Aditivo polimérico derivado de fonte renovável para aplicação em cimento asfáltico de petróleo

This study evaluated the effects of incorporating an additive from an agro-industrial residue, after some chemical modification reactions, to petroleum asphalt cement (CAP) through the polymerization reaction of a viscous polyol obtained by bagasse biomass oxypropylation reaction sugarcane with anhydrides. The polyol is obtained by biomass oxypropylation reaction with propylene oxide, the reaction was performed in an autoclave sealed with pressure and temperature control using 25 mL of OP for every 5 grams of biomass 200°C, which time reaction was two hours. The reaction is revealed by varying the system pressure, initially at atmospheric pressure to reach a maximum pressure value and its subsequent return to atmospheric pressure. For the choice of the most suitable reaction time for polymerization of the polyol with pyromellitic anhydride, the reaction was also conducted in an autoclave sealed with temperature controller (150 ° C) using 20 g of polyol, 1 g of sodium acetate (catalyst) and 8 g of pyromellitic anhydride with the times 30 and 60 minutes. The polymerized materials with different times were characterized by determining the relative viscosity and percentage content of extractable in cyclohexane / ethanol. Given the results with the polymerized material 30 minutes showed the lowest percentage content of extractives and an increased viscosity relative indicating that this time is highlighted with respect to time 60 minutes, because the material is possibly in the form of a crosslinked polymer. Given the choice of time of 30 minutes other polymerization reactions were performed with various anhydrides and other conditions employed different proportions by mass of polyol anhydrides we were referred to as condition I (20 g anhydride and 8 g of polyol), II (20 g anhydride and 20 g of polyol) and III (8 g anhydride and 20 g of polyol). The FTIR spectra of polymeric materials with different polymerization conditions used to prove the occurrence of chemical modification due to the appearance of a characteristic band ester groups (1750 cm-1) present in the polymerized material. He chose to work with the condition III, as is the condition which employs a larger amount of polyol, and even with the smaller amount of anhydride used FTIR spectra revealed that the polymerization reaction was performed. Among the various anhydrides (phthalic, maleic and pyromellitic) of the different conditions used that stood out before the solubility test with solvents analyzed was polymerized material with pyromellitic anhydride because the polymerized material likely in the form of a crosslinked polymer because it was insoluble or poorly soluble in the solvents tested. Polymerization of the polyol with pyromellitic anhydride using condition III, that is, BCPP30, CSPP30, PCPP30 e BCPPG30, provided an increase in thermal stability relative to material in the form of polyol. Applicability tests concerning the incorporation of 16% m / m BCPP30, CSPP30, PCPP30 e BCPPG30 additive in relation to the mass of 600 g CAP showed through characterization tests used, softening point, elastic recovery and marshall dosage, it is possible to use BCPP30 as an additive the conventional CAP, because even with the incorporation of this new additive modified CAP met the specifications of the appropriate standard.

Efeito da irrigacao e adubacao sobre algumas caracteristicas quimicas de um vertissolo.

Em um Vertissolo, cultivado com videira, avaliou-se o efeito da irrigacao e da adubacao NPK aplicadas naulamente, durante 17 anos, sobre algumas caracteristicas quimicas do solo. O sistema de irrigacao foi em bacia de infiltracao, onde tambem foram aplicados os fertilizantes e incorporados ao solo ate a profundidade de 5 cm. A amostragem do solo foi feite em 18 pontos da area cultivada e em sete pontos da area de solo virgem, em torno do parreiral, as profundidades de 0-15 cm, 15-30 cm, 30-60 cm, 60-90 cm e 90-120 cm. Os resultados analiticos mostraram que praticamente nao ocorreram variacoes perceptiveis nos teores de Ca2+, Mg2+ e Na+ trocaveis, materia organica, N-HN4+ e Zn, em relacao ao solo virgem, em resposta aos tratamentos. Quanto aos outros parametros, constatou-se que nas camadas superiores houve diminuicao do pH e aumento da condutividade eletrica (CEe) e dos teores de K+ trocavel, P, N total, N-NO3-, Cu, Mn e Fe. Estas diferencas, com excecao do Fe, diminuiram com a profundidade. Teores mais elevados de Cu e Mn devem ter sido consequencia da aplicacao anual de fungicidas e da solubilizacao de compostos contendo estes elementos. Os resultados obtidos indicaram que as variacoes ocorridas em alguns parametros, decorrentes da irrigacao e aplicacao de fertilizantes, principalmente aquelas relacionadas com o aumento da salinidade, nao devem comprometer a capacidade produtiva do solo.

Características químicas de las principales especies marinas para consumo humano

Comprende las variaciones estacionales de la composición química de las principales especies marinas para consumo humano: merluza, sardina, machete, jurel y caballa. Así como también las técnicas desarrolladas para evaluar el grado de frescura desde el punto de vista químico.

Características químicas y de clorofila A del mar peruano durante el otoño 1998. Crucero BIC Humboldt 9803-05 de Tumbes a Tacna

Informan los resultados de las observaciones sobre oxígeno, nutrientes y clorofila "a" en 415 estaciones oceanográficas y 145 calas de pesca realizadas durante marzo a mayo de 1998 frente a la costa peruana. La distribución de los parámetros químicos en la superficie de mar mostró condiciones anómalas para la época, pero que corresponden de los eventos cálidos. Los nutrientes inorgánicos disueltos indicaron en el norte, centro y sur, predominio de valores pobres en la superficie del mar (<0,5 ug-at/L fosfatos, <5 ug-at/L silicatos, <5 ug-at/L nitratos y <0.25 ug-at/L nitritos) hasta los 50 m de profundidad. Pequeños núcleos de nutrientes con concentraciones mayores (5-15 ug-at/L) se hallaron frente a Chimbote-Huarmey, Punta Doña María-San Juan y Atico Mollendo dentro de 30 millas, asociados a bajas temperaturas, salinidades de 35% y concentraciones de oxígeno menores de 4 mL/L, indicando afloramiento costero. La biomasa fitoplanctónica en términos de clorofila "a" presentó núcleos con concentraciones altas (9,61 - 2,40 ug/L) cerca de la costa frente a Caleta La Cruz-Punta Falsa en una banda costera de 10 millas.

Drenagem subterranea no Perimetro Irrigado de Manicoba: criterios de dimensionamento e avaliacao de performance.

Os trabalhos foram conduzidos num sistema de drenagem subterranea entubado (1,5 ha), instalado nos solos classe 3 do P.I. de Manicoba, BA, para observar a aplicabilidade das equacoes de escapamento de drenos usados, conferir alguns parametros hidrologicos dos solos e ajustar parametros de dimensionamento. Foram consederadas variaveis o espacamento entre drenos e uma combinacao de materiais de envoltura. O espacamento de drenagem foi calculado baseado em parametros determinados "in loco" e usando as equacoes de Hooghoudt e Glover e Dumm. O duplo do espacamento calculado foi considerado como variacao deste parametro. As variacoes do lencol freatico e as vazoes dos drenos como resposta as recargas de irrigacao superficial (sulcos) e chuvas foram levantadas para drenose espacados 15 e 30m , acompanhando os regimes de umidade do perfil do solo. Assim mesmo, foram determinadas, em analise de laboratorio, as caracteristicas quimicas e a quantidade de sedimentos das aguas de drenagem. Resultados do estudo mostraram que o espacamento calculado manteve melhor regime de umidade no perfil do solo. A descarga maxima instantanea dos drenos e de 8 a 10 mm/d, caindo a 4 mm/d ou menos no terceiro dia apos a recarga. O lencol freatico manteve entre 0,6 e 1,0 m embaixo da superficie na area com L = 30 e entre 1,2 e 1,50 na area com L = 15 m. Demonstrou-se a contribuicao desprezivel da camada embaixo dos drenos ao fluxo subterraneo, e a precisao do metodo do furo de trato (auger hole) na determinacao da condutividade hidraulica.(...).

ANÁLISE DAS CARACTERISTICAS FÍSICAS E QUIMICAS DA ÁGUA DO RIO DOCE A MONTANTE DA PEQUENA CENTRAL HIDROELÉCTRICA DE IRARA – GO

O presente trabalho objetivou avaliar as características físicas e químicas das águas do rio Doce (GO), a montante da PCH Irara. Foram realizadas seis amostragens bimestrais em cinco pontos de coleta, no período de julho/09 a junho/10 para variáveis: pH, temperatura, condutividade elétrica, salinidade, turbidez e total de sólido dissolvido. As características físicas e químicas observadas evidenciaram uma boa qualidade da água do rio Doce, considerando-se os padrões Resolução CONAMA N0 357, de 17 de março de 2005.

Estudo do comportamento de um solo residual melhorado atraves de tecnicas mecanicas e fisico-quimicas e sua aplicacao a analise de fundacoes superficiais

O presente trabalho tem como objetivo estudar o comportamento de um solo residual melhorado através do uso de técnicas mecânicas de compactação e da adição de cimento. Complementarmente foram realizadas análises numéricas destes materiais tratados quando utilizados como base de fundações superficiais. O programa experimental incluiu a retirada de amostras intactas e de material amolgado para a execução de ensaios triaxiais saturados drenados com medida interna de deformações, a fim de estudar o comportamento do solo natural e do solo tratado, quer por compactação, quer por adição de cimento e compactação. Além disto, tais ensaios são determinantes na obtenção de parâmetros constitutivos para a realização de simulações numéricas. O Método dos Elementos Finitos foi utilizado para simular o comportamento carga versus recalque de placas assentes sobre o solo natural e sobre camadas de solo melhorado. O modelo Hiperbólico foi empregado na análise numérica para modelar o comportamento tensãodeformação dos materiais. Os resultados das simulações dos ensaios de placa sobre camadas de solo melhorado demonstraram que houve um aumento significativo da capacidade de suporte, além de uma redução considerável dos recalques, quando comparados ao comportamento do solo natural.

Características físicas e mecânicas de misturas de solo, cimento e cinzas de bagaço de cana-de-açúcar

This work was done with the objective of studying some physical and mechanical characteristics of the sugarcane bagasse ash added to a soil-cement mixture, in order to obtain an alternative construction material. The sugarcane bagasse ash pre-treatment included both sieving and grinding, before mixing with soil and cement. Different proportions of cement-ash were tested by determining its standard consistence and its compressive resistance at 7 and 28 days age. The various treatments were subsequently applied to the specimens molded with different soil-cement-ash mixtures which in turns were submitted to compaction, unconfined compression and water absorption laboratory tests. The results showed that it is possible to replace up to 20% of Portland cement by sugarcane bagasse ash without any damage to the mixture's compressive strength.

Avaliação térmica de placas de argamassa de cimento e casca de arroz aquecidas por resistência elétrica

An alternative proposal for floor heating system by means of electric resistance for both chick and piggy installation is presented in this work. Several formulations of rice husk and cement mortar boards were used. An electronic device controlled all board temperature. This system presented a good efficiency design. The conventional cement mortar mixed with rice husk showed a better performance.

Características físicas e mecânicas de misturas de solo, cimento e casca de arroz

The main objective of this work is the study of the effect of rice husk addition on the physical and mechanical properties of soil-cement, in order to obtain an alternative construction material. The rice husk preparation consisted of grinding, sieving, and the pre-treatment with lime solution. The physical characteristics of the soil and of the rice husk were determined. Different amounts of soil, cement and rice husk were tested by compaction and unconfined compression. The specimens molded according to the treatments applied to the mixtures were subsequently submitted to compression testing and to tensile splitting cylinder testing at 7 and 28 days of age and to water absorption testing. After determining its physical and mechanical characteristics, the best results were obtained for the soil + 12% (cement + rice husk) mixture. The results showed a promising use as an alternative construction material.

Durabilidade de compósito biomassa vegetal-cimento modificado por polímero

The durability of the cellulose-cement composites is a decisive factor to introduce such material in the market. Polymers have been used in concrete and mortar production to increase its durability. The goal of this work was the physical and mechanical characterization of cellulose-cement composites modified by a polymer and the subsequent durability evaluation. The work also evaluated the dispersion of acrylic polymer in composites made of Pinus caribaea residues. The physical properties observed were water absorption by immersion and bulk density. Rupture modulus and toughness were determined by flexural test. The specimens were obtained from pads, produced by pressing and wet curing. Samples were subjected to accelerated aging tests by repeated wetting and drying cycles and hot-water bath and natural aging. The scanning electron microscopy (SEM) allowed verifying the fiber and composite characteristics along the time. For the composite range analyzed, it was observed the polymer improved the mechanical properties of composites besides a significant decreasing in water absorption. The use of polymer improved the performance of vegetable fiber-cement composites when compared to the conventional mortar, due to water absorption decreasing.

Efeito da adição de cinza da casca de arroz em misturas cimento-casca de arroz

The rice husk and its ash are abundant and renewable and can be used to obtain alternative building materials. An increase in the consumption of such waste could help minimize the environmental problems from their improper disposal. This study aimed to evaluate the use of ashes as a cargo mineral (filler). However, the rice husk chemically interferes in the conduct of the based cement mixtures. Thus, different mixes cement-rice husk with and without the addition of ash were evaluated in order to highlight the influence of its components (husk; ash), which could otherwise be excluded or be underestimated. Cylindrical samples (test of simple compression and traction by diametrical compression) and samples extracted from manufactured pressed board (test of bending and parallel compression to the surface), were used to evaluate the behavior of different mixtures of components (rice hush; RHA - rice husk ahs). The results of the mechanical tests showed, in general, there is not a statistical difference between the mixtures, which are associated with the chemical suppressive effect of the rice husk ash. The mixture of rice husk of 10 mm, with an addition of 35% of the rice husk ash, is notable for allowing the highest consumption of rice husk and rice husk ash, to reduce 25% the consumption of cement and to allow the storage (without emissions to the atmosphere), around 1.9 ton of CO2 per ton of cement consumed, thus contributing to the reduction of CO2 emissions, which can stimulate rural constructions under an ecological point of view.

Caracterização física e mecânica de argamassas à base de cimento Portland e cinza de casca de arroz residual

Rice husk, employed as an energy source at milling industries in Brazil generates, after burning, a dark ash. This residue is not yet conveniently disposed, being currently dumped on large areas, causing environmental problems. This research intended to evaluate the applications of residual rice husk ashes (RHA) as a partial replacement of cement for mortar production. Rice husk ash was chemically characterized through X-ray fluorescence, determination of carbon content, X-ray diffraction, and laser granulometric analysis. Mortar specimens were submitted to two different exposure conditions: internal and external environments at a maximum period of five months. Physical-mechanical testing were compressive strength and ultrasonic pulse velocity (UPV). Although presenting good mechanical performance, the mortar based on ash (RHA) did not present pozolanicity but it can be employed in cement matrices as inert material (filler).

Analise comparativa das caracteristicas cinematicas da coluna durante a marcha e a corrida

Universidade Estadual de Campinas . Faculdade de Educação Física

Basquetebol masculino paulista : apropriação das caracteristicas do esporte profissional na estrutura organizacional das categorias de base

Universidade Estadual de Campinas . Faculdade de Educação Física