Projeto Chile: um elo ativo na Revolução Passiva

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Synthesis of palladium nanoparticles over graphite oxide and carbon nanotubes by reduction in ethylene glycol and their catalytic performance on the chemoselective hydrogenation of para-chloronitrobenzene

Pd nanoparticles have been synthesized over carbon nanotubes (CNT) and graphite oxide (GO) by reduction with ethylene glycol and by conventional impregnation method. The catalysts were tested on the chemoselective hydrogenation of p-chloronitrobenzene and the effect of the synthesis method and surface chemistry on their catalytic performance was evaluated. The catalysts were characterized by N2 adsorption/desorption isotherms at 77 K, TEM, powder X-ray diffraction, thermogravimetry, infrared and X-ray photoelectron spectroscopy and ICP-OES. It was observed that the synthesis of Pd nanoparticles employing ethylene glycol resulted in metallic palladium particles of smaller size compared to those prepared by the impregnation method and similar for both supports. The presence of oxygen groups on the support surface favored the activity and diminished the selectivity. It seems that ethylene glycol reacted with the surface groups of GO, this favoring the selectivity. The activity was higher over the CNT-based catalysts and both catalysts prepared by reduction in ethylene glycol were quite stable upon recycling.

Synthesis of palladium nanoparticles on carbon nanotubes and graphene for the chemoselective hydrogenation of para-chloronitrobenzene

We have studied the synthesis of palladium nanoparticles over carbon nanotubes (Pd/CNT) and graphene (Pd/G) and we have tested their catalytic performance in the liquid phase chemoselective hydrogenation of para-chloronitrobenzene at room temperature. The catalysts were characterized by N2 adsorption/desorption isotherms, TEM, X-ray diffraction, infrared and X-ray photoelectron spectroscopy and ICP-OES. The palladium particle size on Pd/G (3.4 nm) and Pd/CNT (2.8 nm) was similar though the deposition was higher on Pd/G. Pd/CNT was more active which can be ascribed to the different surface area and electronic properties of the Pd nanoparticles over CNT, while the selectivity was 100% to the corresponding haloaniline over both catalysts and they were quite stable upon recycling.

Huella de carbono de vivienda y movilidad en Concepción, Chile. Uso del cálculo de huella de carbono para concretar y solucionar problemáticas sociales en barrios desfavorecidos. El caso de Pedro de Valdivia Bajo y Cerro Centinela

En este proyecto se ha calculado la huella de carbono parcial, es decir, únicamente se ha tenido en cuenta la movilidad y la energía usada en la vivienda. Se ha aplicado la metodología creada por Mathis Wackernagel y William Rees en 1997 para el cálculo de la huella ecológica. Diferentes barrios distribuidos a distintas distancias del CBD (Central Business District) de Concepción (Chile), han sido los objetos de estudio de la Huella de Carbono y en concreto se ha focalizado la atención en dos barrios de bajas rentas (Cerro Centinela y Pedro de Valdivia Bajo). En ellos se ha propuesto mejoras tanto ecológicas como sociales para aumentar la calidad de vida de los vecinos.

INCLUDING RISK IN ECONOMIC FEASIBILITY ANALYSIS:A STOCHASTIC SIMULATION MODEL FOR BLUEBERRY INVESTMENT DECISIONS IN CHILE

ABSTRACT The traditional method of net present value (NPV) to analyze the economic profitability of an investment (based on a deterministic approach) does not adequately represent the implicit risk associated with different but correlated input variables. Using a stochastic simulation approach for evaluating the profitability of blueberry (Vaccinium corymbosum L.) production in Chile, the objective of this study is to illustrate the complexity of including risk in economic feasibility analysis when the project is subject to several but correlated risks. The results of the simulation analysis suggest that the non-inclusion of the intratemporal correlation between input variables underestimate the risk associated with investment decisions. The methodological contribution of this study illustrates the complexity of the interrelationships between uncertain variables and their impact on the convenience of carrying out this type of business in Chile. The steps for the analysis of economic viability were: First, adjusted probability distributions for stochastic input variables (SIV) were simulated and validated. Second, the random values of SIV were used to calculate random values of variables such as production, revenues, costs, depreciation, taxes and net cash flows. Third, the complete stochastic model was simulated with 10,000 iterations using random values for SIV. This result gave information to estimate the probability distributions of the stochastic output variables (SOV) such as the net present value, internal rate of return, value at risk, average cost of production, contribution margin and return on capital. Fourth, the complete stochastic model simulation results were used to analyze alternative scenarios and provide the results to decision makers in the form of probabilities, probability distributions, and for the SOV probabilistic forecasts. The main conclusion shown that this project is a profitable alternative investment in fruit trees in Chile.

Constituting "Community" at the onset of the Pascua Lama Mining Project

Mémoire numérisé par la Division de la gestion de documents et des archives de l'Université de Montréal.

Plataforma Tecnológica Colaborativa Comunidad de Negocios San Antonio, Chile, red de aprovisionamiento local: OpenSupply

El proyecto que se quiere plantear es la creación de una Plataforma electrónica a través de la cual se pretende agrupar a los diferentes proveedores que intervienen en la cadena de abastecimiento de la comunidad logística de San Antonio, abriendo la posibilidad de participación de empresas grandes y pequeñas y más aun promoviendo la creación de las mismas por parte de los ciudadanos de la región, de esta manera, se eliminan las brechas asimétricas existentes entre la oferta y la demanda permitiendo que las empresas medianas y grandes accedan a ofertas y transacciones con empresas proveedoras medianas y pequeñas. Dicho proyecto, tiene como objetivo general el consolidar los procesos de abastecimiento implementados por las empresas a través de la organización y estandarización de los mismos mediante el uso del portal, planteado en el presente proyecto, como apoyo tecnológico. Existen dos conceptos básicos a analizar de manera teórica dentro del proyecto, el primero de ellos es el de clúster logístico-portuario, lo cuales son reconocidos como instrumentos importantes para el progreso del desarrollo industrial, innovación, competitividad y crecimiento, tomando como ejemplos a los puertos de Valencia y Long Beach en la ciudad de Los Ángeles. El segundo concepto es el de E-Procurement, el cual se desarrolla siguiendo los pasos básicos de una cadena de abastecimiento tradicional, sin embargo, lo que genera un cambio real dentro de los procesos es el hecho que los procesos de cotización y seguimiento de proveedores se van a llevar a cabo a través de una plataforma electrónica con base a las evaluaciones que se llevan a cabo por parte de las empresas demandantes de los productos o servicios ofrecidos por las compañías proveedoras. (Renko, 2011) De la misma manera, se tomaran varios proyectos de e-procurement desarrollados a nivel mundial como base comparativa y de apoyo para el presente proyecto tales como: HYDRA: Es un sistema que tiene su soporte en la web, el cual es orientado “en el medio” lo cual lo hace un sistema con una arquitectura híbrida, que posee tanto un diseño en capas como una estructura comprensiva para desarrollar integración de negocios, colaboración y monitoreo en la gestión de la cadena de suministro (Renko, 2011) IPT: BidNet ha proporcionado servicios de oferta de información a miles de proveedores y compradores de bienes en el ámbito gubernamental por más de 25 años. (Bidnet, 2013) E-BUYPLACE: E-buyplace.com es el 1° especialista en SupplierRelationship Management que ha desarrollado un original y singular SRM 100% a través de Internet. (e-buyplace, 2013) RosettaNet: La iniciativa RosettaNet anima a optimizar los procesos de la cadena de suministro mediante el establecimiento, implementación y promoción de estándares abiertos en el mercado e-Business (AQS, Advance Quality Solutions, 2002)

Análisis y oportunidades comerciales entre las repúblicas de Colombia y Chile

Como consecuencia de las relaciones establecidas entre Colombia y Chile se busca analizar las relaciones comerciales, el impacto que tuvo la puesta en marcha del TLC y la identificación de oportunidades para los colombianos en ese mercado.

Observatorio del acuerdo comercial alianza pacífico en Colombia: oportunidades de exportación para Colombia a Chile, México y Perú

El desarrollo del presente proyecto de investigación, identifica, consolida, analiza datos económicos y el comportamiento del comercio exterior de Colombia, Chile, Perú y México dentro de la evolución del Acuerdo Alianza Pacífico durante los años 2011 - 2013. El estudio permitirá tener una visión más concreta, sobre la viabilidad que este bloque comercial representa para Colombia y mostrará cual ha sido el desempeño del país dentro del acuerdo con base a las exportaciones e importaciones efectuadas con los demás países miembros de la alianza. A lo largo del estudio, se analizará la balanza comercial de los treinta y dos (32) departamentos colombianos con los países miembros del acuerdo Alianza del Pacifico (Chile, México y Perú) entre 2011 – 2013. A partir de la obtención y análisis de resultados de tipo cuantitativo y cualitativo como el valor las exportaciones e importaciones, se hace un diagnóstico del comportamiento de la comercialización de productos por parte de los departamentos con destino y desde de Chile, México y Perú. Este análisis nos permitirá identificar cuáles son los bienes de mayor exportación y su participación dentro de las transacciones comerciales del acuerdo Alianza Pacifico. Con base a los datos que se recopilen, será posible analizar la situación y el papel que juega Colombia actualmente dentro del acuerdo y así identificar así las oportunidades, debilidades y posibles consecuencias, producto de la firma de este tratado. Finalmente, con la presente investigación se buscará iniciar el Observatorio del Acuerdo Alianza Pacifico, el cual se creará con fines investigativos, facilitando el seguimiento a la evolución de dicho acuerdo. A través del observatorio se lograra saber cuáles son los comportamientos en materia económica, tales como balanza comercial, inversión extranjera, movilidad, entre otros de este bloque de integración. Adicionalmente, será posible y analizar el comportamiento de los principales sectores económicos y los departamentos involucrados en este proceso, en términos comerciales.

Climate and construction delays: case study in Chile

Purpose – Construction projects usually suffer delays, and the causes of these delays and its cost overruns have been widely discussed, the weather being one of the most recurrent. The purpose of this paper is to analyze the influence of climate on standard construction work activities through a case study. Design/methodology/approach – By studying the extent at which some weather variables impede outdoor work from being effectively executed, new maps and tables for planning for delays are presented. In addition, a real case regarding the construction of several bridges in southern Chile is analyzed. Findings – Few studies have thoroughly addressed the influences of major climatic agents on the most common outdoor construction activities. The method detailed here provides a first approximation for construction planners to assess to what extent construction productivity will be influenced by the climate. Research limitations/implications – Although this study was performed in Chile, the simplified method proposed is entirely transferable to any other country, however, other weather or combinations of weather variables could be needed in other environments or countries. Practical implications – The implications will help reducing the negative social, economic and environmental outcomes that usually emerge from project delays. Originality/value – Climatic data were processed using extremely simple calculations to create a series of quantitative maps and tables that would be useful for any construction planner to decide the best moment of the year to start a project and, if possible, where to build it.

Política de formação docente na América Latina :Argentina, Brasil e Chile

This work aims at studying the policies of teaching training and their impact in the actors and in the education systems of the countries in which these policies were implemented into the context of neoliberal reforms. We particularly studied these policies in three Latin America countries: Argentina, Brazil and Chile. The policies studied here are the ones implemented from the 90 s. However, the horizon of this study is at the beginning of the 80 s, period that starts one of the four intervention initiatives of education here studied: The Main Project of Education For Latin America and Caribbean (PROMEDLAC), which in 2002 goes into a new stage and it is called Regional Project of Education for Latin America and Caribbean (PRELAC), worked out by UNESCO as a request of government representatives of countries of the region, based on the suggestions of Declaration of Mexico , signed by them in 1979. These suggestions will be in the base of the other three initiatives: The Education For All (EPT); Ibero-American Conferences of Education (CIE) and The Hemisphere Action Plan of Education (PAHE), whose documents are the base to the production of an abundant legislation and normatization on education that created the parameters on which the policies of education reforms were worked out and implemented and the dynamism of our education systems from the last two decades of the twentieth century on. All these initiatives intend to work with objectives, projects and programs that, in some cases, in isolation or in groups, are under influence of their actions in a way that frequently it is difficult to identify which of them is the main responsible for some advances. It is important to stand out that not all of the suggestions produced by these initiatives were implemented as policies, and many of them to be implemented were changed in such a way that they were distorted, even they were a result of a multilateral deal, each country gave to them its own interpretation. Moreover, in all these processes the teaching entities had and keep having a fundamental role. The evidences, result of the evaluations of each initiative, show that education policies implemented produced advances in several aspects. They are still not the ideal ones, in truth, but they do exist. In relation to the teaching questions, there were and are still being implemented multiples and varied actions that did not have the expected impact in the education systems of the countries, objects of this study, but, many of them that go on, are promising and start to have a positive impact into the education systems. Even so, the teaching subject matter, even playing a central role in the agenda of all countries of the region, still represents one of the big challenges to the advance and improvement of our education systems

A snapshot of Chile's 20 largest multinational enterprises in 2011: Sustained growth in South America

Includes bibliography

The top 20 multinationals in Chile in 2010: retail, forestry and transport lead the international expansion

Incluye bibliografía

Política comercial de Chile y los TLC con Asia: evaluación de los efectos de los TLC con Japón y China

Incluye Bibliografía

Chile: the Chilean national investment system and projects integrated bank

Includes bibliography