178 resultados para 03271246 TM-17


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We present a generation condition for realizing high-Q TM whispering-gallery modes (WGMs) in semiconductor microcylinders. For microcylinders with symmetry or weak asymmetry vertical waveguiding, we show that TM WGMs can have a high Q factor, with the magnitude of 10(4) at the radius of the microcylinder of 1 mu m, by three-dimensional numerical simulation. The Q factor of TE WGMs is much less than that of TM WGMs in the semiconductor microcylinders due to a vertical radiation loss caused by mode coupling with the vertical propagating mode. The results open up a possible application of TM WGMs in semiconductor microcylinders for efficient current injection microlasers and single photon sources.

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This paper reports that lnAs/In0.53Ga0.47As/AlAs resonant tunnelling diodes have been grown on InP substrates by molecular beam epitaxy. Peak to valley current ratio of these devices is 17 at 300K. A peak current density of 3kA/cm(2) has been obtained for diodes with AlAs barriers of ten monolayers, and an In0.53Ga0.47As well of eight monolayers with four monolayers of InAs insert layer. The effects of growth interruption for smoothing potential barrier interfaces have been investigated by high resolution transmission electron microscope.

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Glass spherical microcavities containing CdSSe semiconductor quantum dots (QDs) of a few microns in diameter are fabricated using a physical method. When a single glass microspherical cavity is excited by a laser beam at room temperature, very strong and sharp whispering gallery modes are shown on the background of PL spectra of CdSSe QDs, which confirms that coupling between the optical emission of embedded QDs and spherical cavity modes is realized. For a glass microsphere only 4.6 mum in diameter, it was found that the energy separation is nearly up to 26 nm both for TE and TM modes. With the increasing excitation intensity, the excitation intensity dependence of the emission intensity is not linear in the double-logarithmic scale. Above the threshold value, the linewidths of resonance modes become narrower. The lasing behavior is achieved at relatively low excitation intensity at room temperature. High optical stability and low threshold value make this optical system promising in visible microlaser applications. (C) 2002 Elsevier Science B.V. All rights reserved.

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Polarization-independent laterally-coupled micro-ring resonator has been designed and demonstrated. The origin of the polarization-sensitivity of the photonic wire waveguide (PWW) was analyzed. A polarization-insensitive PWW structure was designed and a polarization-insensitive MRR based on this PWW structure was designed by finite difference time-domain method and was fabricated on an 8-inch silicon-on-insulator wafer. The offset between the resonant wavelengths of the quasi-TE mode and the quasi-TM mode is smaller than 0.15 nm. The FSR is about 17 nm, extinction ratio about 10 dB and Q about 620.

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We have investigated the mode characteristics for three-dimensional (3D) semiconductor microresonators by finite-difference time-domain (FDTD) technique. The results show that the quality-factors (Q-factors) of TM-like modes are much larger than those of TE-like modes as the vertical waveguidng formed by semiconductor materials.

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Radiant heat conversion performance dominated by the active layer of Ga0.84In0.16As0.14Sb0.86 diode has been systematically investigated based on an analytic absorption spectrum, which is suggested here by numerically fitting the limited experimental data. For the concerned diode configuration, our calculation demonstrates that the optimal base doping is 3-4 x 10(17) cm(-3), which is less sensitive to the variation of the external radiation spectrum. Given the scarcity of the alloy elements, an economical device configuration of the 0.2-0.6 mu m emitter and the 4-6 mu m base would be particularly acceptable because the corresponding conversion efficiency cannot exhibit discouraging degradation in comparison to the one for the optimal structure, the thickness of which may be up to 10 mu m. More importantly, the method we suggested here to calculate alloy absorption can be easily transferred to other composition, thus bringing great convenience for design or optimization of the optoelectronic device formed by these alloys.

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It is predicted that large and opposite generalized Goos-Hanchen (GGH) shifts may occur simultaneously for TE and TM light beams upon reflection from an asymmetric double-prism configuration when the angle of incidence is below but near the critical angle for total reflection, which may lead to interesting applications in optical devices and integrated optics. Numerical simulations show that the magnitude of the GGH shift can be of the order of beam's width.

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对于稀土与非稀土所组成的二元复合氧化物的研究国外已有较多的报导。但是,对于稀土和锑的复合氧化物只是近年来才开始有些研究工作。含锑与稀土的多元复合氧化物的报导就更少。本文在我们实验室张静筠等人三元复合氧化物研究的基础上,开展Mo—Sb_2O_5—R_2O_3—R'_2O_3—Bi_2O_3多元体系的研究工作,这对于我国丰产元素稀土和锑的应用以及利用Bi~(3+)的激活与敏化将是有益的。本文按Thornton等人的方法合成了Ba_2BiSbO_6,Ba_2GdSbO_6,按EγΦECEHKO等人的方法合成了M_2RSbO_6 (M = Ba、Sr、Ca, R = La Y)。并以M_2RSbO_6为基质,掺Sm~(3+)、Eu~(3+)、Dy~(3+)、Ho~(3+)、Er~(3+)、Tm~(3+)和Bi~(3+),研究它们的化学组成,晶体结构与发光性能的关系及规律,Bi~(3+)的荧光和敏作用。同时研究了它们的磁学和热学性能。化学组成的分析结果表明,计算的含量与实验测得的含量符合较好,说明化学反应是按化学计量比进行的。通过X-射线粉沫物相分析和晶胞参数的理论计算确定M_2RSbO_6(M = Ba、Sr、R = La、Y、Gd、Bi)复合氧化物是属于立方钙钛太型化合物。空间群为Fm3m,点群为Oh。用计算机计算了Ca_2YSbO_6的晶胞参数并结合荧光光谱分析确定它属于畸变的单斜钙钛矿,空间群为P_(21)。用磁天平测量了样品M_2RSbO_6 (M = Ba、Sr、Ca; R = Gd、Y、Bi)的磁化率。除Ba_2GdSbO_6是顺磁性物质外共余的都是反磁性的物质。按所用原料Sb_2O_5计算的磁化率与测量值符合较好,表明在所研究的M_2RSbO_6化合物中锑是正五价的。用热重热差分析仪测量了样品在反应中的热性能,观察到在化合物形成的过程中所用原料Sb_2O_3大约在520 ℃左右氧化变为Sb_2O_5。除所用原料碳酸盐分解外没有挥发性的物质,这就进一步证明化学组成分析和磁化率测量的结果是正确的。光学测量的结果表明,所有的磷光体随着激活离子浓度的不同其光谱都发生规律性的变化。对于不同Eu~(3+)浓度的Ba_2YSbO_6:Eu~(3+)和Br_2YSbO_6:Eu~(3+), Bi~(3+)体系用254nm激发时均能观察到Eu~(3+)于595nm的尖峰发射。用基质和Bi~(3+)的激发峰325nm激发时,明显地看到敏化剂Bi~(3+)到Eu~(3+)的能量传递,使Eu~(3+)于595nm的发射大大增强,我们认为Bi~(3+)对Eu~(3+)的敏化作用是由于基质和Bi~(3+)的~1S。→ 3P_1的跃迁吸收了激发的能量,然后无辐射弛豫到Eu~(3+)的激发态~5D_0,产生~5D_0 → 7F_1的磁偶极跃迁。对于不同Eu~(3+)浓度的Sr_2YSbO_6:Eu~(3+)和Sr_2YSbO_6:Eu~(3+), Bi~(3+)体系用245nm激发时均能观察到Eu~(3+)于595nm的尖峰发射。用基质和Bi~(3+)的激发峰335nm激发时,观察到基质和Bi~(3+)对Eu~(3+)具有某种能量传递。敏化作用机理与上述的Ba_2YSbO_6:Eu~(3+)和Ba_2YSbO_6:Eu~(3+), Bi~(3+)体系相同。对于不同Eu~(3+)浓度的Ca_2YSbO_6:Eu~(3+)和Ca_2YSbO_6:Eu~(3+), Bi~(3+)体系用396nm激发时,均能观察到Eu~(3+)于613nm很强的尖峰发射。用基质和Bi~(3+)的激发峰313nm激发时,见到Bi~(3+)和基质对Eu~(3+)具有某种能量传递,这种敏化作用主要是由于基质和Bi~(3+)的3P_1 → ~1S_0的400nm的宽带发射和Eu~(3+)的~7F_0 → ~5L_6的396nm的吸收相匹配产生~5L_6→~5D_0→~7F_2的跃迁。通过对激发光谱和荧光光谱的分析给出了Ca_2Y_(0.96)Eu_(0.04)SbO_6的能级图,从实验上可见,Eu~(3+)的发光强烈地依赖于钙钛矿的结构,当Eu~(3+)在空间群为Fm3m 的Ba_2YSbO_6和Sr_2YSbO_6中处于Oh点对称性时,主要是~5D_0 → ~7F_1的磁偶极跃迁。当Eu~(3+)在空间群为P_(21)的单斜钙钛矿中时,主要是~5D_0 → ~7F_2的电偶极跃迁。对于不同掺杂浓度M_2YSbO_6:R~(13+)(M = Ba、Ca; R' = Sm、Dy、Ho、Er、Tm)体系,通过激发和荧光光谱的研究,合理地确定了谱项。发现基质对Sm~(3+)、Dy~(3+)、Ho~(3+)具有敏化作用。对不同Bi~(3+)浓度的Ca_2YSbO_6:Bi~(3+),由激发和荧光光谱可见Bi~(3+)具有二个激发带,第一激发带位于240nm处相当于~1S_0 → ~1P_1的跃迁,第二激发带位于315nm处相当于~1S_0 → ~3P_1的跃迁。有一个很强的兰紫色发射位于400nm处相当于~3P_1 →~1S_0的跃迁。

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本论文合成了R_1Ba_2Cu_3O_(2-x) (R = La、Nd、Sm、Eu、Gd、Dr、Ho、Er、Tm、Yb)、Y_2Ba_2Cu_3O_(2-x) (x = 0.10~1.17)和Y_1Ba_2Cu_3O_(7-x)S_x (x = 0~2),并对磁性和超导电性进行了较为系统的研究。R_1Ba_2Cu_3O_(2-x)的磁化率在T > Tc的很宽的温度范围内服从Curic-Weiss定律,求得的有效磁矩略大于理论值,差值与Y_1Ba_2Cu_3O_(2-x)中Cu~(2+)磁矩相近,说明Cu~(2+)的磁矩对体系磁性有额外贡献,这贡献随R~(3+)离子中自旋平行的电子权的增多而增大。其高温下的磁化率CT > 700K)相对Curic-Weiss定律发生较大偏离,这偏离可能的来源有三个:高温下稀土离子发生较大的能级反转效应,高温下结构相变对磁性的影响,高温下氧含量减少造成Cu~(2+)磁矩增大。R_1Ba_2Cu_3O_(2-x)磁化率在T < Tc时也服从Curic-Weiss定律,R~(3+)磁矩是定域的,表明超导与磁性相互独立。互不相关,稀土磁矩与传导电子间无相互作用。用Sr取代R_1Ba_2Cu_3O_(2-x)中的Ba,没能使体系产生磁有序的变化,但却使有效磁矩增大,并完全破坏了样品的超导电性。Sm~(3+)磁化率不服从Curic-Weiss定律,在Sm_1Ba_2Cu_3O_(2-x)中Sm~(3+)显示了典型Van VlccK离子的特性。Y_1Ba_2Cu_3O_(2-x)随氧含量减少发生超导体一半导体一绝缘体的转化,当氧含量由6.90减小至6.49时发生由正交到四方的结构相变。当(7-x) = 5.83时有较多杂质相出现,123相开始分解。样品磁化率均服从Curic-Weiss定律,并随氧含量增大磁化率-温度曲线越来越趋于平缓(直线),当(7-x) = 6.90时磁化率基本不随温度变化,这时Pauli顺磁性占主导地位,这说明氧含量增加定域磁矩减少,求得的有效磁矩Peff随氧含量增大总趋势减小。提出了电子“巡游”的观点,较好地解释了上述现象,并推测出Cu(2)的d电子是离域的,对样品磁矩没有贡献,样品Peff来源于部分Cu(1)的定域Cu~(2+)的磁矩,上述推测被EPR结果证实。正交相Y_1Ba_2Cu_3O_(2-x)的EPR谱显示了中心对称成准立方晶场中Cu~(2+)(d~9, S = 1/2, I = 3/2)的EPR物性。而四方相样品的EPR谱却出现了明显的各向异性,说明观察到的为Cu(1)的EPR信号,由Cu(1)~(2+)的写域磁矩产生。Y_1Ba_2Cu_3O_(2-x)的EPR信号束源于本体相,而非Y_2Cu_2O_5、BaCuO_2、Y_2BaCuO_5等杂质相。各样品EPR信号的自旋浓度远小于1spin/cu,并随氧含量减小而增大,当(7-x) = 6.49、6.40时自旋浓度出现陡增,这时伴随由正交到四方的转化,证明了电子“巡游”观点的正确。用硫部分取代Y_1Ba_2Cu_3O_2g中的氧,当Y_1Ba_2Cu_3O_(2-x)Sx中x = 0.11时Tc = 92.6K,比Y_1Ba_2Cu_3O_(7-x)升高2K,但由于杂质相的存在,ΔTc加宽。其他样品多为半导体和绝缘体。硫取代0,当x = 0.04,0.06,0.11和1.20时磁化率服从Curic-Weiss定律,并且x = 0.87,1.2时分别在230K、240K出现反铁磁有序。其他样品由于Cu被还原为+1价而变成抗磁性。x = 0.11 (Tc = 92.6K),EPR谱为正交场中Cu~(2+)的信号。自旋浓度与温度无关。当所有Cu均为Cu~(1+)时,测问的是-s-的EPR信号,而Cu为混合价态(+1和+2时)测问是上述两种信号的叠加。

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丙型肝炎病毒(Hepatitis C virus, HCV)的全基因组序列测定,曾经由于许多方面 的条件限制而难于完成。但是,其对于研究HCV 分子病毒学、流行病学、进化和致 病性却至关重要,特别是在临床应用中,不同序列的基因型决定α-干扰素治疗的不同 效果。在本研究完成之前,HCV 基因型6 仅有6 个亚型有其全基因组序列。因此, 本研究的主要目的在于,测定HCV 变异株代表基因型6 其余的11 个亚型和新亚型的 全基因组序列,并深入分析。 本研究从样品分别来自于中国、泰国,和在美国及加拿大生活的东南亚国家移民 的HCV 感染者。因为样品有限,改良传统的PCR 方法,摸索出“桥”和“岛”DNA 全序列扩增法,从每例样品100μl 血清或从100μl 血清中获得的cDNA 中测定了13 个HCV 全基因组核苷酸序列。 以来源于Genbank 的已知基因型6 的七个全长序列为参考对所测定的13 个亚型 全序列进行共同分析显示,这些全基因组核苷酸的两两比较相似率变化范围为 71.9%--82.7%,著地, 这四对序列间的相同率高于标准定义的HCV 基因亚型之间的 范围值75%-80%。为了进一步理解和证实这些亚型间的遗传相似性,本研究还测定 了代表这4 对亚型的病毒原型株的全基因序列,结果显示了相同的核苷酸水平上的变 异范围,这为HCV 基因亚型的分类提供了新的认识,亦强调了全长序列对于分类的 重要性。 从系统发育方面的分析证实,本研究所测得的13 个分离株都属于基因型6。在系 统发育树上,每个病毒株代表一个独立的枝。并形成了高度分化的HCV 基因型6 分 枝,从而清楚显示,各亚型的独立分布。本研究至此完成了基因型6 中17 个亚型的 全序列测定,而km41 和gz52557 因缺乏其临床上和流行病学上的多个感染病例的证 实,而继续保留其亚型未命名状态。结合来源于Los Alamos HCV database 的基因型6 的已知部分序列的变异株进一步分析,发现各相近亚型变异株均来自东南亚或东南亚国家移民,这提示了这些HCV 的相同感染源。 为了探讨HCV 夫妻间传播的可能性,本研究还测定了来自于泰国的两位感染 HCV 的献血员及其感染HCV 的配偶。这4 个基因序列C-0044 和C-0046 之间核苷 酸相同率为98.1%,而C-0185 和 C-0192 之间为97.8%。文献研究感染HCV 的夫妇 间的部分亚基因序列的相同率为96.3%至100%,本研究结果与此范围相符,并第一 次用全基因组序列提示了HCV 在夫妻间传播的可能性。 本研究还测定了基因型6 的另一个变异株的全基因组序列:HK6554,香港的某患 者,与上文中的GX004 一起,均为静脉吸毒者,并共同感染了HCV 和HIV-1。分析 结果还表明了一种趋势,即是在中国南方,基因亚型6e 有从以前的地方性传播方式 转为现有的流行性传播方式。这种转变可能由于静脉吸毒感染HCV 的人群的网络传 播而加快。 综上,本研究用传统PCR、简并引物结合链特异引物的方法有效地测定了共21 个病毒株的全基因序列。该方法也可用于其它分子流行病学的研究,特别在测定珍贵 的病毒序列然而样品量又受限时。本研究所测定的全基因组序列代表HCV 中最古老、 分化最多、地方性传播、又可能动物源性的基因型6 的全套17 个亚型。这有助于进 一步理解HCV 基因亚型的分类意义、更准确评价HCV 的进化和起源,亦有助于发 现HCV 新的变异株和提高临床诊断、治疗,为将来HCV 的流行及公众健康的预测、 预防和疫苗的制备奠定了坚实的分子遗传学基础。

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研制了有源区为InGaAs张应变体材料的1.55μm偏振不灵敏半导体光放大器(SOA)。采用束传播法计算了偏离镜面垂直方向7°的埋层波导结构模式场分布,并用平面波展开法设计了多层抗反射膜,在TE模和TM模反射率同时小于10^-4时膜厚允许误差为3%。对放大自发发射谱(ASE)和增益谱的分析表明,他们具有基本一致的偏振灵敏度。对一腔长800μm的SOA在注入电流250mA时,测量得出TE模和TM模的ASE谱偏振灵敏度小于0.5dB,增益谱3dB带宽为63nm,1550nm处光纤到光纤增益为11.9dB,3dB饱和输出功率为5.6dB,在1570nm处的噪声指数为7.8dB。而一腔长1000μmSOA耦合封装后得到的最大增益为15dB。

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高功率激光二极管列阵广泛应用于抽运固体激光器.报道了17 kW GaAs/AlGaAs叠层激光二极管列阵的设计、制作过程和测试结果.为了提高器件的输出功率,一方面采用宽波导量子阱外延结构,降低腔面光功率密度,提高单个激光条的输出功率,通过金属有机物化学气相沉积(MOCVD)方法进行材料生长,经过光刻、金属化、镀膜等工艺制备1 cm激光条,填充密度为80%,单个激光条输出功率达100 W以上;另一方面器件采用高密度叠层封装结构,提高器件的总输出功率,实现了160个激光条叠层封装,条间距0.5 mm.经测试,器件输出功率达17kW,峰值波长为807.6 nm,谱线宽度为4.9 nm.