Cis-trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
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| Data(s) |
14/10/2013
14/10/2013
2012
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| Resumo |
The cis to trans isomerizations during the syntheses of trans-[Ru(NO)(OH)(cyclam)](PF6)(2), from cis-[RuCl2 (cyclam)]Cl, and [Ru(NO)Cl(cyclam)] (PF6)(2), from cis-[RuCl2(dmso)(4)], are reported. The novel trans-[Ru(NO) (OH)(cyclam)](PF6)(2) complex was characterized by X-ray crystallography and vibrational infrared and nuclear magnetic resonance spectroscopies. The Ru-N-O bond angle (176.75 degrees) and v( NO) (1835 cm(-1)) suggest a nitrosonium character for this hydroxo complex. The crystal and molecular structure of trans-[Ru(NO)Cl(cyclam)] (ClO4)(2)center dot 2 H2O is also reported. Results presented here support the cis-trans isomerization observed for the first time with ruthenium cyclam complexes. (C) 2011 Elsevier B.V. All rights reserved. Fapesp [2006/53266-4] FAPESP CNPq CNPq CAPES CAPES Fapesb FAPESB |
| Identificador |
INORGANIC CHEMISTRY COMMUNICATIONS, AMSTERDAM, v. 15, n. 5, supl. 4, Part 1-2, pp. 93-96, JAN, 2012 1387-7003 http://www.producao.usp.br/handle/BDPI/34546 10.1016/j.inoche.2011.09.046 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE BV AMSTERDAM |
| Relação |
INORGANIC CHEMISTRY COMMUNICATIONS |
| Direitos |
closedAccess Copyright ELSEVIER SCIENCE BV |
| Palavras-Chave | #RUTHENIUM #CYCLAM #NITROSYL #NITRIC OXIDE #CIS-TRANS ISOMERIZATION #NITRITE #1,4,8,11-TETRAAZACYCLOTETRADECANE CYCLAM #MACROCYCLIC COMPLEXES #MOLECULAR-STRUCTURE #NITROSYL COMPLEXES #PENDANT-ARM #MECHANISM #CRYSTAL #NO #KINETICS #AMINE #CHEMISTRY, INORGANIC & NUCLEAR |
| Tipo |
article original article publishedVersion |
