica-rich granitoids, while in mica-poor granitoids, an increase in roughness precedes catastrophic failure.

Thermodynamic calculations for the salt crystallisation damage in porous built heritage using PHREEQC

This work considers the crystallisation mechanisms of the most common and aggressive salts that generate stress in porous building stones as a result of changing ambient conditions. These mechanisms include the salt crystallisation that result from decreasing relative humidity and changes in temperature and, in hydrated salts, the dissolution of the lower hydrated form and the subsequent precipitation of the hydrated salt. We propose a new methodology for thermodynamic calculations using PHREEQC that includes these crystallisation mechanisms. This approach permits the calculation of the equilibrium relative humidity and the parameterization of the critical relative humidity and crystallisation pressures for the dissolution–precipitation transitions. The influence of other salts on the effectives of salt crystallisation and chemical weathering is also assessed. We review the sodium and magnesium sulphate and sodium chloride systems, in both single and multicomponent solutions, and they are compared to the sodium carbonate and calcium carbonate systems. The variation of crystallisation pressure, the formation of new minerals and the chemical dissolution by the presence of other salts is also evaluated. Results for hydrated salt systems show that high crystallisation pressures are possible as lower hydrated salts dissolve and more hydrated salts precipitate. High stresses may be also produced by decreasing temperature, although it requires that porous materials are wet for long periods of time. The presence of other salts changes the temperature and relative humidity of salt transitions that generates stress rather than reducing the pressure of crystallisation, if any salt has previously precipitated. Several practical conclusions derive from proposed methodology and provide conservators and architects with information on the potential weathering activity of soluble salts. Furthermore, the model calculations might be coupled with projections of future climate to give as improved understanding of the likely changes in the frequency of phase transitions in salts within porous stone.

The influence of rock fabric in the durability of two sandstones used in the Andalusian Architectural Heritage (Montoro and Ronda, Spain)

Natural stone has been a popular and reliable building material throughout history appearing in many historic monuments and in more recent buildings. Research into the intrinsic properties of specific stones is important because it gives us a greater understanding of the factors that limit and act on them. This can help prevent serious problems from occurring in our buildings bringing both esthetic benefits and financial savings. To this end, the main objective of this research has been to study the influence of the fabric and the mineral composition of two types of sandstone on their durability. The first is a red continental sandstone from the Buntsandstein Age called “Molinaza Roja”, which is quarried in Montoro (Cordoba). The second is quarried in Ronda (Malaga) and is sold under the trade name of “Arenisca Ronda”. It is a light pink-whitish calcarenite deposited during the Late Tortonian to Late Messinian. We characterized their petrological and petrophysical properties by studying their rock fabrics, porous systems and mechanical properties. In order to obtain a complete vision of the behavior of their rock fabrics, we also carried out two decay tests, the salt crystallization and the freeze–thaw tests. We then measured the effects on the textures of the altered samples during and after the decay tests and we evaluated the changes in the porous system. By comparing the results between intact and altered samples, we found that Arenisca Ronda is less durable because it has a high quantity of expandable clays (smectites) and a high percentage of pores in the 0.1–1 μm range, in which the pressure produced by salt crystallization is strongest. In Molinaza Roja the decay agents caused significant sanding due to loss of cohesion between the clasts, especially during the salt crystallization test. In both stones, the anisotropies (oriented textures) have an important role in their hydric and dynamic behavior and also affect their mechanical properties (especially in the compression resistance). No changes in color were detected.

Predicting water permeability in sedimentary rocks from capillary imbibition and pore structure

In this paper, absolute water permeability is estimated from capillary imbibition and pore structure for 15 sedimentary rock types. They present a wide range of petrographic characteristics that provide degrees of connectivity, porosities, pore size distributions, water absorption coefficients by capillarity and water permeabilities. A statistical analysis shows strong correlations among the petrophysical parameters of the studied rocks. Several fundamental properties are fitted into different linear and multiple expressions where water permeability is expressed as a generalized function of the properties. Some practical aspects of these correlations are highlighted in order to use capillary imbibition tests to estimate permeability. The permeability–porosity relation is discussed in the context of the influence of pore connectivity and wettability. As a consequence, we propose a generalized model for permeability that includes information about water fluid rate (water absorption coefficient by capillarity), water properties (density and viscosity), wetting (interfacial tension and contact angle) and pore structure (pore radius and porosity). Its application is examined in terms of the type of pores that contribute to water transport and wettability. The results indicate that the threshold pore radius, in which water percolates through rock, achieves the best description of the pore system. The proposed equation is compared against Carman–Kozeny's and Katz–Thompson's equations. The proposed equation achieves very accurate predictions of the water permeability in the range of 0.01 to 1000 mD.