(2E)-3-(4-Bromophenyl)-1-(2-methyl-4phenyl-3-quinolyl)prop-2-en-1-one

The conformation about the ethene bond [1.316 (3) angstrom] in the title compound, C25H18BrNO, is E. The quinoline ring forms dihedral angles of 67.21 (10) and 71.68 (10)degrees with the benzene and bromo-substituted benzene rings, respectively. High-lighting the non-planar arrangement of aromatic rings, the dihedral angle formed between the benzene rings is 58.57 (12)degrees.

(2E)-3-(4-Ethoxyphenyl)-1-(2-methyl-4-phenylquinolin-3-yl)prop-2-en-1-on e monohydrate

The title hydrate, C27H23NO2 center dot H2O, features an almost planar quinoline residue (r.m.s. deviation = 0.015 angstrom) with the benzene dihedral angle = 63.80 (7)degrees] and chalcone C-C-C-O torsion angle = -103.38 (18)degrees] substituents twisted significantly out of its plane. The configuration about the C=C bond 1.340 (2) angstrom] is E. In the crystal, molecules related by the 21 symmetry operation are linked along the b axis via water molecules that form O-H center dot center dot center dot O-c and O-H center dot center dot center dot N-q hydrogen bonds (c = carbonyl and q = quinoline). A C-H center dot center dot center dot O interaction also occurs.

(2E)-1-(5-Chlorothiophen-2-yl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one

In the title molecule, C(16)H(15)ClO(4)S, the chlorothiophene and trimethoxyphenyl rings make a dihedral angle of 31.12 (5)degrees. The C = C double bond exhibits an E conformation. In the crystal, C-H center dot center dot center dot O interactions generate bifurcated bonds, linking the molecules into chains along the b axis.

(2E)-1-(5-Chlorothiophen-2-yl)-3-(2,3-dimethoxyphenyl)prop-2-en-1-one

In the title compound, C(15)H(13)ClO(3)S, the chlorothiophene and dimethoxyphenyl groups are linked by a prop-2-en-1-one group. The C=C double bond exhibits an E conformation. The molecule is non-planar, with a dihedral angle of 31.12 (5)degrees between the chlorothiophene and dimethoxyphenyl rings. The methoxy group at position 3 is coplanar with the benzene ring to which it is attached, with a C-O-C-C torsion angle of -3.8 (3)degrees. The methoxy group attached at position 2 of the benzene ring is in a (+)synclinal conformation, as indicated by the C-O-C-C torsion angle of -73.6 (2)degrees. In the crystal, two different C-H center dot center dot center dot O intermolecular interactions generate chains of molecules extending along the b axis.

Recherches sur le développement des organes genitaux de quelques Gasteropodes hermaphrodites. 1. Thèse ; Propositions données par la Faculté. 2e. Thèse

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Kaffe在龙芯2E上的移植

为了在龙芯2E处理器上建立稳定的Java运行环境,丰富龙芯平台的上层软件库,以Kaffe这款开源Java虚拟机为移植对象,分析了其运行机制,确定了其代码结构中平台相关的3个主要模块:SysCallMethod、Trampoline和JTT,并结合龙芯2E处理器的特点,给出了相关模块的修改方案.最后用第三方的测试标准对移植后的虚拟机进行了测试,表明了移植的有效性.

Kaffe虚拟机在龙芯2E上的移植研究

Java虚拟机作为Java运行环境的核心，已成为现代计算机平台不可缺少的组成部分。Java虚拟机和平台间的兼容性直接决定了上层Java程序的运行的稳定性。龙芯2E是由中科院计算机研究所自主研发的高性能微处理器。由于采用MIPS指令集，现有Java虚拟机对龙芯的支持并不理想，这极大地限制了龙芯平台的上层应用。 针对这一问题，本文对现有虚拟机进行了分析，选择了移植性较强的Kaffe虚拟机作为移植对象，力求在龙芯2E上建立一个稳定的Java运行环境。以此为目的，本文整理了龙芯2E相关的内容，包括龙芯2E的指令集特点，龙芯下参数传递的方式，龙芯下函数栈的组织等等；研究了Java虚拟机规范中，一般Java虚拟机的体系结构；分析了Kaffe虚拟机的代码结构，确定了移植需要修改的三个主要模块：本地代码调用接口，Trampoline技术和JIT3引擎；给出了移植方案。其中，JIT3引擎作为整个虚拟机的核心，是整个移植工作的重点。本文对其编译过程，寄存器分配策略，Java栈的组织方式，以及标签，常量池等平台相关机制进行了深入的分析。在此基础上，修改了Java栈向本地栈的映射方式，实现了标签机制中平台相关部分的代码，重新描述了寄存器信息并重新实现了本地汇编指令。 针对Java虚拟机调试困难的问题，本文总结了龙芯平台下Kaffe虚拟机的调试方法。在调试过程中发现了Kaffe原有代码中的编码错误，并给出了修改方案。 最后采用第三方的评测工具对移植后的虚拟机进行测试，验证了移植的有效性。

Ne原子(e,2e)反应中反冲离子动量分析；Analysis of Recoil Ion Momentum in Ne(e,2e)Ne~+ Reaction

利用冷靶反冲离子动量谱仪,对电子轰击Ne原子的单电离反应(e,2e)进行了研究,实验测量了70—3300eV入射能量情况下,反应过程中产生的一价反冲离子的动量分布,并对反冲离子的总动量进行了还原。介绍了一个简单的碰撞机制,据此着重分析了反冲离子纵向动量和横向动量二维谱形成的原因,该碰撞机制能够较好地解释较高能量入射时的实验结果。最后根据反冲离子的动量,估算了出射电子的能量范围,为下一步进行电子、离子的符合测量奠定了基础。

A STUDY ON 2E SPECTRA OF BIPHENYL DERIVATIVES

A study of doubly charged ion mass spectra (2E spectra), the substituents effect and the target gas pressure deppendence of biphenyl derivitives was presented in this work. The decomposition of doubly charged ion formed in the ion source is dominant by the losses of H, C2H2, C2H4 and HR(R represents substituent). [C12H8]2+, [C12H6]2+ and [C10H6]2+ among others are the most stable product ions. The substituents effect is Various in different decomposition reactions, and in some cases it can not be predicted by Hammett equition. While the TIC of 2E spectra was markedly influenced by the target gas pressure, but the fragmentation pattern of the 2E spectra is independent of it.

联苯取代物的双电荷离子质谱(2E谱)研究

本文研究了联苯取代物双电荷离子2E谱及其取代基效应和靶气压力影响。离子源中产生的双电荷离子的解离反应主要有丢失H原子、C_2H_2、C_2H_4、HR(R为取代基)等反应通道。产物离子中[C_(12)H_8]~(2+)、[C_(12)H_6]~(2+)、[C_(10)H_6]~(2+)等具有相当的稳定性。取代基对不同的反应有不同的影响,主要取决于产物离子的相对稳定性。取代基对分子离子的稳定性的贡献有以下顺序:NH_2>OH>Ph>F>H>Br>NO_2。升高靶气压力,2E谱的总离子流迅速升高,而样品离子流占总离子流的百分数却直线降低。靶气压力影响样品的检测灵敏度,但不影响离子的碎裂途径。

On the observation of the fine structure effect in non- relativistic (e, 2e) processes

The spin asymmetry arising in an (e,2e) process using spin- polarized incoming electrons with non-relativistic energies is shown to be dominated by the fine structure effect if a suitable kinematical regime is chosen. Calculations in the distorted wave Born approximation (DWBA) for both the triple differential cross-section and the spin asymmetry are presented for the inner shell ionization of argon. This process would provide an accessible target for existing experimental set-ups.