三相高压变压器型电子加速器性能研究

在当前国际上，强流大功率电子加速器的研究是应用于辐射行业辐射源的一个主要研究方向。内置加速管三相高压变压器型电子加速器与外置加速管强流大功率电子加速器相比，具有结构紧凑、造价低、结构简单等特点。本文对内置加速管三相变压器型电子加速器在研制过程中出现的高压击穿频繁、高压硅堆的损坏率高、能量脉动高、引出窗束流损失大等问题进行了研究，提出并实施了改进措施，得到了较好的调试结果。并对存在的问题进一步提出了改进方案。首先介绍了内置加速管三相变压器型电子加速器的原理、结构及组成。在此基础上，针对在加速器调试过程中出现的经常性高压击穿等严重制约加速器正常运行的问题，通过对三相高压变压器型的高压发生器在变压器特性分析、气体绝缘和电场分布计算、高压电极形状优化、过电压分布的计算、正常工作时的仿真，提出了改进方案。经过改进后，从调试结果来看，所设计的高压发生器能够正常稳定的工作。研究了作为高压发生器易损坏的关键部件之一的高压整流硅堆的性能。根据硅堆内部的结构和在高压发生器中所处的位置，合理的建立了等效电路，并对电路中各结构电容在硅堆耐高压方面的作用进行了详细的理论计算和分析。对硅堆内部管芯的排列及在加速器中的摆放位置提出了改进方案，经过改进，提高了硅堆的耐压值，也保证了高压发生器的正常稳定运行。对于加速器引出窗束流损失大和能量脉动高的问题，用PBGUN程序计算了优化后的阴极鼻锥聚束极结构在强流状态下的束流轨迹和加速管出口处的束斑；对能量脉动测量做了分析，并得到较真实的脉动值。论文最后对内置加速管三相变压器型电子加速器在整体调试中存在电子束受到变压器杂散磁场影响的问题做了介绍，提出了分离式的改进结构

高压变压器型电子加速器理论与实验研究

根据工业辐照对大功率电子加速器的需求，中科院近物所开展了高压变压器型DG系列电子加速器的研制。本文的主要工作是围绕其中两个型号DG-1.2（1.2MeV/40mA）和DG-2.5（2.5MeV/40mA）的研制及产业化而展开的研究。该类型电子加速器具备技术和市场优势， DG系列的研制成功，必将推动我国辐照加工业的发展。论文重点研究了基于空心变压器结构高压发生器的性能，改进了线圈、磁路结构，提高了发生器耦合效率；优化了高压电极结构，改善了电极周围电场分布，提升了发生器的绝缘性能，并评估了发生器高压击穿故障时的特性；选取了匹配的无功补偿方式，提高了发生器的功率因数。设计出新型热辐射间热式强流电子枪，研究了六硼化镧、六硼化镧钡两种材料热阴极的发射特性，均获得300mA以上的稳定束流发射。分析了DG型束流加速、传输结构，改进了引出系统结构，提高了束流引出效率；构建了基于PLC的工业化加速器控制系统，运行状况良好。通过专家测试，DG-1.2型已经达到设计参数1.2MeV/40mA，并能够稳定运行在1.2MeV/50mA；DG-2.5型，1.6MeV/30mA下通过测试，能够调试到2.0MeV/40mA。 最后，分析了DG系列电子加速器的进一步发展方向，初步确定了DG加速器的产业化目标

具有高压平台的SFC轴向注入系统的设计研究

兰州重离子加速系统(HIRFL)是由注入器SFC(螺旋型扇聚焦加速器)和主加速器SSC(分离扇聚焦加速器)组成注入器SFC使用外离子源轴向注入方法,注入从ECR离子源引出的低能高电荷态重离子束流.由于空间电荷效应和SFC杂散磁场的影响,造成SFC的注入效率不高,使得SFC的引出束流强度较低,从而也制约了SSC的束流强度,远远不能满足正在建造的兰州重离子加速器冷却储存环(HIRFL-CSR)和放射性束流物理实验对束流强度的要求.为了满足CSR和物理实验对束流强度的要求,该文通过对具有高压平台的SFC轴向注入系统的较为详细的设计研究,探讨在SFC上实现提高注入效率的可行性和有效性.

高稳定度高压开关电源设计

本文分析了国内外开关电源的发展和现状，研究了高压开关电源的基本原理以及开关电源在电力直流操作电源系统中的应用。根据兰州重离子加速器的要求，设计了一种高稳定度高压开关电源。该系统在借鉴国外和已有的类似电源的基础上，通过采用新的元器件和新的电力电子技术设计而成。该系统以工GBT作为功率开关器件，构成BUCK开关变换器，采用脉宽调制（PWM）技术来控制输出电压的变化。系统中采用TL494、UC3637、ML57962等一系列集成电路，以实现实时采样电压反馈信号、PWM信号以及工GBT所需要的功率驱动信号。电路中采用斩波调压和逆变分开，各司其职的结构，保证了电路可靠、线性的调节；采用前馈电路进行补偿，确保系统能很好的抑制电网的中频扰动。通过MATLAB的计算仿真证明，这些措施都对对系统的性能起到了很好的作用。为了系统的安全可靠，还设计了软启动和过流保护电路。通过实验证明该系统能安全、可靠运行，达到了设计要求。

八单元一维位置灵敏雪崩室

In the experiment of nuclear reaction, it is important to measure the mass, charge, energy and emitted direction of particles. For multiparameter measurement, we must use a detector or a group of detectors which can give the time, energy, and position information. The Large Area position sensitive Ionization Chamber(LAIC) is one of the eight experiment terminals of HIRFL. It is built for researching nuclear reactions from low energy to intermediate energy. It is an excellent equipment for energy measurements and atomic number identification of emitted fragments in this energy region. It is also designed to give the time and position information of the emitted fragments by itself. Obviously, an IC can not supply a good timing signal. Moreover, the mechanical installation is different from the original design by some other reasons. In this case, it is not enough to obtain the correct direction information of the emitted fragments. To obtain good timing signals and the correct direction information, some modifications must be made. It is well known that a PPAC can give us excellent timing signals. It also can be easily built as a position sensitive detector. For this reason, a specially designed PPAC is installed in the entrance of the LAIC. For the different purposes, two types of PPACs were designed and tested. Both are OCTPSACs (OCTunit one dimension Position Sensitive Avalanche Counter). In this paper, both OCTPSACs will be introduced. Based on the requirements of the LAIC, the OCTPSACs consist of eight position sensitive PPACs. Each PPAC has an anode and a cathode. In both cases, the sizes are same. But different type of cathodes are used. In one type of OCTPSAC, its cathode is made of wire plane. It consists of gold-plated tungsten wires with the diameter of 20μm, spaced 0.5 mm apart from each other. The anode is a mylar foil which was evaporated by gold layer with the thickness of 50μg/cm~2 mounted on a printed plate in the shape of rectangle. the thickness of mylar foil is 1.5μm. The gap between anode and cathode is 3mm. The performance of the OCTPSAC has been tested by using a ~(252)Cf source in flowing isobutylene gas at the pressure of 3.4mb. The intrinsic time resolution of 289ps and position resolution of 2 mm have been obtained. In another type of OCTPSAC, the cathode is made of mylar foil, which is composed of gold strip by vacuume evaporation method with a special mask on the mylar foil. The thickness and the width of the gold strip is 50μg/cm~2 and 1.7mm. The strips are spaced 0.3 mm apart from each other. The anode is the same as the former type. We have obtained the time resolution of 296ps and position resolution of 2mm by using ~(241)Am-a source when the gas pressure is 6 mb and high voltage is 600V. The working gas is heptane

An etched porous interface for on-line capillary electrophoresis-based two-dimensional separation system

The construction and evaluation of an on-column etched fused-silica porous junction for on-line coupling of capillary isoelectric focusing (CIEF) with capillary zone electrophoresis (CZE) are described. Where two separation columns were integrated on a single piece of fused-silica capillary through the etched similar to4 to 5-mm length porous junction along the capillary. The junction is easily prepared by etching a short section of the capillary wall with HF after removing the polyimide coating. The etched section becomes a porous glass membrane that allows only small ions related to the background electrolyte to pass through when high voltage is applied across the separation capillary. The primary advantages of this novel porous junction interface over previous designs (in which the interface is usually formed by fracturing the capillary followed by connecting the two capillaries with a section of microdialysis hollow fiber membrane) are no dead volume, simplicity, and ruggedness, which is particularly well suited for an on-line coupling capillary electrophoresis-based multiple dimensional separation system. The performance of the 2D CIEF-CZE system constructed by such an etched porous junction was evaluated by the analyses of protein mixtures.

Study of an electroosmotic pump for liquid delivery and its application in capillary column liquid chromatography

A packed-bed electroosmotic pump (EOP) was constructed and evaluated. The EOP consisted of three capillary columns packed in parallel, a gas-releasing device, Pt electrodes and a high-voltage power supply. The EOP could generate output pressure above 5.0 MPa and constant flow rate in the range of nl/min to a few mul/min for pure water, pure methanol, 2 mM potassium dihydrogenphosphate buffer, the buffer-methanol mixture and the pure water-methanol mixture at applied potentials less than 20 W The composition of solvent before/after pumping was quantitatively determined by using a gas chromatograph equipped with both flame ionization detector and thermal conductivity detector. It was found that there were no apparent changes in composition and relative concentrations after pumping process for a methanol-ethanol-acetonitrile mixture and a methanol-water mixture. Theoretical aspect of the EOP was discussed in detail. An capillary HPLC system consisting of the EOP, an injection valve, a 15 cm x 320 mum i.d., 5 mum Spherigel C(18) stainless steel analytical column, and an on-column UV detector was connected to evaluate the performance of the EOP. A comparative study was also carried out with a mechanical capillary HPLC pump on the same system. The results demonstrated that the reproducibility of flow rate and the pulsation-free flow property of the EOP are superior to that of mechanical pump in capillary HPLC application. (C) 2004 Elsevier B.V. All rights reserved.

Effect of sodium alginate concentration on membrane strength and permeating property of poly-l-arginine group microcapsule

A novel poly-l-arginine microcapsule was prepared due to its nutritional function and pharmacological efficacy. A high-voltage electrostatic droplet generator was used to make uniform microcapsules. The results show that the membrane strength and permeating property are both remarkably affected with the changes of sodium alginate concentration. With the sodium alginate concentration increasing, gel beads sizes increase from 233 mum to 350 mum, release ratio is also higher at the same time, but the membrane strength decreases.

An electroosmotic pump for packed capillary liquid chromatography

An electroosmotic pump (EOP) capable of generating pressure above 3 MPa and mul/min flow rate with reverse phase mobile phases of HPLC was constructed and evaluated. The pump consisted of three parallel connected fused silica capillary columns (25 cm x 320 mum I.D.) packed with 2 mum silica materials, hollow electrodes, a high voltage DC power supply, and. a liquid pressure transducer. The EOP was applied in a capillary liquid chromatographic system for mobile phase delivery instead of a mechanical pump. Standard samples containing thiourea, naphthalene, anthracene, phenanthrene and acetonitrile were separated on a 15 cm x 320 mum I.D. 5 mum Chromasil C-18 packed capillary column with acetonitrile/water as mobile phase. (C) 2003 Elsevier Science B.V. All rights reserved.

On-line hyphenation of capillary isoelectric focusing and capillary gel electrophoresis by a dialysis interface

An on-line two-dimensional (2D) capillary electrophoresis (CE) system consisting of capillary isoelectric focusing (CIEF) and capillary gel electrophoresis (CGE) was introduced. To validate this 2D system, a dialysis interface was developed by mounting a hollow fiber on a methacrylate resin plate to hyphenate the two CE modes. The two dimensions of capillary shared a cathode fixated into a reservoir in the methacrylate plate; thus, with three electrodes and only one high-voltage source, a 2D CE framework was successfully established. A practical 2D CIEF-CGE experiment was carried out to deal with a target protein, hemoglobin (Hb). After the Hb variants with different isoelectric points (pIs) were focused in various bands in the first-dimension capillary, they were chemically mobilized one after another and fed to the second-dimension capillary for further separation in polyacrylamide gel. During this procedure, a single CIEF band was separated into several peaks due to different molecular weights. The resulting electrophoregrarn is quite different from that of either CIEF or CGE; therefore, more information about the studied Hb sample can be obtained.

Two-dimensional capillary electrophoresis involving capillary isoelectric focusing and capillary zone electrophoresis

Capillary isoelectric focusing (cIEF) and capillary zone electrophoresis (CZE) was on-line hyphenated by a dialysis interface to achieve a 2D capillary electrophoresis (CE) system. The system was used with just one high-voltage power supply and three electrodes (one cathode shared by the two dimensions). The focused zone in the first dimension (i.e. the cIEF) was driven to the dialysis interface by electroosmotic flow (EOF), besides chemical mobilization from the first anode to the shared cathode. And then in the second dimension (i.e. the CZE), the separated zone was further separated and driven by an inverted EOF, which originated from the charged layer of a cationic surfactant adsorbed onto the inner wall of the capillary. Finally, a solution of ribonuclease was rapidly separated to assess the feasibility of the two-dimensional CE implement. (C) 2003 Elsevier B.V. All rights reserved.

Conversion process of the dominant electroluminescence mechanism in a molecularly doped organic light-emitting device with only electron trapping

In this work, the detailed conversion process of the dominant electroluminescence (EL) mechanism in a device with Eu(TTA)(3)phen (TTA=thenoyltrifluoroacetone, phen=1,10-phenanthroline) doped CBP (4,4(')-N,N-'-dicarbazole-biphenyl) film as the emitting layer was investigated by analyzing the evolution of carrier distribution on dye and host molecules with increasing voltage. Firstly, it was confirmed that only electrons can be trapped in Eu(TTA)(3)phen doped CBP. As a result, holes and electrons would be situated on CBP and Eu(TTA)(3)phen molecules, respectively, and thus creates an unbalanced carrier distribution on both dye and host molecules. With the help of EL and photoluminescence spectra, the distribution of holes and electrons on both Eu(TTA)(3)phen and CBP molecules was demonstrated to change gradually with increasing voltage. Therefore, the dominant EL mechanism in this device changes gradually from carrier trapping at relatively low voltage to Forster energy transfer at relatively high voltage.

Capillary electrophoresis coupled with electrochemiluminescence detection using porous etched joint

A new setup to couple capillary electrophoresis (CE) with electrochemiluminescence (ECL) detection is described in which the electrical connection of CE is achieved through a porous section at a distance of 7 mm from the CE capillary outlet. Because the porous capillary wall allowed the CE current to pass through and there was no electric field gradient beyond that section, the influence of CE high-voltage field on the ECL procedure was eliminated. The porous section formed by etching the capillary with hydrofluoric acid after only one side of the circumference of 2-3 mm of polyimide coating of the capillary was removed, while keeping the polyimide coating on the other part to protect the capillary from HF etching makes the capillary joint much more robust since only a part of the circumference of it is etched. A standard three-electrode configuration was used in experiments with Pt wire as a counter electrode, Ag/AgCl as a reference electrode, and a 300-mum diameter Pt disk as a working electrode. Compared with CE-ECL conventional decoupler designs, the present setup with a porous joint has no added dead volume created.

Charge carrier injection and transport in PVK: Alq(3) blend films

We have investigated the current-voltage and electroluminescent (EL) characteristics of single-layer organic devices based on poly(9-vinylcarbazole) (PVK) and tris(8-hydroxyquinoline)aluminium (Alq(3)) blend with different PVK : Alq(3) concentrations. The experimental results from the observed thickness and temperature dependence clearly demonstrate that the current at low voltage is due to the holes injected at the anode and is space-charge limited, whereas the current at the high voltage that steeply increases is explained as the electron tunnelling injection at the cathode. The hole mobility is directly determined by space-charge-limited current at the low voltage region and decreases with increasing Alq(3) content in the blend. The EL efficiency shows concentration dependence, which is attributed to the change of the transport of electrons and holes in the blend film.

New technique for capillary electrophoresis directly coupled with end-column electrochemiluminescence detection

capillary electrophoresis (CE) is characterized. A 300 mum diameter Pt working electrode was used to directly couple with a 75 mum inner diameter separation capillary without an electric field decoupler. The hydrodynamic cyclic voltammogram (CV) of Ru(bpy)(3)(2+) showed that electrophoretic current did not affect the ECL reaction. The presence of high-voltage (HV) field only resulted in the shift of the ECL detection potential. The distance of capillary to electrode was an important parameter for optimizing detection performance as it determined the characteristics of mass transport toward the electrode and the actual concentration of Ru(bpy)(3)(2+) in the detection region. The optimum distance of capillary to electrode was decided by the inner diameter of the capillary, too. For a 75 mum capillary, the working electrode should be placed away from the capillary outlet at a distance within the range of 20-260 mum. The effects of pH value of ECL solution and molecular structure of analytes on peak height and theoretical plate numbers were discussed. Using the 75 mum capillary, under the optimum conditions, the method provided a linear range for tripropylamine (TPA) between 1 x 10(-10) and 1 X 10(-5) mol/L with correlation coefficient of 0.998. The detection limit (signal-to-noise ratio S/N = 3) was 5.0 x 10(-11) mol/L. The relative standard deviation in peak height for eight consecutive injections was 5.6%. By this new technique lidocaine spiked in a urine sample was determined. The method exhibited the linear range for lidocaine from 5.0 x 10(-8) to 1.0 X 10(-5) mol/L with correlation efficient of 0.998. The limit of detection (S/N = 3) was 2.0 x 10(-1) mol/L.