1-[(Z)-1-Bromo-2-(butyldichloro-lambda(4)tellanyl)ethenyl]cyclohex-1-ene
Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
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Data(s) |
17/04/2012
17/04/2012
2011
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Resumo |
The Te(IV) atom in the title compound, [Te(C(4)H(9))(C(8)H(10)Br)Cl(2)] or C(12)H(19)BrCl(2)Te, is in a distorted psi-trigonal-bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)degrees]. Close intramolecular [Te center dot center dot center dot Br = 3.3444 (18) angstrom] and intermolecular [Te center dot center dot center dot Cl = 3.675 (3) angstrom] interactions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C-H center dot center dot center dot Cl. Brazilian agency FAPESP[07/59404-2] Brazilian agency CNPq[306532/2009-3] Brazilian agency CNPq[308116/2010-0] Brazilian agency CAPES[808/2009] |
Identificador |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.67, p.O1751-U1249, 2011 1600-5368 http://producao.usp.br/handle/BDPI/14825 10.1107/S1600536811023142 |
Idioma(s) |
eng |
Publicador |
WILEY-BLACKWELL |
Relação |
Acta Crystallographica Section E-structure Reports Online |
Direitos |
closedAccess Copyright WILEY-BLACKWELL |
Palavras-Chave | #CRYSTAL #Crystallography |
Tipo |
article original article publishedVersion |