Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)

Comunicación al congreso 1st European Conference on Metal Organic Frameworks and Porous Polymers, celebrado en Postdam del 11 al 14 de octubre de 2015

Host-guest chemistry of solid coordination frameworks (SCFs) based on Copper(II)-Pyridine Ligands

283 p.

Egalitarian distributions in coalitional models: The Lorenz criterion

The paper presents a framework where the most important single-valued solutions in the literature of TU games are jointly analyzed. The paper also suggests that similar frameworks may be useful for other coalitional models.

Ahalmen espaziala hezkuntza matematikoan

[EUS] Matematikaren irakaskuntzaren helburuenetako bat hezkuntza maila guztietan ikasleen ahalmen intelektualen garapena da. Ahalmen espazialaren trataera eskolan urria izan da, bereziki zenbakizko ahalmenak edota arrazonamenduzko ahalmenak izan duten trataerarekin konparatzen badugu. Hezkuntza Matematikoan egindako berrikusketek ahalmen espazialaren azterketaren garrantzia azpimarratzen dute nahiz eta erreferentzi marko baten ezak sakabanatzen eta zailtzen dituen emaitzen lorpena, behin betikoak izateko erreplikagarriak izan behar dutela jakinik. Ondoren proposatzen den ikerketa-lerroak ahalmen espaziala alderdi hirukoitz batetik abiaturik aztertu nahi du: egitura, garapena eta hobetze-proposamenak kontutan harturik. Hiru arlo horietan proposaturiko ereduek bermatuko dute diagnostiko zuzen bat, ikasleen ahalmen espaziala hobetuko duena.

Arqueología de la Arquitectura en España

[ES]En esta ponencia se traza un cuadro general sobre el concepto actual de la arqueología de la arquitectura en España, y se plantea una serie de propuestas y de elementos de reflexión que la disciplina tendrá que abordar en un próximo futuro. Para ello se analizarán las fases formativas de la disciplina como resultado de la adquisición en los años 80 de un bagaje conceptual y metodológico aprehendido de la tradición italiana, y como se ha aplicado a la situación de la investigación y la gestión del patrimonio edificado en los 90. Concretamente se prestará una atención específica a los marcos institucionales, académicos y administrativos que han condicionado hasta el momento su desarrollo. Por último, se prestará una atención particular al uso que se realiza de la información producida por las investigaciones arqueológicas en las intervenciones de rehabilitación y restauración del patrimonio edificado, analizando críticamente algunos ejemplos significativos.

Implications of governance structures on urban climate action: evidence from Italy and Spain

47 p.

Synthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))

[EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ligands. In this sense, combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce extended structures. In this context, this work is focused on two novel CuII-based SCFs exhibiting PDC (2,5-pyridinedicarboxylate) and bpa (1,2-di(4-pyridyl)ethane), being the first structures reported in literature containing both ligands. Chemical formula are [Cu2[(PDC)2(bpa)(H2O)2]•3H2O•DMF (1), and [Cu2(PDC)2(bpa)(H2O)2]•7H2O (2), where DMF is dimethylformamide. Compounds 1 and 2 have been characterized by means of XRD, IR, TG/DTG, and DTA analysis.

Polímeros de Coordinación con Centros Metálicos en Entornos de Coordinación Variables: Posibles Aplicaciones.

Presentación de power point. Comunicación oral presentada en el 1er Simposium sobre Propiedades y Aplicaciones de MOFs y COFs, celebrado en Granada en abril de 2015

Deep learning review and its applications

Deep neural networks have recently gained popularity for improv- ing state-of-the-art machine learning algorithms in diverse areas such as speech recognition, computer vision and bioinformatics. Convolutional networks especially have shown prowess in visual recognition tasks such as object recognition and detection in which this work is focused on. Mod- ern award-winning architectures have systematically surpassed previous attempts at tackling computer vision problems and keep winning most current competitions. After a brief study of deep learning architectures and readily available frameworks and libraries, the LeNet handwriting digit recognition network study case is developed, and lastly a deep learn- ing network for playing simple videogames is reviewed.

Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs

Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities.

Modeling habits as self-sustaining patterns of sensorimotor behavior

In the recent history of psychology and cognitive neuroscience, the notion of habit has been reduced to a stimulus-triggered response probability correlation. In this paper we use a computational model to present an alternative theoretical view (with some philosophical implications), where habits are seen as self-maintaining patterns of behavior that share properties in common with self-maintaining biological processes, and that inhabit a complex ecological context, including the presence and influence of other habits. Far from mechanical automatisms, this organismic and self-organizing concept of habit can overcome the dominating atomistic and statistical conceptions, and the high temporal resolution effects of situatedness, embodiment and sensorimotor loops emerge as playing a more central, subtle and complex role in the organization of behavior. The model is based on a novel "iterant deformable sensorimotor medium (IDSM)," designed such that trajectories taken through sensorimotor-space increase the likelihood that in the future, similar trajectories will be taken. We couple the IDSM to sensors and motors of a simulated robot, and show that under certain conditions, the IDSM conditions, the IDSM forms self-maintaining patterns of activity that operate across the IDSM, the robot's body, and the environment. We present various environments and the resulting habits that form in them. The model acts as an abstraction of habits at a much needed sensorimotor "meso-scale" between microscopic neuron-based models and macroscopic descriptions of behavior. Finally, we discuss how this model and extensions of it can help us understand aspects of behavioral self-organization, historicity and autonomy that remain out of the scope of contemporary representationalist frameworks.

Design and implementation of a cloud computing adoption decision tool: Generating a cloud road

Migrating to cloud computing is one of the current enterprise challenges. This technology provides a new paradigm based on "on-demand payment" for information and communication technologies. In this sense, the small and medium enterprise is supposed to be the most interested, since initial investments are avoided and the technology allows gradual implementation. However, even if the characteristics and capacities have been widely discussed, entry into the cloud is still lacking in terms of practical, real frameworks. This paper aims at filling this gap, presenting a real tool already implemented and tested, which can be used as a cloud computing adoption decision tool. This tool uses diagnosis based on specific questions to gather the required information and subsequently provide the user with valuable information to deploy the business within the cloud, specifically in the form of Software as a Service (SaaS) solutions. This information allows the decision makers to generate their particular Cloud Road. A pilot study has been carried out with enterprises at a local level with a two-fold objective: To ascertain the degree of knowledge on cloud computing and to identify the most interesting business areas and their related tools for this technology. As expected, the results show high interest and low knowledge on this subject and the tool presented aims to readdress this mismatch, insofar as possible. Copyright: © 2015 Bildosola et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

A genealogical map of the concept of habit

The notion of information processing has dominated the study of the mind for over six decades. However, before the advent of cognitivism, one of the most prominent theoretical ideas was that of Habit. This is a concept with a rich and complex history, which is again starting to awaken interest, following recent embodied, enactive critiques of computationalist frameworks. We offer here a very brief history of the concept of habit in the form of a genealogical network-map. This serves to provide an overview of the richness of this notion and as a guide for further re-appraisal. We identify 77 thinkers and their influences, and group them into seven schools of thought. Two major trends can be distinguished. One is the associationist trend, starting with the work of Locke and Hume, developed by Hartley, Bain, and Mill to be later absorbed into behaviorism through pioneering animal psychologists (Morgan and Thorndike). This tradition conceived of habits atomistically and as automatisms (a conception later debunked by cognitivism). Another historical trend we have called organicism inherits the legacy of Aristotle and develops along German idealism, French spiritualism, pragmatism, and phenomenology. It feeds into the work of continental psychologists in the early 20th century, influencing important figures such as Merleau-Ponty, Piaget, and Gibson. But it has not yet been taken up by mainstream cognitive neuroscience and psychology. Habits, in this tradition, are seen as ecological, self-organizing structures that relate to a web of predispositions and plastic dependencies both in the agent and in the environment. In addition, they are not conceptualized in opposition to rational, volitional processes, but as transversing a continuum from reflective to embodied intentionality. These are properties that make habit a particularly attractive idea for embodied, enactive perspectives, which can now re-evaluate it in light of dynamical systems theory and complexity research.

Análisis de marcos de trabajo para la gestión de la calidad de negocio (QoBiz) en el ámbito de las telecomunicaciones.

[ES]Este trabajo fin de grado se presenta un estudio y análisis de marcos de trabajo para la gestión de la calidad de negocio (QoBiz) en el ámbito de las telecomunicaciones. Este estudio es una propuesta para unificar las ventajas de los distintos marcos con el objetivo de definir un único marco que permita gestionar la calidad de negocio de forma sencilla y óptima. Para ello, en primer lugar, se desarrollará un análisis de varios estándares empleados hoy en día en el mundo empresarial. Se explicará el funcionamiento de cada uno de ellos, sus ventajas frente a otros y los procesos más generales e importantes para poder aplicarse en escenarios reales. Una vez finalizado el análisis, se tomarán los procesos más importantes de cada marco y se procederá a la creación de un nuevo modelo, a partir del eTOM, con una visión amplia y completa de los diferentes aspectos que afectan a la gestión de la calidad de negocio.

SupraMOFs: Supramolecular porous materials assembled from metal-nucleobase discrete entities

289 p.