Forward-Running Detonation Drivers for High-Enthalpy Shock Tunnels

To improve the quality of driving flows generated with detonation-driven shock tunnels operated in the forward-running mode, various detonation drivers with specially designed sections were examined. Four configurations of the specially designed section, three with different converging angles and one with a cavity ring, were simulated by solving the Euler equations implemented with a pseudo kinetic reaction model. From the first three cases, it is observed that the reflection of detonation fronts at the converging wall results in an upstream-traveling shock wave that can increase the flow pressure that has decreased due to expansion waves, which leads to improvement of the driving flow. The configuration with a cavity ring is found to be more promising because the upstream-traveling shock wave appears stronger and the detonation front is less overdriven. Although pressure fluctuations due to shock wave focusing and shock wave reflection are observable in these detonation-drivers, they attenuate very rapidly to an acceptable level as the detonation wave propagates downstream. Based on the numerical observations, a new detonation-driven shock tunnel with a cavity ring is designed and installed for experimental investigation. Experimental results confirm the conclusion drawn from numerical simulations. The generated driving flow in this shock tunnel could maintain uniformity for as long as 4 ms. Feasibility of the proposed detonation driver for high-enthalpy shock tunnels is well demonstrated.

正向爆轰驱动高焓激波风洞的数值模拟

对充满氢氧可燃气体、带扩容腔的正向爆轰驱动的激波风洞进行了数值模拟.计算采用了欧拉方程,频散可控耗散差分格式(DCD)和改进的二阶段化学反应模型.在扩容腔附近采用二维轴对称计算模型,而在驱动段和被驱动段的直管道部分则采用一维计算模型.本文分析了爆轰波在管道中的传播、反射和绕射过程.计算结果表明扩容腔的尺寸对爆轰波的传播、反射、汇聚等起着决定性的作用;带扩容腔的正向爆轰驱动的激波风洞能够得到平稳的持续时间较长的气流,提高了实验的精确度和可重复性.

脉冲风洞中新型自由天平探索

为解决常规天平在高焓高超声速脉冲风洞中测得信号无法识别，无法提取的问题，提出了一种全新的自由型天平，并设计了两种不同方案（分自由度自由型三分力天平和整体自由型三分力天平），实验表明这种加速度测力是可行的，并能很好地解决传统天平遇到的问题。

水中悬浮隧道研究进展

介绍了各国关于水中悬浮隧道的研究进展,主要包括：波浪和水流作用下水中悬浮隧道与流体相互作用的理论分析模型,波浪环境下水中悬浮隧道的锚固系统的涡激振动数值分析,地震激励下水中悬浮隧道的动力响应分析,水中悬浮隧道的结构问题,针对实际工程背景的波浪环境载荷下的模型试验及水流环境中水中悬浮隧道阻力系数、惯性力系数的试验研究。最后讨论了水中悬浮隧道尚需要进一步研究的问题：荷载的确定,结构分析和设计方法,针对性的模型试验,安全性研究等。

辛体系下曲线形水中悬浮隧道对波浪激励的动力响应研究

在哈密顿体系下建立曲线形水中悬浮隧道的运动方程,即哈密顿正则方程.用哈密顿混合能变分原理处理曲线形水中悬浮隧道的两端边界条件以及径向布设的张力腿弹性支承,建立满足边界条件的线性方程组,采用分离变量法和本征向量展开法求解哈密顿正则方程.为曲线形水中悬浮隧道的动力响应分析提供一类方法.最后结合案例,运用辛方法分析波浪作用下曲线形水中悬浮隧道的弯矩和扭矩,结果表明,可以忽略扭矩对弯矩的影响.

Direct initiation of detonation with ignition tube

Experiments of direct initiation of hydrogen-oxygen by means of a hot turbulent jet were made. Results indicate that the length of ignition tube is the dominant factor in determining the ignition capability of hot turbulent jet, and that the ignition capability of turbulence jet increases with the length of ignition tube. Because this ignition capability can meet the demands of a gas-detonation-driver shock tunnel and it doesn't require additional facilities, the hot turbulent jet initiation method can be applied to large hydrogen-oxygen detonation-driver shock tunnels. Influences of obstacles on the ignition capability were also studied. It was found that the presence of obstacles weakens the ignition capability of a hot turbulent jet.

Research progress on high-enthalpy and hypersonic flows

The research progress on high-enthalpy and hypersorlic flows having been achieved in the Institute of Mechanics, Chinese Academy of Sciences, is reported in this paper. The paper consists of three main parts: The first part is on the techniques to develop advanced hypersonic test facilities, in which the detonation-driven shock-reflected tunnel and the detonation-driven shock-expanded tube are introduced. The shock tunnel can be used for generating hypersonic flows of a Mach number ranging from 10 to 20, and the expansion tube is applicable to simulate the flows with a speed of 7 similar to 10km/s. The second part is dedicated to the shock tunnel nozzle flow diagnosis to examine properties of the hypersonic flows thus created. The third part is on experiments and numerical simulations. The experiments include measuring the aerodynamic pitching moment and heat transfer in hypersonic flows, and the numerical work reports nozzle flow simulations and flow non-equilibrium effects on the possible experiments that may be carried out on the above-mentioned hypersonic test facilities.

高超声速激波风洞研究进展

回顾了高超声速激波风洞的研制与发展,并依据高超声速实验研究对地面实验模拟技术的要求,分别介绍了应用轻气体、自由活塞和爆轰驱动技术研制的主要激波风洞的性能、特点和存在问题.重点介绍了爆轰驱动高焓激波风洞的3种主要运行模武:反向、正向爆轰驱动与双爆轰驱动.根据这些运行模式的工作原理,分析了应用这些驱动技术产生的高温、高压气源的特点,探讨了不同驱动技术可能影响激波风洞性能的关键问题与解决方法.目前发展的激波风洞已经能够用于开展马赫数3～30的高超声速流动的试验模拟研究,但是试验气流的品质还不能满足高超声速科技研究的需求.为了获得可靠的实验结果,通过不断改进、完善、提高激波风涧的性能,尽可能复现高超声速飞行条件是今后主要的研究方向.

Correlations between antibunching and blinking of photoluminescence from a single CdSe quantum dot

The antibunching and blinking from a single CdSe/ZnS nanocrystal with an emission wavelength of 655 nm were investigated under different excitation powers. The decay process of the photoluminescence from nanocrystal was fitted into a stretched exponential, and the small lifetime and the small stretching exponent under a high excitation power were explained by using nonradiative multi-channel model. The probability of distributions for off-times from photoluminescence intermittence was fitted into the power law, and the power exponents were explained by using a tunneling model. For higher excitation power, the Auger-assisted tunneling model takes effect, where the tunneling rate increases and the observed lifetime decreases. For weak excitation power, the electron directly tunnels between the nanocrystal and trapping state without Auger assistance. The correlation between antibunching and blinking from the same nanocrystal was analyzed.

The direct electrochemistry behavior of Cyt c on the modified glassy carbon electrode by SBA-15 with a high-redox potential

It is discovered that SBA-15 (santa barbara amorphous) can provide the favorable microenvironments and optimal direct electron-transfer tunnels (DETT) of immobilizing cytochrome c (Cyt c) by the preferred orientation on it. A high-redox potential (254 mV vs. Ag/AgCl) was obtained on glassy carbon (GC) electrode modified by immobilizing Cyt c on rod-like SBA-15. With ultraviolet-visible (UV-vis), circular dichroism (CD), FTIR and cyclic voltammetry, it was demonstrated that immobilization made Cyt c exhibits stable and ideal electrochemical characteristics while the biological activity of immobilized Cyt c is retained as usual.

A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na-2[{Mn(phen)(2)(H2O)}{Mn(phen)(2)}(3){Mn (Mo12O24)-O-V (HPO4)(6)(PO4)(2)(OH)(6)}] center dot 4H(2)O (phen=1,10-phenanthroline)

An organic-inorganic hybrid molybdenum phosphate, Na-2[{Mn(phen)(2)(H2O)} {Mn(phen)(2)}(3){(MnMo12O24)-O-v (HPO4)(6)(PO4)(2) (OH)(6)}] . 4H(2)O (phen=1,10-phenanthroline), involving molybdenum present in V oxidation state and covalently bonded transition metal coordination complexes, has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Deep brown-red crystals are formed in the triclinic system, space group P (1) over bar, a=16.581(l)Angstrom, b=18.354(1)Angstrom, c=24.485(2)Angstrom, alpha=80.589(l)degrees, beta=71.279(1)degrees, gamma=67.084(1)degrees, V=6493.8(8)Angstrom(3), Z=2, lambda(MoKalpha)=0.71073Angstrom (R(F)=0.0686 for 29,053 reflections). Data were collected on a Bruker Smart Apex CCD diffractometer at 293 K in the range of 1.76 < theta < 28.06degrees using omega-2theta scans technique. The structure of the title compound may be considered to be based on {Mo6O12(HPO4)(3)(PO4)(OH)(3)} units bonded together with {Mn(phen)(2)} subunits into a two-dimensional network. Two types of tunnels are observed in the solid of the title compound.

A chromic molybdenum phosphate with a tunnel structure: hydrothermal synthesis and structure of (NH3CH2CH2NH3)(2) center dot (NH3CH2CH2NH2)(3)center dot[NaCr2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 6H(2)O

A chromic molybdenum phosphate, (NH3CH2CH2NH3)(2).(NH3CH2CH2NH2)(3).[NaCr2Mo12O30(PO4)(HPO4)(3)]. 6H(2)O, involving molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction and IR spectrum. Deep brown-red crystals are formed in the triclinic system, space group P (1) over bar, a = 12.067(2), b = 14.677(3), c = 21.290(2) Angstrom, alpha = 80.940(10)degrees, beta = 82.960(10)degrees, gamma = 76.61(2)degrees. The structure of the title compound may be considered to be two [Mo6O15(HPO4)(H2PO4)(3)](5-) units bonded to a chromic atom, although several P-O groups are not protonated on account of coordination with a Na+ cation. The one-dimensional tunnels were formed in the solid of the title compound. (C) 2000 Elsevier Science B.V. All rights reserved.

A manganese molybdenum phosphate with a tunnel: hydrothermal synthesis, structure and catalytic properties of (NH3CH2CH2NH3)(10-)H3O)(3)(H5O2)Na-2[MnMo12O24(OH)(6)(PO4)(4)(PO3OH)(4)]-[MnMo12O24(OH)(6)(PO4)(6)(PO3OH)(2)] center dot 9H(2)O

A manganese molybdenum phosphate, (NH3CH2CH2NH3)(10)(H3O)(3)(H5O)Na-2[MnMo12O24(OH)(6) (PO4)(4)(PO3OH)(4)][MnMo12O24 (OH)(6)(PO4)(6)(PO3OH)(2)]. 9H(2)O, has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. The structure of this compound may be considered to be two [Mo6O12(OH)(3)(PO4)(2)(HPO4)(2)](7-) units bonded together by a manganese atom, although several P-O groups are not protonated on account of coordination to a Na+ cation. One-dimensional tunnels were formed in the solid. A probe reaction of the oxidation of acetaldehyde with H2O2 using this compound as catalyst was carried out in a liquid-solid system, showing that the manganese molybdenum phosphate has high catalytic activity in the reaction.

A nickel molybdenum phosphate with tunnel: Hydrothermal synthesis and structure of (NH3CH2CH2NH3)(4)center dot(NH3CH2CH2NH2)center dot Na center dot[Ni2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 6H(2)O

A nickel molybdenum phosphate, (NH3CH2CH2NH3)(4).(NH3CH2CH2NH2). Na .[Ni2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]. 6H(2)O, invoicing molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Deep brown-red crystals are formed in the triclinic system, space group P (1) over bar, a = 12,011(2), b = 14,612(3), c = 21.252(4) Angstrom, alpha = 80.54(2)degrees, beta = 83.10(2)degrees, gamma = 76.29(2)degrees, V = 3561.4(12) Angstrom(3), Z = 2, lambda(MoK alpha) = 0.71073 Angstrom (R(F) = 0.0529 for 9880 reflections), Data mere collected on a Siemens P4 diffractometer at 20 degrees C in the range of 1.75 degrees < theta < 23.02 degrees using the omega-scan technique. The structure was solved by direct methods using the program SHELXTL-93 and refined with the method of fun-matrix least-squares on F-2. The structure of the title compound may be considered to be two [Mo6O15(HPO4)(H2PO4)(3)](5-) units bonded together with a nickel atom, although several P-O groups are not protonated on account of coordination with a Na+ cation, The one-dimensional tunnels were formed in the solid of the title compound. A probe reaction of the oxidation of acetaldehyde with H2O2 using the title compound as catalyst was carried out in a liquid- solid system, showing that the title compound had high catalytic activity in the reaction, (C) 1999 Academic Press.

金川矿山岩体移动规律及竖井变形、破坏机理研究

The Jinchuan Nickel Mine is the largest underground mine with cut-and-fill mining in China. It is very difficult to be exploited for very low safety stability of rock mass caused by complex geological conditions, developed faults, cracked rock mass and high stress. In this paper, the laws of rock mass movement、mechanics of shaft deformation and destroy were analyzed based on the collection of date, the detailed field engineering investigations, ground movement monitoring by GPS, theoretical analysis and numerical simulation. According to the GPS monitoring result of ground surface movement, there are different ground movement characteristics among the three Mine area of Jinchuan Nickel Mine. In No. 2 Mine area, the ground movement funnel with apparent asymmetry is developing, the influence scope is larger in the up faulted block than in the down faulted block, and the centre of ground movement is moving along the up faulted block direction with increasing depth of mining. Moreover, the tunnels in the corresponding area with the centre of ground movement are damaged seriously. In Longshou Mine area, the ground movement funnel is also developing, but the moving path and the nonlinear characters are more sophisticated because of the long-term effects of open excavating and the effects of underground mining together. In No. 3 Mine area, the underground mining impact on surface is not serious for the time of mining activity is not for long, but the ground movement funnel is also forming now. The underground mining has caused widespread land subsidence in Jinchuan Nickel Mine area, but the phenomena of surface raise appeared in some partial areas of Longshou Mine area and No. 3 Mine area. Analysis proved that the reason for the open pit bottom raise is the slope deformation activation caused by the excavation from open pit into underground mine; and that the raise of surface in No.3 Mine area is caused by the effect of elastic foundation due to underground mining. Although the GPS Monitoring results show the amount of subsidence is increasing constantly, the subsidence rate has a descending tendency with fluctuation in Jinchuan No. 2 Mine area. The subsidence rate curve is a time function and exists an extreme point, the rate increasing before extreme point and decreasing after the extreme point ,but the scale of decreasing rate will be very small after the rate decreasing up to a certain degree, moreover, the characteristics is different among different areas, which have some relation with the distance to the mining section and the dip of the ore body. ArcView is GIS software, which we adopted as a development platform, and made secondary development by its development language “avenue”, through which we developed a ground movement analysis and forecast System for Jinchuan Nickel Mine, which contain three modules : management of ground movement information; analysis and evaluation of ground movement; and ground movement forecast. In the module of evaluation, using the technique of MATLAB6.5 program with VB6.0, the system can achieve the ANN prediction model for GPS monitoring data, data preparation results analysis and model integrated was realized by Avenue programming. Finally, the author analyzed the mechanical of deformation and destroy of the No. 14 shaft, and its repair and artificial-support effectiveness also given detailed demonstration in various aspect. The result showed that the reason for the destroy of No. 14 shaft is underground mining, and being the case, the destroy of the shaft also has its special features, which mainly contains forked stress contour for mining steep ore and fault effect caused by mining activities. The repair and artificial-support played some restrictions on the rock mass movement and deformation, but did not show a strong or marked effect. With the increasing of mining depth and large-scale, the closure rock of the shaft will still deformed, even be destroyed.