Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs


Autoria(s): Fidalgo Marijuan, Arkaitz; Amayuelas López, Eder; Barandika Argoitia, Miren Gotzone; Bazán Blau, Begoña del Pilar; Urtiaga Greaves, Miren Karmele; Arriortua Marcaida, María Isabel
Data(s)

20/10/2015

20/10/2015

15/04/2015

Resumo

Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities.

Identificador

Molecules 20 : 6683-6699 (2015) // Special Issue: Metal-Organic Frameworks: Chemistry and Applications

1420-3049

http://hdl.handle.net/10810/15951

Idioma(s)

eng

Publicador

MDPI (Multidisciplinary Digital Publishing Institute) Basel, Switzerland

Relação

http://www.mdpi.com/1420-3049/20/4/6683

Direitos

© 2015 by the authors; licensee MDPI, Basel, Switz erland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).

info:eu-repo/semantics/openAccess

Palavras-Chave #metalloporphyrin #solid coordination frameworks (SCFs) #crystal struture #dimensionality
Tipo

info:eu-repo/semantics/article