990 resultados para 340.2


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The title hydrate, C27H23NO2 center dot H2O, features an almost planar quinoline residue (r.m.s. deviation = 0.015 angstrom) with the benzene dihedral angle = 63.80 (7)degrees] and chalcone C-C-C-O torsion angle = -103.38 (18)degrees] substituents twisted significantly out of its plane. The configuration about the C=C bond 1.340 (2) angstrom] is E. In the crystal, molecules related by the 21 symmetry operation are linked along the b axis via water molecules that form O-H center dot center dot center dot O-c and O-H center dot center dot center dot N-q hydrogen bonds (c = carbonyl and q = quinoline). A C-H center dot center dot center dot O interaction also occurs.

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鲢、鳙放养使微型生态系统的水柱氮、磷浓度和磷的分布发生了明显的变化。至实验结束时,各实验组的水柱颗粒磷、总磷和氨氮浓度都比对照组高,而正磷酸盐浓度和沉积物磷的量均低于对照组。这种变化以鳙单养系统为最大,其次是鲢、鳙混养系统,鲢单养系统的变化最小。微型生态系统中正磷酸盐浓度同浮游动、植物密度和初级生产力显著相关,氨氮浓度同所述变量之间的相关关系则多半与正磷酸盐相反。实验观测期间浮游植物密度与总磷浓度之间存在营养级联假说所预见的下行影响,实验结束时二者之间却有上行影响的趋向。根据实验观测结果认为,微型生态系统

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本文依据收集到的392个地面验潮站8个主要分潮(M2、S2、K1、O1、N2、K2、P1及Q1)的调和常数,对现有7个全球大洋潮汐模式的准确度进行了检验,结果显示各模式在深海区域均达到了比较高的准确度,相互之间差别也不大。经验模式GOT00和CSR4.0、同化模式NAO99、反演同化模式TPXO7.0、数值同化模式FES2002和FES2004的M2分潮均方根偏差在3 cm左右,其它分潮(S2、K1、O1、N2、K2、P1及Q1)大约在1~2 cm。本文还依据中国近海18个岛屿的调和常数对其中的5个大洋潮汐模式的准确度进行了检验,结果表明,M2分潮均方根偏差在6~14 cm,明显高于大洋部分的偏差,其中日本国家天文台的潮汐模式NAO99在中国近海的结果相对较准确。 我们利用1992年8月至2008年8月的TOPEX/POSEIDON和JASON-1(T/P-J)卫星高度计资料,对沿卫星轨道的302816个站点进行了14个分潮的潮汐调和分析,得到了全球大洋潮汐的8个主要分潮以及2个气象分潮Sa、Ssa的经验同潮图。主要结果有:(1)各分潮在卫星上升轨道与下降轨道的交叉点(约7000个)相关性分析表明:M2分潮的振幅和迟角的相关系数很高(分别为0.9965和0.9961);S2,K1,O1和Sa分潮也有较好的相关性(相关系数为0.94~0.99);(2)该结果与392地面个验潮站吻合较好,其中M2分潮的振幅、迟角和向量的均方根偏差分别为:1.73 cm,2.340和2.93 cm;S2,K1和O1分潮的振幅、迟角和向量的均方根偏差为1 cm左右,5.250~7.270和1.5~2.1 cm,该精度与最近几年国际上的主要大洋潮汐模式的准确度相近;(3)首次通过卫星资料获得了Sa、Ssa分潮的同潮图。周期为1年的Sa分潮与大洋105个地面站相比,振幅、迟角和向量的均方根偏差分别为1.50 cm、18.360和2.16 cm。在此基础上,进一步分析了构成Sa、Ssa气象分潮的两个主要因素(海水密度以及海面气压)在全球的分布。 在T/P-J等卫星资料无法覆盖到南大洋和北冰洋,本文利用Princeton Ocean Model(POM)进行了数值模拟,模拟结果与162个地面实测站(其中南大洋30个,北冰洋132个)的观测比较一致。基于卫星资料分析的结果和数值模拟结果合并得到了全球大洋的8个主要分潮同潮图。在此基础上通过全球潮汐能量耗散的计算得到潮能通量的分布,并得到全球M2、S2、K1和O1分潮的潮汐能量耗散率为2.431TW、0.401TW、0.336TW和0.176TW。 本文还利用卫星资料对南海潮汐进行了研究,在中国南海,获得了主要的半日潮、全日潮、四分日分潮和长周期分潮(M2,S2,N2,K2,K1,O1,P1,Q1,M4, MS4,Sa, Ssa)的经验同潮图。与南海沿岸94个地面验潮站的数据符合得比较好,M2,S2,K1及O1等4个主要分潮的平均振幅差为2~4 cm,均方根偏差分别是9~11 cm.其它4个主要分潮N2,K2,P1,Q1的平均振幅差为1~2 cm,均方根偏差为2~4 cm。此外,本文还利用卫星高度计资料潮汐分析结果沿卫星轨道进行高通滤波,分离得出中国近海的M2,S2,K1及O1分潮的内潮信息。

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The mechanism of the hydrogenation/hydrogenolysis of dinitrodiphenyldisulfides using sulfided NiMo/ gamma Al2O3 catalysts has been examined in detail. Although two routes are possible, the major pathway involves an initial S-S bond cleavage followed by reduction of the nitro group. Importantly, the disulfide hydrogenolysis occurs in the absence of the catalyst with the role of the catalyst thought to be to activate the hydrogen and trap the cleaved intermediate as well as facilitate the reduction of the nitro group. Monitoring the mass balance throughout the reaction demonstrates the difficulty in measuring intrinsic kinetics for gas-liquid-solid reactions. Although the mass balance is restored at the end of the reaction, up to 45% of the substrate/products is found to be adsorbed on the catalyst during the reaction. (c) 2008 Elsevier B.V. All rights reserved.

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This paper discusses a number of checks that should be carried out to ensure that the kinetic and spectroscopic measurements made using a DRIFTS cell are meaningful. The observations reported here demonstrate how an appropriately modified commercial DRIFTS cell can provide pertinent kinetic information about both gaseous products and the related surface intermediates. The oxidation of CO with 02 was used as a test to assess the catalyst bed bypass by the reaction mixture. Full CO conversion was obtained after the light-off temperature in the case of the modified cell, contrary to the case of the original cell, for which 80% of the reaction mixture bypassed the catalyst bed. The water-gas shift reaction over a Pt/CeO2 catalyst was used as a model reaction to further characterize the behavior of the cell under reaction conditions. The catalyst bed was shown not to be a dead-zone and was purged in essentially the same time as that needed to purge the cell. The reaction chamber globally operated in a quasi plug-flow mode and the gas composition in the thin catalyst bed appears to be homogeneous when operated under differential conditions. The production of the gas-phase reaction product CO2 could be simultaneously followed both by mass spectrometry and DRIFTS, both techniques leading to identical results. Various IR bands integration methods were discussed to allow a precise and accurate determination of the surface concentration of adsorbates during isotopic exchange. (c) 2008 Elsevier B.V. All rights reserved.

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Originalmente presentada en francés como proyecto de grado para la Maestría en Derecho Bancario y Financiero de la Universidad de Estrasburgo, la presente monografía tiene por objetivo analizar la Gestión Colectiva como estrategia para las Holdings. La Gestión Colectiva es un término francés empleado para designar al intermediario financiero que convierte el ahorro individual en portafolios colectivos. En Colombia, la Gestión Colectiva es conocida como Carteras Colectivas o Fondos de Inversión Colectiva, (su nombre más reciente). Este vehículo financiero, es en cierto modo una democratización de las finanzas, ya que canaliza el ahorro de la población hacia las principales industrias, permitiendo que las empresas hagan del ahorro individual una fuente de financiación para sus proyectos, y que la mayor parte de la población tenga acceso a las finanzas. Es por esto, que el tema frecuentemente es abordado desde el punto de vista de la protección a los inversionistas y no, desde los vehículos que prestan dicho servicio. Sin embargo, la presente Monografía estudia la Gestión Colectiva como una posible estrategia para las Holdings, analizando desde este punto de vista, la pertinencia de implementar la Gestión Colectiva como estrategia para reunir fondos para las Holdings. De ahí que el derecho comparado sea de gran ayuda para comprender si dicha estrategia es viable en todos los países en general o si, por el contrario, como lo vemos en Derecho Bancario, unos países sean más favorables que otros. El presente, es un estudio multidisciplinario en el cual se tienen en cuenta variables de tipo legal, económico y político, y se implementan teorías económicas aplicables al estudio del Derecho como Law & Economics. En una primera parte nos centramos en un análisis comparado de las legislaciones de dos países con niveles de desarrollo diferente, a saber, Francia y Colombia. Y, en la segunda parte analizamos el rol de la Gestión Colectiva en las Holdings, así como sus ventajas y desventajas según la legislación aplicable.

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FoxC, FoxF, FoxL1 and FoxQ1 genes have been shown to be clustered in some animal genomes, with mesendodermal expression hypothesised as a selective force maintaining cluster integrity. Hypotheses are, however, constrained by a lack of data from the Lophotrochozoa. Here we characterise members of the FoxC, FoxF, FoxL1 and FoxQ1 families from the annelid Capitella teleta and the molluscs Lottia gigantea and Patella vulgata. We cloned FoxC, FoxF, FoxL1 and FoxQ1 genes from C. teleta, and FoxC, FoxF and FoxL1 genes from P. vulgata, and established their expression during development. We also examined their genomic organisation in C. teleta and L. gigantea, and investigated local syntenic relationships. Our results show mesodermal and anterior gut expression is a common feature of these genes in lophotrochozoans. In L. gigantea FoxC, FoxF and FoxL1 are closely linked, while in C. teleta Ct-foxC and Ct-foxL1 are closely linked, with Ct-foxF and Ct-foxQ1 on different scaffolds. Adjacent to these genes there is limited evidence of local synteny. This demonstrates conservation of genomic organisation and expression of these genes can be traced in all three bilaterian Superphyla. These data are evaluated against competing theories for the long-term maintenance of gene clusters.

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Monte Carlo simulation and quantum mechanics calculations based on the INDO/CIS and TD-DFT methods were utilized to study the solvatochromic shift of benzophenone when changing the environment from normal water to supercritical (P = 340.2 atm and T = 673 K) condition. Solute polarization increases the dipole moment of benzophenone, compared to gas phase, by 88 and 35% in normal and supercritical conditions, giving the in-solvent dipole value of 5.8 and 4.2 D, respectively. The average number of solute-solvent hydrogen bonds was analyzed, and a large decrease of 2.3 in normal water to only 0.8 in the supercritical environment was found. By using these polarized models of benzophenone in the two different conditions of water, we performed MC simulations to generate statistically uncorrelated configurations of the solute surrounded by the solvent molecules and subsequent quantum mechanics calculations on these configurations. When changing from normal to supercritical water environment, INDO/CIS calculations explicitly considering all valence electrons of the 235 solvent water molecules resulted in a solvatochromic shift of 1425 cm(-1) for the most intense transition of benzophenone, that is, slightly underestimated in comparison with the experimentally inferred result of 1700 cm(-1). TD-B3LYP/6-311+G(2d,p) calculations on the same configurations but with benzophenone electrostatically embedded in the 320 water molecules resulted in a solvatochromic shift of 1715 cm(-1) for this transition, in very good agreement with the experimental result. When using the unpolarized model of the benzophenone, this calculated solvatochromic shift was only 640 cm(-1). Additional calculations were also made by using BHandHLYP/6-311+G(2d,p) to analyze the effect of the asymptotic decay of the exchange functional. This study indicates that, contrary to the general expectation, there is a sizable solute polarization even in the low-density regime of supercritical condition and that the inclusion of this polarization is important for a reliable description of the spectral shifts considered here.

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O estudo foi conduzido numa área de capim-Tanzânia (Panicum maximum), manejada em pastejo rotacionado para estimar o consumo de matéria seca de vacas em lactação. Os três tratamentos foram: vacas mestiças alimentadas com 3 kg de concentrado e vacas mestiças e Zebu (Gir) sem suplementação com concentrado. Observou-se uma quantidade de 7340,2 kg de matéria seca (MS) /ha de forragem disponível antes da ocupação e de 5.639,5 após o 3° dia de ocupação. O consumo de MS de capim-Tanzânia foi 8,26 ± 5,66, 11,01 ± 5,37 e 9,55 ± 2,31 kg de MS/vaca/dia ou 2,15%, 2,37% e 2,34% do peso vivo, respectivamente para as vacas suplementadas, cruzadas não suplementadas e vacas Zebu . A média da produção de leite foi maior para o grupo suplementado (11,98 kg/vaca/dia). A produção de leite observada para as vacas não suplementadas foi similar. Produção de leite de 6,53 foi obtida pelas vacas cruzadas não suplementadas e 5,46 por vaca/dia foi produzida pelas vacas Zebu.

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Studies were made to clarify the role that was played by the lovebirds (Agapornis roseicollis) in the epidemiological plan, under the perspective of its being a potential source of infection of Newcastle Disease Virus (NDV). The study used Specific-Pathogen-Free chicks (SPF) that were housed with lovebirds inoculated with a pathogenic strain (velogenic viscerotropic) of NDV pathogenic to chickens, by the ocular-nasal via. Each group was composed of six SPF chicks and four lovebirds. After five days of the inoculation of the lovebirds with NDV, SPF chicks were put together with each group of lovebirds. Cloacae swabs were collected after 9, 14 and 21 days post-challenge in both species (lovebirds and SPF chicks) for genome viral excretion by Reverse Transcription Polymerase Chain Reaction (RT-PCR). Lovebirds did not demonstrate any clinical signs of NDV. They were refractory to the clinical disease with the NDV. However, NDV genome was detected 9 and 21 days after challenge. This study shows that lovebirds can be carriers NDV. Moreover, 100% of SPF chicks allocated with the infected lovebirds demonstrated clinical signs and lesions suggestive of NDV. In these birds, NDV genome was detected 9, 14 and 21 days after challenge. Thus, the transmission of the pathogenic virus from the lovebirds to SPF chicks that were housed together was evident until 21 days of the experimental infection. This study reveals the importance of lovebirds from the epidemiological point of view as potential source of infection of the NDV to other avian species that could be raised near this species. © Asian Network for Scientific Information, 2012.