49 resultados para Terahertz (THz)


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In this paper, we demonstrated a dual-wavelength competitive output in Nd:Y3SC1.5Al3.5O12 ceramic disk laser. Different dual-wavelength output behaviors for Nd:YSAG and Nd:YAG ceramic disk laser were investigated and discussed. By applying the energy transfer model, we suggested the reasonable explanation for this new phenomenon as the disordered replacing of Al3+ ions by Sc3+ ions. The main advantage of the dual-wavelength ceramic laser is the possibility to serve as the seed source to generate Terahertz radiation. (C) 2008 Elsevier B.V. All rights reserved.

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CP43和CP47是PSII中位于类囊体膜上的两种内周天线色素蛋白复合体,它们都是由六个跨膜的α-螺旋和五个膜外环组成。CP43和CP47的主要功能是把光系统II(PSII)外周天线色素蛋白复合体(LHCII)吸收的能量传给反应中心(RC),从而引起光化学反应。因此,研究CP43和CP47的结构与功能对于揭示植物光合作用高效吸能、传能的分子机理具有重要意义。由于CP43和CP47的分离纯化比较困难,所以相对于其它的光合膜蛋白来说,人们对CP43和CP47的研究比较少。在本文中,我们在分离、纯化CP43和CP47的基础上,采用多种光谱学和波谱学技术对CP43和CP47在GuHCl和高温作用下的变性过程及其结构与功能的变化规律进行了比较深入的研究,获得了如下结果: 1. CP43和CP47膜外区的结构特点及盐酸胍(GuHCl)引起的变性研究 我们用荧光光谱、园二色(CD)光谱研究了GuHCl引起CP43和CP47的变性过程及其膜外区的结构特点。研究发现:CP43和CP47的膜外区具有一定的有序结构,而不是一种没有规则的伸展状态;和CP43相比,CP47的三级结构及Chl a的微环境对GuHCl更敏感。在GuHCl作用下,从β-Car到Chl a的能量传递变化和三级结构的变化密切相关,而与二级结构变化的相关性则较小;和大多数水溶性蛋白不一样,CP43和CP47对GuHCl变性有一定的抵抗力,而且其变性过程不表现为二态过程,这些都是膜蛋白的特点。 2 CP43和CP47中与芳香族氨基酸有关的能量传递研究 我们用吸收光谱、荧光光谱并参照PSII的3.5 Å的晶体结构分析结果研究了CP43和CP47中与芳香族氨基酸有关的能量传递。发现:和水溶性蛋白不一样,CP43和CP47中的酪氨酸(Tyrs)并不能有效的把其能量传给色氨酸(Trps);CP43和CP47中的芳香族氨基酸能通过Föster机制和Dexter机制把其能量传给Chl a,并且CP47中的传递效率要大于CP43;在CP47中Föster机制是芳香族氨基酸和Chl a之间能量传递的主要方式,而在CP43中Dexter机制则是主要方式。这些结果也暗示了,太阳光中的紫外辐射对植物来说除了其伤害作用以外也有一定的益处。 3 GuHCl诱导CP43和CP47变性的太赫兹(THz)光谱研究 THz时域光谱技术(THz-TDS)是研究分子构型状态的一个新工具。近年来,已被应用于物理或化学分子的研究中。我们首次把这个技术应用到光合膜蛋白CP43和CP47的GuHCl变性研究上。研究发现,在小于1.5 THz时,THz吸收光谱强度随着频率的增加而增加可以看作是蛋白质变性的标志。在GuHCl作用下频域光谱中出现的1.8 THz峰应来源于Chl a和GuHCl之间的相互作用。实验结果表明,THz光谱是区分蛋白分子的不同构型状态以及监测蛋白变性过程的有力工具。 4 CP43热变性的傅立叶变换红外光谱和THz光谱研究 我们用傅立叶变换红外光谱技术(FT-IR)、SDS聚丙稀凝胶电泳(SDS-PAGE)和THz光谱技术对CP43的热变性过程进行了研究。结果表明,在高温处理下,CP43的二级结构发生了变化,且其跃变点发生在59℃。随着温度的逐渐升高,CP43先发生凝集,接着又发生降解;CP43的低频振动模随着温度的升高和分子量的减小也发生变化。我们还证实THz光谱技术在监测膜蛋白的热变性时既有它的优越性,也存在一些不足之处。这些结果为THz-TDS技术在生物样品上的应用提供了基本的资料,并完善了相关的理论。

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本文主要研究了一系列具有不同配位环璄的锰化合物与去锰PSII颗粒的光组装过程;其次,应用太赫兹时域光谱技术对锰稳定蛋白PsbO蛋白的结构与功能进行了研究。主要结果如下: 1. 选择了一组单核、锰中心原子为二价、与羧基氧和氮配位的锰化合物与去锰光系统II颗粒进行了重组研究。研究结果表明,锰化合物中锰原子和氮原子的配位连接是影响电子传递恢复和放氧复合物重组效率的重要因素。锰化合物中锰原子与氮原子的配位,促进了锰原子与PSII脱辅基蛋白上的氨基酸残基进行光配位。33 kDa蛋白的加入显著提高光组装放氧活性,33 kDa蛋白的柔性构象有助于锰簇接受体积大的分子,并提高其稳定性,从而促进PSII反应中心锰簇的光组装。 2. 选择了一组拥有相同配体、锰中心原子价态不同的锰化合物与去锰PSII 颗粒进行重组。三个锰价态为+2,+3,+4价的锰化合物均表现出较高的恢复电子传递和放氧活性的能力,但锰与配体氧原子共价连接的锰化合物恢复电子传递和放氧活性的能力的很差,Mn-O连接阻碍WOC的重组。研究结果表明,锰化合物恢复电子传递活性和放氧活性的能力也受其中锰原子的价态及其它结构因素的影响。锰价态较低的锰化合物比锰价态较高的锰化合物更容易向PSII反应中心提供电子。锰化合物恢复电子传递和放氧活性的因素是不同的。锰化合物作为有效电子供体的效率与其螯合环数成反比,但配体的大小不是影响锰化合物重组放氧活性的主要因素。 3. 应用太赫兹时域光谱技术结合荧光光谱技术,研究了锰稳定蛋白PsbO在与金属离子作用及单个氨基酸被修饰后其构象变化和低频振动模的变化。实验结果显示,该蛋白上唯一的色氨酸对整个蛋白构象至关重要,它的改变引起整个蛋白分子低频振动模发生明显改变。此外,太赫兹时域光谱结果显示,PsbO可能含有钙结合位点。太赫兹时域光谱技术在研究蛋白构象变化,尤其是金属离子诱导的构象变化方面是相当灵敏的。

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Mode competitions between modes with different output coupling efficiencies can result in optical bistability under certain asymmetric nonlinear gain. For a GaInAsP/InP equilateral triangle microlaser with the side length of 10 mu m, the drop of the output power with the increase of the injection current is observed corresponding to transverse mode transitions. Furthermore, the measured laser spectra up to 270 K show that lasing modes coexist with the wavelength interval of 39 nm at 240 K. The emission at 5.2 THz can be expected by the mode frequency beating with the 39 nm interval.

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Coupled microcircular resonators tangentially coupled to a bus waveguide, which is between the resonators, are numerically investigated by the finite-difference time-domain technique. For symmetrically coupled microcircular resonators with refractive index of 3.2, radius of 2 mu m, and width of the bus waveguide of 0.4 mu m, a mode Q factor of the order of 105 is obtained for a mode at the frequency of 243 THz. An output coupling efficiency of as high as 0.99 is calculated for a mode with a Q factor ranging from 10(3) to 10(4). The mode Q factor is 2 orders larger than that of the modes confined in a single circular resonator tangentially coupled to the same bus waveguide. Furthermore, the high Q traveling modes in the coupled microcircular resonators are suitable for optical single processing.

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High-power strain-compensated In1-xGaxAs/ln(1-y)Al(y)As quantum cascade lasers (lambda similar to 5.5 mu m) are demonstrated. Peak power at least 1.2W per facet for a 32 mu mx2mm uncoated laser stored in ambient condition for 240 days, is obtained at 80 K. Considering the collection efficiency of 60%, the actual output power is 4W at this temperature.

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A 1.55 mu m InGaAsP-InP partly gain-coupled two-section DFB self-pulsation laser (SPL) with a varied ridge width has been fabricated. The laser produces self-pulsations with a frequency tuning range of more than 135 GHz. All-optical clock recovery from 40 Gb/s degraded data streams has been demonstrated. Successful lockings of the device at frequencies of 30 GHz, 40 GHz, 50 GHz, and 60 GHz to a 10 GHz sidemode injection are also conducted, which demonstrates the capability of the device for all-optical clock recovery at different frequencies. This flexibility of the device is highly desired for practical uses. Crown Copyright

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Based on the phase-conjugate polarization interference between two one-photon processes. When the laser has broadband linewidth, the sum-frequency polarization beat (SFPB) signal shows the autocorrelation of SFPB exhibits hybrid radiation-matter detuning terahertz damping oscillation. As an attosecond ultrafast modulation process, it can be extended intrinsically to any sum-frequency of energy-levels. It hits been also found that the asymmetric behaviors of the polarization beat signals result from the unbalanced dispersion effects, (c) 2005 Elsevier B.V. All rights reserved.

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Based on the phase-conjugation polarization interference between two two-photon processes, we theoretically investigated the attosecond scale asymmetry sum-frequency polarization beat in four-level system (FASPB). The field correlation has weak influence on the FASPB signal when the laser has narrow bandwidth. Conversely, when the laser has broadband linewidth, the FASPB signal shows resonance-nonresonance cross correlation. The two-photon signal exhibits hybrid radiation-matter detuning terahertz; damping oscillation, i.e., when the laser frequency is off resonance from the two-photon transition, the signal exhibits damping oscillation and the profile of the two-photon self-correlation signal also exhibits zero time-delay asymmetry of the maxima. We have also investigated the asymmetry of attosecond polarization beat caused by the shift of the two-photon self-correlation zero time-delay phenomenon, in which the maxima of the two two-photon signals are shifted from zero time-delay point to opposite directions. As an attosecond ultrafast modulation process, FASPB can be intrinsically extended to any level-summation systems of two dipolar forbidden excited states.

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We have investigated the dressed effects of non-degenerate four-wave mixing (NDFWM) and demonstrated a phase-sensitive method of studying the fifth-order nonlinear susceptibility due to atomic coherence in RN-type four-level system. In the presence of a strong coupling field, NDFWM spectrum exhibits Autler-Townes splitting, accompanied by either suppression or enhancement of the NDFWM signal, which is directly related to the competition between the absorption and dispersion contributions. The heterodyne-detected nonlinear absorption and dispersion of six-wave mixing signal in the RN-type system show that the hybrid radiation-matter detuning damping oscillation is in the THz range and can be controlled and modified through the colour-locked correlation of twin noisy fields.

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Based on the phase-conjugate polarization interference between two-pathway excitations, we obtained an analytic closed form for the second-order or fourth-order Markovian stochastic correlation of the V three-level sum-frequency polarization beat (SFPB) in attosecond scale. Novel interferometric oscillatory behavior is exposed in terms of radiation-radiation, radiation-matter, and matter-matter polarization beats. The phase-coherent control of the light beams in the SFPB is subtle. When the laser has broadband linewidth, the homodyne detected SFPB signal shows resonant-nonresonant cross correlation, a drastic difference for three Markovian stochastic fields, and the autocorrelation of the SFPB exhibits hybrid radiation-matter detuning terahertz damping oscillation. As an attosecond ultrafast modulation process, it can be extended intrinsically to any sum frequency of energy levels. It has been also found that the asymmetric behaviors of the polarization beat signals due to the unbalanced controllable dispersion effects between the two arms of interferometer do not affect the overall accuracy in case using the SFPB to measure the Doppler-free energy-level sum of two excited states.

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We investigate the interband optical absorption spectra near the band edge of a cylindrical semiconductor quantum wire in the presence of a static electric field and a terahertz electric field polarized along the axis. Optical absorption spectra are nonperturbatively calculated by solving the low-density semiconductor Bloch equations in real space and real time. The influence of the Franz-Keldysh (FK) effect and dynamical FK effect on the absorption spectrum is investigated. To highlight the physics behind the FK effect and dynamical FK effect, the spatiotemporal dynamics of the polarization wave packet are also presented. Under a reasonable static electric field, substantial and tunable absorption oscillations appear above the band gap. A terahertz field, however, will cause the Autler-Townes splitting of the main exciton peak and the emergence of multiphoton replicas. The presented results suggest that semiconductor quantum wires have potential applications in electro-optical devices.

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A zero-pole cancellation transimpedance amplifier (TIA) has been realized in 0.35 μm RF CMOS tech nology for Gigabit Ethernet applications. The TIA exploits a zero-pole cancellation configuration to isolate the input parasitic capacitance including photodiode capacitance from bandwidth deterioration. Simulation results show that the proposed TIA has a bandwidth of 1.9 GHz and a transimpedance gain of 65 dB·Ω for 1.5 pF photodiode capaci tance, with a gain-bandwidth product of 3.4 THz·Ω. Even with 2 pF photodiode capacitance, the bandwidth exhibits a decline of only 300 MHz, confirming the mechanism of the zero-pole cancellation configuration. The input resis tance is 50 Ω, and the average input noise current spectral density is 9.7 pA/(Hz)~(1/2). Testing results shows that the eye diagram at 1 Gb/s is wide open. The chip dissipates 17 mW under a single 3.3 V supply.