PMo12-doped carbon ceramic composite electrode based on sol-gel chemistry and its electrocatalytic reduction of bromate
Data(s) |
2000
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Resumo |
A conductive carbon ceramic composite electrode (CCE) comprised of cc-type 1:12 phosphomolybdic acid (PMo12) and carbon powder in an organically modified silicate matrix was fabricated using a sol-gel method and characterized by scanning electron microscopy, cyclic voltammetry, and Osteryoung square-wave voltammetry. Osteryoung square-wave voltammograms of the modified electrode immersed in different acidic aqueous solutions present the dependence of current and redox potential on pH. The PMo12-doped CCE shows more reversible reaction kinetics, good stability and reproducibility, especially the renewal repeatability by simple polishing in the event of surface fouling or dopant leaching. Moreover, the modified electrode shows good catalytic activity for the electrochemical reduction of bromate. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Wang P;Wang XP;Zhu GY .PMo12-doped carbon ceramic composite electrode based on sol-gel chemistry and its electrocatalytic reduction of bromate,ELECTROANALYSIS,2000,12(18):1493-1497 |
Palavras-Chave | #FILM-MODIFIED MICROELECTRODES #KEGGIN-TYPE HETEROPOLYANIONS #12-MOLYBDOPHOSPHORIC ACID #OXIDATION #SURFACE #OXIDE #ELECTROCHEMISTRY #POLYPYRROLE #FABRICATION #MONOLAYERS |
Tipo |
期刊论文 |