Detection of C8H- and Comparison with C8H toward IRC+10216

We report the detection of new transitions of octatetraynyl (C8H) toward the circumstellar envelope IRC +10 216 using data taken with the 100 m Green Bank Telescope (GBT). In addition, we report five features from the Ku, K, and Q bands that have been identified as transitions of the octatetraynyl anion (C8H-). From a rotational temperature diagram and an assumed source size of 30", we find a total C8H column density of 8(3)×10^12 cm-2 and a rotational temperature of ~13 K. From the five detected transitions of C8H-, we find a total C8H- column density of ~2.1×10^12 cm-2 consistent with a rotational temperature of ~34 K for a total C8H/C8H- column density ratio of ~3.8. This observed C8H/C8H- column density ratio is similar to the theoretical prediction of 3.6, while the observed column densities were lower than that predicted by a factor of ~30. This prompted us to reinvestigate the initial conditions of the circumstellar envelope (CSE) model. The new model results are presented, and they more closely match the C8H and C8H- abundances observed with the GBT. Finally, we use the new CSE model results to predict the abundance of decapentaynyl (C10H), and we compare them with the measured upper limit found from the GBT observations.

Density-Enhanced Gas and Dust Shells in a New Chemical Model for IRC+10216

A new chemical model is presented for the carbon-rich circumstellar envelope (CSE) of the asymptotic giant branch star IRC+10216. The model includes shells of matter with densities that are enhanced relative to the surrounding circumstellar medium. The chemical model uses an updated reaction network including reactions from the RATE06 database and a more detailed anion chemistry. In particular, new mechanisms are considered for the formation of CN-, C3N-, and C2H-, and for the reactions of hydrocarbon anions with atomic nitrogen and with the most abundant cations in the CSE. New reactions involving H- are included which result in the production of significant amounts of C2H- and CN- in the inner envelope. The calculated radial molecular abundance profiles for the hydrocarbons C2H, C4H, and C6H and the cyanopolyynes HC3N and HC5N show narrow peaks which are in better agreement with observations than previous models. Thus, the narrow rings observed in molecular microwave emission surrounding IRC+10216 are interpreted as arising in regions of the envelope where the gas and dust densities are greater than the surrounding circumstellar medium. Our models show that CN- and C2H- may be detectable in IRC+10216 despite the very low theorized radiative electron attachment rates of their parent neutral species. We also show that magnesium isocyanide (MgNC) can be formed in the outer envelope through radiative association involving Mg+ and the cyanopolyyne species.

Large molecules in the envelope surrounding IRC+10216

A new chemical model of the circumstellar envelope surrounding the carbon-rich star IRC+10216 is developed that includes carbon-containing molecules with up to 23 carbon atoms. The model consists of 3851 reactions involving 407 gas-phase species. Sizeable abundances of a variety of large molecules - including carbon clusters, unsaturated hydrocarbons and cyanopolyynes - have been calculated. Negative molecular ions of chemical formulae C-n(-) and CnH- (7 less than or equal to n less than or equal to 23) exist in considerable abundance, with peak concentrations at distances from the central star somewhat greater than their neutral counterparts. The negative ions might be detected in radio emission, or even in the optical absorption of background field stars. The calculated radial distributions of the carbon-chain CnH radicals are looked at carefully and compared with interferometric observations.

A NEW CHEMICAL-MODEL OF THE CIRCUMSTELLAR ENVELOPE SURROUNDING IRC+10216

A new chemical model of the circumstellar envelope surrounding the carbon-rich star IRC+10216 has been developed. This model incorporates a variety of newly measured rapid neutral-neutral reactions between carbon atoms and hydrocarbons and between the radical CN and a variety of stable neutral molecules. In addition, other neutral-neutral reactions in the above two classes or involving atoms such as N or radicals such as C(2n)H have been included with large rate coefficients although they have not yet been studied in the laboratory. Unlike the interstellar case, where the inclusion of these neutral-neutral reactions destroys molecular complexity, our model results for IRC+10216 show that sufficient abundances of large hydrocarbon radicals and cyanpolyynes can be produced to explain observations. We also discuss the formation of H2CN and NH2CN, two potentially observable molecules in IRC+10216.

Uso didáctico del IRC (Internet Relay Chat) en la formación inicial del profesorado.

El IRC (Internet Relay chat) es un recurso que nos brinda Internet. Aunque habitualmente se convierta en un medio a través del cual poder mantener una conversación informal entre personas de cualquier lugar del mundo, también se puede convertir en una herramienta con potencialidades didácticas muy interesantes. la formación inicial del profesorado exige, actualmente, una formación en el conocimiento y uso de los recursos que aportan las nuevas tecnologías de la información y la comunicación. El IRC es uno de ellos, y es necesario que los estudiantes de magisterio tengan oportunidad de conocerlo y experimentarlo desarrollando actividades que les puedan resultar significativas dentro de su proceso de formación. La experiencia se desarrolló en Girona durante el curso 1997-1998. El actual currículum de los estudios de Magisterio incluye la asignatura 'Nuevas tecnologías aplicadas a la Educación', en cuyo marco se desarrolló a lo largo del curso 1997-1998, una serie de actividades que tenían como objetivo conseguir que el alumnado conociese y experimentase ese medio de comunicación en un contexto educativo significativo para ellos..

Nuevas tecnologías : una experiencia de chat en Inglés : IRC English chat.

Comunicación en la que se comenta la experiencia de un chat por IRC de Inglés, actividad celebrada dentro de la 'I Maratón de Alfabetización Tecnológica' que se ha desarrollado en Extremadura. Los participantes fueron estudiantes y profesores de ESO, Bachillerato, Escuelas Oficiales de Idiomas, Diplomados y Licenciados en Lengua Inglesa y hablantes nativos. El objetivo de la actividad fue que las personas residentes en Extremadura, con el interés de practicar Inglés, se conociesen y organizasen grupos para conversar en Inglés aprovechando las nuevas tecnologías teniendo en cuenta el nivel de cada participante.

Linguistic innovations in IRC: Cypriot-Greek phonological features

The Cypriot Greek variety (CG), spoken in the island of Cyprus, is relatively distinct from Standard Greek (SG) in all linguistic domains and, especially, in the area of pronunciation. Youth language, within the Greek-Cypriot context, is an area of study that has, until recently, received little attention. Tsiplakou (2004) makes reference to the emergence of a new slang among young Greek-Cypriots, influenced by new comedy series, in which the actors make extensive use of ‘exaggeratedly peasant’ CG. As these comedy series become increasingly popular, the use of marked regional features becomes evident in the speech style of young Greek-Cypriots. A preliminary study has also revealed that marked CG linguistic features are equally evident in the online interactions of young internet users (Themistocleous 2005). In this study, I examine the use of CG phonological elements in a corpus of messages collected from channel #Cyprus, of Internet Relay Chat (IRC). It is demonstrated that young Greek-Cypriots use language in creative ways, in order to represent in writing phonological features, typical of their informal speech.

Comunidades virtuais no IRC : o caso do #Pelotas - um estudo sobre a comunicação mediada por computador e a estruturação de comunidades virtuais

Neste trabalho procuramos observar uma comunidade virtual no IRC (Internet Relay Chat), o canal #Pelotas. A partir de seu estudo, sob o viés da Grounded Theory, procuramos construir categorias básicas sobre diversos aspectos encontrados na comunidade, tais como questões de identidade, gênero e as próprias relações e convenções sociais. Ao mesmo tempo, procuramos construir um conceito de comunidade virtual que abarque nosso entendimento e os resultados da pesquisa empírica. Deste modo, sob vários aspectos, é possível analisar uma comunidade virtual, e principalmente, o modo sobre o qual ela se estrutura através da Comunicação Mediada por Computador.