Projeto Chile: um elo ativo na Revolução Passiva

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Synthesis of palladium nanoparticles over graphite oxide and carbon nanotubes by reduction in ethylene glycol and their catalytic performance on the chemoselective hydrogenation of para-chloronitrobenzene

Pd nanoparticles have been synthesized over carbon nanotubes (CNT) and graphite oxide (GO) by reduction with ethylene glycol and by conventional impregnation method. The catalysts were tested on the chemoselective hydrogenation of p-chloronitrobenzene and the effect of the synthesis method and surface chemistry on their catalytic performance was evaluated. The catalysts were characterized by N2 adsorption/desorption isotherms at 77 K, TEM, powder X-ray diffraction, thermogravimetry, infrared and X-ray photoelectron spectroscopy and ICP-OES. It was observed that the synthesis of Pd nanoparticles employing ethylene glycol resulted in metallic palladium particles of smaller size compared to those prepared by the impregnation method and similar for both supports. The presence of oxygen groups on the support surface favored the activity and diminished the selectivity. It seems that ethylene glycol reacted with the surface groups of GO, this favoring the selectivity. The activity was higher over the CNT-based catalysts and both catalysts prepared by reduction in ethylene glycol were quite stable upon recycling.

Synthesis of palladium nanoparticles on carbon nanotubes and graphene for the chemoselective hydrogenation of para-chloronitrobenzene

We have studied the synthesis of palladium nanoparticles over carbon nanotubes (Pd/CNT) and graphene (Pd/G) and we have tested their catalytic performance in the liquid phase chemoselective hydrogenation of para-chloronitrobenzene at room temperature. The catalysts were characterized by N2 adsorption/desorption isotherms, TEM, X-ray diffraction, infrared and X-ray photoelectron spectroscopy and ICP-OES. The palladium particle size on Pd/G (3.4 nm) and Pd/CNT (2.8 nm) was similar though the deposition was higher on Pd/G. Pd/CNT was more active which can be ascribed to the different surface area and electronic properties of the Pd nanoparticles over CNT, while the selectivity was 100% to the corresponding haloaniline over both catalysts and they were quite stable upon recycling.

Destination image: identifying baseline perceptions of Brazil, Argentina and Chile in the nascent Australian long haul travel market

While the popularity of destination image research has increased exponentially in the literature, there has been relatively little published about perceptions held by international consumers of destinations in South America. The purpose of this paper is to report the findings of a research project that aimed to identify the baseline market perceptions of Brazil, Argentina and Chile amongst Australian residents, at the time of the emergence of this long haul market. Of interest was the extent to which Australians differentiate the three distinct countries versus perceiving the continent as a gestalt. These baseline perceptions enable the effectiveness of future marketing communications in Australia by the three national tourism offices to be monitored over time. Importance-Performance Analysis (IPA) is used as a practical analytical tool to guide decision makers. In terms of operationalising destination image, a key research finding was the very high ratio or participants using the ‘Don’t know’ (DK) option for each destination performance scale item. This finding has practical implications for the destination marketers, as well as for researchers engaged in destination image research in long haul and/or emerging markets.

The climate and eastern ocean systems project

A brief description of the NMFS/ORSTOM/ILCARM climate and Eastern Ocean systems (CEOS) project is given. CEOS will study the four major eastern boundary current regions (Peru/Chile, California, Northwest and Southwest Africa) and attempt to separate local short term changes of their resources and/or dynamics from long-term, climatic global changes. Expected products range from a large, widely accessible oceanographic / atmospheric database to various documents that will present key results as well as improved contacts and stronger analytical capabilities in cooperating national institutions.

As demandas curriculares da revolução pinguina no Chile: lutando pela qualidade da educação.

Identificar e analisar as demandas de tipo curricular articuladas no discurso do movimento social denominado como Revolução Pinguina, o que luta por uma educação de qualidade, gratuita e equitativa para os chilenos. Utilizo como referencial teórico, com registro pos-estrutural, a teoria do currículo desenvolvida por Alice Casimiro Lopes e Elizabeth Macedo a partir de uma abordagem discursiva e, a teoria do discurso desenvolvida por Ernesto Laclau em parceria com Chantal Mouffe. Entendo que essas demandas se inserem dentro dum conjunto mais amplo de demandas diferenciais que tem por antagonismo o projeto neoliberal do governo, representado pela concertación de partidos por la democracia. Dessa forma existem duas cadeias discursivas, por um lado o discurso dos estudantes, por outro, o discurso do governo, ambos tentam fixar determinados sentidos para o que representa qualidade da educação, desenvolvendo una guerra de representações. Defendo que por essa amplitude da cadeia discursiva a partir da incorporação de novas demandas representativas de diferentes atores sociais, também há um esvaziamento das bandeiras de luta, mas também uma maior força do movimento. Nesse sentido o significante qualidade da educação se transformou num significante vazio que se desprendeu de seus conteúdos concretos e precisos para poder representar provisoriamente a totalidade que a excede, ou seja, deixou de representar apenas um grupo especifico para representar a totalidade do movimento social. Assim, a luta política do movimento estudantil chileno pela educação de qualidade, tem colocado no centro do debate nacional diversas temáticas vinculadas com educação, mobilizando periodicamente á sociedade e conseguindo importantes transformações dentro da estrutura do sistema educativo nacional, significada pelo discurso estudantil como um sistema em crise.

CANCIONES ARGENTINAS (SONGS OFARGENTINA): A RECORDING PROJECT

This Dissertation Project comprises recordings of Argentine art songs. The discs are approximately 40-60 minutes in length and consist of songs from the traditional art-song repertoire for voice and piano. This project is particularly appropriate because of the very limited number of recordings of Argentine songs, which are notable both not only for their high quality but for their accessibility of performance for voice teachers, students, and professional singers alike. Art songs in the Spanish language are a welcome resource, and the poetry included in this project is of an outstanding quality. Some of the poets set to music are Gabriela Mistral (a poet laureate of Chile and the first Latin American woman to win the Nobel Prize for Literature), Pablo Neruda (also a Nobel laureate), Luis Cernuda, and Leon Benar6s. The lyrics of some songs are based on traditional sources, and the melodies and rhythms of all are representative of South American-indigenous and European­ immigrant cultures. The composers represented here will be familiar to some listeners but more than likely unfamiliar to most. Yet Alberto Ginastera (1916-1983) is considered to be the greatest of all Argentine composers. Alberto Williams (1862-1952) is known as the father of the Nationalist School of composition in Argentina, and Carlos Lopez Buchardo (1881-1963) is a most influential composer and pedagogue after whom the national Conservatory of Music in Buenos Aries is named. Two composers who remain relatively unknown outside of South America, Abraham Jurafsky (1906- 1993) and Julio Perceval (1903-1963) are also represented in this project. A complete compact disc is devoted to the works of Carlos Guastavino. Known as the "Argentine Schubert", Guastavino has over 250 songs to his credit. Chiefly a composer for piano and voice, his recent death (October 2000) makes a recording of his works especially appropriate. This project also includes a written component, a supportive dissertation briefly describing the history of the Argentine art song and the lives and influences of the composers and poets represented in the studio recordings. The CD recordings are held in the Michelle Smith Performing Arts Library at the University of Maryland.

The soundscape as time capsule: A creative project based on the sounds of the first train station of Cuenca

This article reflects on the changing environment through the passage of time and how certain technologies for a creative proposal allow the preservation and transmission of a significant part of that ephemeral heritage for future generations. The general purpose of this particular project is aimed to achieve the sound synthesis of a specific and representative cityscape as the old train station in Cuenca –located in the heart of the city– that could be preserved and reproduced as an unique document of a present time, ascertainable in the future: a memory that interpret sound as a time capsule. This soundscape was made to mark the arrival of the high speed train in 2010 to a brand new station in the outskirts of the city. Therefore, the goal of this research was focused on achieving a synthetic document that provided a sound memory capable of reflecting the significant social, cultural and logistical features, of what was until then the only railway communication symbol in the city of Cuenca from 1883 to the first decade of the 21st century.

Constituting "Community" at the onset of the Pascua Lama Mining Project

Mémoire numérisé par la Division de la gestion de documents et des archives de l'Université de Montréal.

Plataforma Tecnológica Colaborativa Comunidad de Negocios San Antonio, Chile, red de aprovisionamiento local: OpenSupply

El proyecto que se quiere plantear es la creación de una Plataforma electrónica a través de la cual se pretende agrupar a los diferentes proveedores que intervienen en la cadena de abastecimiento de la comunidad logística de San Antonio, abriendo la posibilidad de participación de empresas grandes y pequeñas y más aun promoviendo la creación de las mismas por parte de los ciudadanos de la región, de esta manera, se eliminan las brechas asimétricas existentes entre la oferta y la demanda permitiendo que las empresas medianas y grandes accedan a ofertas y transacciones con empresas proveedoras medianas y pequeñas. Dicho proyecto, tiene como objetivo general el consolidar los procesos de abastecimiento implementados por las empresas a través de la organización y estandarización de los mismos mediante el uso del portal, planteado en el presente proyecto, como apoyo tecnológico. Existen dos conceptos básicos a analizar de manera teórica dentro del proyecto, el primero de ellos es el de clúster logístico-portuario, lo cuales son reconocidos como instrumentos importantes para el progreso del desarrollo industrial, innovación, competitividad y crecimiento, tomando como ejemplos a los puertos de Valencia y Long Beach en la ciudad de Los Ángeles. El segundo concepto es el de E-Procurement, el cual se desarrolla siguiendo los pasos básicos de una cadena de abastecimiento tradicional, sin embargo, lo que genera un cambio real dentro de los procesos es el hecho que los procesos de cotización y seguimiento de proveedores se van a llevar a cabo a través de una plataforma electrónica con base a las evaluaciones que se llevan a cabo por parte de las empresas demandantes de los productos o servicios ofrecidos por las compañías proveedoras. (Renko, 2011) De la misma manera, se tomaran varios proyectos de e-procurement desarrollados a nivel mundial como base comparativa y de apoyo para el presente proyecto tales como: HYDRA: Es un sistema que tiene su soporte en la web, el cual es orientado “en el medio” lo cual lo hace un sistema con una arquitectura híbrida, que posee tanto un diseño en capas como una estructura comprensiva para desarrollar integración de negocios, colaboración y monitoreo en la gestión de la cadena de suministro (Renko, 2011) IPT: BidNet ha proporcionado servicios de oferta de información a miles de proveedores y compradores de bienes en el ámbito gubernamental por más de 25 años. (Bidnet, 2013) E-BUYPLACE: E-buyplace.com es el 1° especialista en SupplierRelationship Management que ha desarrollado un original y singular SRM 100% a través de Internet. (e-buyplace, 2013) RosettaNet: La iniciativa RosettaNet anima a optimizar los procesos de la cadena de suministro mediante el establecimiento, implementación y promoción de estándares abiertos en el mercado e-Business (AQS, Advance Quality Solutions, 2002)

Análisis y oportunidades comerciales entre las repúblicas de Colombia y Chile

Como consecuencia de las relaciones establecidas entre Colombia y Chile se busca analizar las relaciones comerciales, el impacto que tuvo la puesta en marcha del TLC y la identificación de oportunidades para los colombianos en ese mercado.

Observatorio del acuerdo comercial alianza pacífico en Colombia: oportunidades de exportación para Colombia a Chile, México y Perú

El desarrollo del presente proyecto de investigación, identifica, consolida, analiza datos económicos y el comportamiento del comercio exterior de Colombia, Chile, Perú y México dentro de la evolución del Acuerdo Alianza Pacífico durante los años 2011 - 2013. El estudio permitirá tener una visión más concreta, sobre la viabilidad que este bloque comercial representa para Colombia y mostrará cual ha sido el desempeño del país dentro del acuerdo con base a las exportaciones e importaciones efectuadas con los demás países miembros de la alianza. A lo largo del estudio, se analizará la balanza comercial de los treinta y dos (32) departamentos colombianos con los países miembros del acuerdo Alianza del Pacifico (Chile, México y Perú) entre 2011 – 2013. A partir de la obtención y análisis de resultados de tipo cuantitativo y cualitativo como el valor las exportaciones e importaciones, se hace un diagnóstico del comportamiento de la comercialización de productos por parte de los departamentos con destino y desde de Chile, México y Perú. Este análisis nos permitirá identificar cuáles son los bienes de mayor exportación y su participación dentro de las transacciones comerciales del acuerdo Alianza Pacifico. Con base a los datos que se recopilen, será posible analizar la situación y el papel que juega Colombia actualmente dentro del acuerdo y así identificar así las oportunidades, debilidades y posibles consecuencias, producto de la firma de este tratado. Finalmente, con la presente investigación se buscará iniciar el Observatorio del Acuerdo Alianza Pacifico, el cual se creará con fines investigativos, facilitando el seguimiento a la evolución de dicho acuerdo. A través del observatorio se lograra saber cuáles son los comportamientos en materia económica, tales como balanza comercial, inversión extranjera, movilidad, entre otros de este bloque de integración. Adicionalmente, será posible y analizar el comportamiento de los principales sectores económicos y los departamentos involucrados en este proceso, en términos comerciales.

Climate and construction delays: case study in Chile

Purpose – Construction projects usually suffer delays, and the causes of these delays and its cost overruns have been widely discussed, the weather being one of the most recurrent. The purpose of this paper is to analyze the influence of climate on standard construction work activities through a case study. Design/methodology/approach – By studying the extent at which some weather variables impede outdoor work from being effectively executed, new maps and tables for planning for delays are presented. In addition, a real case regarding the construction of several bridges in southern Chile is analyzed. Findings – Few studies have thoroughly addressed the influences of major climatic agents on the most common outdoor construction activities. The method detailed here provides a first approximation for construction planners to assess to what extent construction productivity will be influenced by the climate. Research limitations/implications – Although this study was performed in Chile, the simplified method proposed is entirely transferable to any other country, however, other weather or combinations of weather variables could be needed in other environments or countries. Practical implications – The implications will help reducing the negative social, economic and environmental outcomes that usually emerge from project delays. Originality/value – Climatic data were processed using extremely simple calculations to create a series of quantitative maps and tables that would be useful for any construction planner to decide the best moment of the year to start a project and, if possible, where to build it.

Política de formação docente na América Latina :Argentina, Brasil e Chile

This work aims at studying the policies of teaching training and their impact in the actors and in the education systems of the countries in which these policies were implemented into the context of neoliberal reforms. We particularly studied these policies in three Latin America countries: Argentina, Brazil and Chile. The policies studied here are the ones implemented from the 90 s. However, the horizon of this study is at the beginning of the 80 s, period that starts one of the four intervention initiatives of education here studied: The Main Project of Education For Latin America and Caribbean (PROMEDLAC), which in 2002 goes into a new stage and it is called Regional Project of Education for Latin America and Caribbean (PRELAC), worked out by UNESCO as a request of government representatives of countries of the region, based on the suggestions of Declaration of Mexico , signed by them in 1979. These suggestions will be in the base of the other three initiatives: The Education For All (EPT); Ibero-American Conferences of Education (CIE) and The Hemisphere Action Plan of Education (PAHE), whose documents are the base to the production of an abundant legislation and normatization on education that created the parameters on which the policies of education reforms were worked out and implemented and the dynamism of our education systems from the last two decades of the twentieth century on. All these initiatives intend to work with objectives, projects and programs that, in some cases, in isolation or in groups, are under influence of their actions in a way that frequently it is difficult to identify which of them is the main responsible for some advances. It is important to stand out that not all of the suggestions produced by these initiatives were implemented as policies, and many of them to be implemented were changed in such a way that they were distorted, even they were a result of a multilateral deal, each country gave to them its own interpretation. Moreover, in all these processes the teaching entities had and keep having a fundamental role. The evidences, result of the evaluations of each initiative, show that education policies implemented produced advances in several aspects. They are still not the ideal ones, in truth, but they do exist. In relation to the teaching questions, there were and are still being implemented multiples and varied actions that did not have the expected impact in the education systems of the countries, objects of this study, but, many of them that go on, are promising and start to have a positive impact into the education systems. Even so, the teaching subject matter, even playing a central role in the agenda of all countries of the region, still represents one of the big challenges to the advance and improvement of our education systems

A snapshot of Chile's 20 largest multinational enterprises in 2011: Sustained growth in South America

Includes bibliography