(2E)-1-(5-Chlorothiophen-2-yl)-3-(2,3-dimethoxyphenyl)prop-2-en-1-one


Autoria(s): Prabhu, AN; Jayarama, A; Sankolli, Ravish; Row, Guru TN; Upadhyaya, V
Data(s)

01/10/2011

Resumo

In the title compound, C(15)H(13)ClO(3)S, the chlorothiophene and dimethoxyphenyl groups are linked by a prop-2-en-1-one group. The C=C double bond exhibits an E conformation. The molecule is non-planar, with a dihedral angle of 31.12 (5)degrees between the chlorothiophene and dimethoxyphenyl rings. The methoxy group at position 3 is coplanar with the benzene ring to which it is attached, with a C-O-C-C torsion angle of -3.8 (3)degrees. The methoxy group attached at position 2 of the benzene ring is in a (+)synclinal conformation, as indicated by the C-O-C-C torsion angle of -73.6 (2)degrees. In the crystal, two different C-H center dot center dot center dot O intermolecular interactions generate chains of molecules extending along the b axis.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/41930/1/Chlorothiophen.pdf

Prabhu, AN and Jayarama, A and Sankolli, Ravish and Row, Guru TN and Upadhyaya, V (2011) (2E)-1-(5-Chlorothiophen-2-yl)-3-(2,3-dimethoxyphenyl)prop-2-en-1-one. In: Acta Crystallographica Section E, 67 (Part 1). O2665+.

Publicador

International Union of Crystallography.

Relação

http://scripts.iucr.org/cgi-bin/paper?S1600536811037135

http://eprints.iisc.ernet.in/41930/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed