1-[(Z)-1-Bromo-2-(butyldichloro-lambda(4)tellanyl)ethenyl]cyclohex-1-ene

The Te(IV) atom in the title compound, [Te(C(4)H(9))(C(8)H(10)Br)Cl(2)] or C(12)H(19)BrCl(2)Te, is in a distorted psi-trigonal-bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)degrees]. Close intramolecular [Te center dot center dot center dot Br = 3.3444 (18) angstrom] and intermolecular [Te center dot center dot center dot Cl = 3.675 (3) angstrom] interactions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C-H center dot center dot center dot Cl.

Cold Nuclear Matter Effects on J/psi Yields as a Function of Rapidity and Nuclear Geometry in d plus A Collisions at root S(NN)=200 GeV

We present measurements of J/psi yields in d + Au collisions at root S(NN) = 200 GeV recorded by the PHENIX experiment and compare them with yields in p + p collisions at the same energy per nucleon-nucleon collision. The measurements cover a large kinematic range in J/psi rapidity (-2.2 < y < 2.4) with high statistical precision and are compared with two theoretical models: one with nuclear shadowing combined with final state breakup and one with coherent gluon saturation effects. In order to remove model dependent systematic uncertainties we also compare the data to a simple geometric model. The forward rapidity data are inconsistent with nuclear modifications that are linear or exponential in the density weighted longitudinal thickness, such as those from the final state breakup of the bound state.

Measurement of transverse single-spin asymmetries for J/psi production in polarized p plus p collisions at root s=200 GeV

We report the first measurement of transverse single-spin asymmetries in J/psi production from transversely polarized p + p collisions at root s = 200 GeV with data taken by the PHENIX experiment in 2006 and 2008. The measurement was performed over the rapidity ranges 1.2 < vertical bar y vertical bar < 2.2 and vertical bar y vertical bar < 0.35 for transverse momenta up to 6 GeV/c. J/psi production at the Relativistic Heavy Ion Collider is dominated by processes involving initial-state gluons, and transverse single-spin asymmetries of the J/psi can provide access to gluon dynamics within the nucleon. Such asymmetries may also shed light on the long-standing question in QCD of the J/psi production mechanism. Asymmetries were obtained as a function of J/psi transverse momentum and Feynman-x, with a value of -0.086 +/- 0.026(stat) +/- 0.003(syst) in the forward region. This result suggests possible nonzero trigluon correlation functions in transversely polarized protons and, if well defined in this reaction, a nonzero gluon Sivers distribution function.

Transverse momentum dependence of J/psi polarization at midrapidity in p plus p collisions at root s=200 GeV

We report the measurement of the transverse momentum dependence of inclusive J/psi polarization in p + p collisions at root s = 200 GeV performed by the PHENIX Experiment at the Relativistic Heavy Ion Collider. The J/psi polarization is studied in the helicity, Gottfried-Jackson, and Collins-Soper frames for p(T) < 5 GeV/c and vertical bar y vertical bar < 0.35. The polarization in the helicity and Gottfried-Jackson frames is consistent with zero for all transverse momenta, with a slight (1.8 sigma) trend towards longitudinal polarization for transverse momenta above 2 GeV/c. No conclusion is allowed due to the limited acceptance in the Collins-Soper frame and the uncertainties of the current data. The results are compared to observations for other collision systems and center of mass energies and to different quarkonia production models.

Cold nuclear matter effects on J/psi production as constrained by deuteron-gold measurements at root S(NN)=200 GeV

We present a new analysis of J/psi production yields in deuteron-gold collisions at root s(NN) =200 GeV using data taken from the PHENIX experiment in 2003 and previously published in S. S. Adler [Phys. Rev. Lett 96, 012304 (2006)]. The high statistics proton-proton J/psi data taken in 2005 are used to improve the baseline measurement and thus construct updated cold nuclear matter modification factors (R(dAu)). A suppression of J/psi in cold nuclear matter is observed as one goes forward in rapidity (in the deuteron-going direction), corresponding to a region more sensitive to initial-state low-x gluons in the gold nucleus. The measured nuclear modification factors are compared to theoretical calculations of nuclear shadowing to which a J/psi (or precursor) breakup cross section is added. Breakup cross sections of sigma(breakup)=2.8(-1.4)(+1.7) (2.2(-1.5)(+1.6)) mb are obtained by fitting these calculations to the data using two different models of nuclear shadowing. These breakup cross-section values are consistent within large uncertainties with the 4.2 +/- 0.5 mb determined at lower collision energies. Projecting this range of cold nuclear matter effects to copper-copper and gold-gold collisions reveals that the current constraints are not sufficient to firmly quantify the additional hot nuclear matter effect.

First-principles study of the adsorption of atomic and molecular hydrogen on BC(2)N nanotubes

The adsorption of atomic and molecular hydrogen on armchair and zigzag boron carbonitride nanotubes is investigated within the ab initio density functional theory. The adsorption of atomic H on the BC(2)N nanotubes presents properties which are promising for nanoelectronic applications. Depending on the adsorption site for the H, the Fermi energy moves toward the bottom of the conduction band or toward the top of the valence band, leading the system to exhibit donor or acceptor characteristics, respectively. The H(2) molecules are physisorbed on the BC(2)N surface for both chiralities. The binding energies for the H(2) molecules are slightly dependent on the adsorption site, and they are near to the range to work as a hydrogen storage medium.

J/psi production at high transverse momenta in p plus p and Cu plus Cu collisions at root s(NN)=200 GeV

The STAR Collaboration at the Relativistic Heavy Ion Collider presents measurements of J/psi e(+) e(-) at midrapidity and high transverse momentum (pT > 5 GeV/c) in p + p and central Cu + Cu collisions at root s(NN) = 200 GeV. The inclusive J/psi production cross section for Cu + Cu collisions is found to be consistent at high p(T) with the binary collision-scaled cross section for p + p collisions. At a confidence level of 97%, this is in contrast to a suppression of J/psi production observed at lower p(T). Azimuthal correlations of J/psi with charged hadrons in p + p collisions provide an estimate of the contribution of B-hadron decays to J/psi production of 13% +/- 5%.

Germline BRCA1 promoter deletions in UK and Australian familial breast cancer patients: Identification of a novel deletion consistent with BRCA1 :psi VBRCA1 recombination

Inherited susceptibility to breast cancer results from germline mutations in one of a number of genes including BRCA1. A significant number of BRCA1-linked familial breast cancer patients, however, have no detectable BRCA1 mutation. This could be due in part to the inability of commonly used mutation-detection techniques to identify mutations outside the BRCA1 coding region. This paper addresses the hypothesis that non coding region mutations, specifically in the BRCA1 promoter, account for some of these cases. We describe a new and detailed restriction map of the 5' region of the BRCA1 gene including the nearby NBR2, psiBRCA1, and NBR1 genes and the isolation of a number of new informative hybridization probes suitable for Southern analysis. Using this information we screened DNA from lymphoblastoid cell-lines made from 114 UK familial breast cancer patients and detected one large deletion in the 5' region of BRCA1. We show that the breakpoints for this deletion are in BRCA1 intron 2 and between NBR2 and exon 2 of psiBRCA1, raising the possibility that this deletion arose via a novel mechanism involving BRCA1:psiBRCA1 recombination. We have also screened 60 familial breast cancer patients from the Australian population, using an amplification refractory mutation system (ARMS) technique described previously by our group, and found one patient with a genotype consistent with a BRCA1 promoter deletion. These findings indicate that germline BRCA1 promoter deletions are a rare and yet significant mutation event and that they could arise via a novel genetic mechanism. Hum Mutat 19:435-442, 2002. (C) 2002 Wiley-Liss, Inc.

A cassette ligation strategy with thioether replacement of three Gly-Gly peptide bonds: Total chemical synthesis of the 101 residue protein early pregnancy factor [psi(CH2S)(28-29,56-57,76-77)]

The 101 residue protein early pregnancy factor (EPF), also known as human chaperonin 10, was synthesized from four functionalized, but unprotected, peptide segments by a sequential thioether ligation strategy. The approach exploits the differential reactivity of a peptide-NHCH2CH2SH thiolate with XCH2CO-peptides, where X = Cl or I/Br. Initial model studies with short functionalized (but unprotected) peptides showed a significantly faster reaction of a peptide-NHCH2CH2SH thiolate with a BrCH2CO-peptide than with a CICH2CO-peptide, where thiolate displacement of the halide leads to chemoselective formation of a thioether surrogate for the Gly-Gly peptide bond. This rate difference was used as the basis of a novel sequential ligation approach to the synthesis of large polypeptide chains. Thus, ligation of a model bifunctional N-alpha-chloroacetyl, C-terminal thiolated peptide with a second N-alpha-bromoacetyl peptide demonstrated chemoselective bromide displacement by the thiol group. Further investigations showed that the relatively unreactive N-alpha-chloroacetyl peptides could be activated by halide exchange using saturated KI solutions to yield the highly reactive No-iodoacetyl peptides. These findings were used to formulate a sequential thioether ligation strategy for the synthesis of EPF, a 101 amino acid protein containing three Gly-Gly sites approximately equidistantly spaced within the peptide chain. Four peptide segments or cassettes comprising the EPF protein sequence (BrAc-[EPF 78-101] 12, ClAc-[EPF 58-75]-[NHCH2CH2SH] 13, ClAc-[EPF 30-55]-[NHCH2CH2SH] 14, and Ac-[EPF 1-27]-[NHCH2CH2SH] 15) of EPF were synthesized in high yield and purity using Boc SPPS chemistry. In the stepwise sequential ligation strategy, reaction of peptides 12 and 13 was followed by conversion of the N-terminal chloroacetyl functional group to an iodoacetyl, thus activating the product peptide for further ligation with peptide 14. The process of ligation followed by iodoacetyl activation was repeated to yield an analogue of EPF (EPF psi(CH2S)(28-29,56-57,76-77)) 19 in 19% overall yield.

Atenção seletiva: PSI em crianças com distúrbio de aprendizagem

A atenção seletiva é importante para o aprendizado da leitura e escrita. OBJETIVO: Estudar os processos de atenção seletiva de crianças com e sem distúrbio de aprendizagem. MATERIAL E MÉTODO: O Grupo I foi constituído de quarenta indivíduos com idades entre nove anos e seis meses a dez anos e 11 meses, que apresentavam baixo risco para alteração no desenvolvimento das habilidades auditivas, linguagem e aprendizagem. O Grupo II foi constituído de 20 indivíduos com idades entre nove anos e cinco meses a 11 anos e dez meses, diagnosticados como portadores de distúrbio de aprendizagem. Foi realizado estudo prospectivo através do Teste Pediátrico de Inteligibilidade de Fala (PSI). RESULTADO: O teste PSI com mensagem competitiva ipsilateral, à orelha direita, na relação fala/ruído 0 e -10 foi apropriado para diferenciar o Grupo I e o Grupo II de forma estatisticamente significante. Atenção ao desempenho do Grupo II na performance da primeira orelha testada deve ser dada, por subsidiar características importantes de desempenho e reabilitação. CONCLUSÃO: O PSI foi adequado para diferenciar os grupos, havendo uma associação com o grupo com distúrbio de aprendizagem, que revelou alteração nos processos de atenção seletiva.

Factores determinantes do valor da empresa no mercado de capitais: evidência empírica para o PSI 20

El principal finalidad de la presente comunicación se traduce en el análisis del efecto de los indicadores de desempeño empresarial en la explicación del precio de las acciones que integran el principal índice bursátil de la Euronext Lisboa, el PSI 20. Para tal, recurrimos a un análisis fundamental, habiendo dividido los indicadores de desempeño empresarial en dos grupos, un con un cariz económico-financiero otro con un cariz bursátil. Utilizando una muestra de 17 empresas, los resultados son obtenidos a través de la aplicación del método OLS y reportan a 31 de Diciembre de 2007. Los resultados obtenidos sugieren que los indicadores de desempeño empresarial se presentan susceptibles de explicar el precio de mercado de las acciones de las empresas que integran el PSI 20. Se destaca el efecto significativamente positivo del resultado líquido y del valor contable y el efecto significativamente negativo del cash-flow. Los resultados obtenidos sugieren la existencia de una expectativa positiva relativamente al desempeño futuro de las empresas que integran el PSI 20.

Evidência empírica dos factores explicativos dos dividendos distribuídos pelas empresas do PSI 20

La presente comunicación tiene como objetivo central el análisis de los factores explicativos de la política de dividendos de las empresas que integran el principal índice bursátil del mercado de capitales portugués, el PSI 20. Con ese designio, utilizamos un conjunto de informaciones económicas y financieras de las empresas no financieras para explicar los dividendos por acción distribuidos en el período temporal comprendido por los años de 2005 a 2009. Los resultados logrados en el estudio empírico sugieren que el resultado líquido, los dividendos por acción distribuidos en el ejercicio económico anterior y el crecimiento de las ventas presentan un efecto positivo y estadísticamente significativo en la explicación de los dividendos por acción distribuidos en un determinado ejercicio económico. Sugieren todavía que el modelo desarrollado por Lintner (1956) se presenta válido para explicar la política de dividendos de las empresas de lo PSI 20.

Evidência empírica dos factores explicativos dos dividendos distribuidos pelas empresas do PSI 20

La presente comunicación tiene como objetivo central el análisis de los factores explicativos de la política de dividendos de las empresas que integran el principal índice bursátil del mercado de capitales portugués, el PSI 20. Con ese designio, utilizamos un conjunto de informaciones económicas y financieras de las empresas no financieras para explicar los dividendos por acción distribuidos en el período temporal comprendido por los años de 2005 a 2009. Los resultados logrados en el estudio empírico sugieren que el resultado líquido, los dividendos por acción distribuidos en el ejercicio económico anterior y el crecimiento de las ventas presentan un efecto positivo y estadísticamente significativo en la explicación de los dividendos por acción distribuidos en un determinado ejercicio económico. Sugieren todavía que el modelo desarrollado por Lintner (1956) se presenta válido para explicar la política de dividendos de las empresas de lo PSI 20.

A divulgação de informação sobre planos de benefícios de reforma em Portugal e a sua relação com o endividamento: Uma análise do PSI geral

Mestrado em Contabilidade e Gestão das Instituições Financeiras