Na 1 Nachlass Max Horkheimer, 54 - Korrespondenzen u.a. mit Jiri Veltruský (p. I 25, 242-321)

4 Briefe und 8 Beilagen zwischen Gerhard Tinter und Max Horkheimer, 1938; 1 Brief von Hans Tischler an Max Horkheimer, 08.12.1938; 4 Briefe zwischen Bernhard H. Titcomb und Max Horkheimer, 22.09.1935, 1935; 2 Briefe zwischen Paul Titus und Max Horkheimer, 07.06.1942, 09.06.1942; 1 Brief von Ferdinand Tönnies an Max Horkheimer, 17.10.1935; 1 Brief von Tonetti Juliette Favez, 21.11.1935; 1 Brief vom Treasury Department an Max Horkheimer, 11.02.1937; 1 Brief von Edith A. Trotter an Max Horkheimer, 13.02.1941; 2 Briefe zwischen The Twentieth Century Fund und Max Horkheimer, 22.12.1942, 02.01.1943; 4 Briefe zwischen Robert Ulich und F. Pollock, 1936, 10.04.1941, 1941; 1 Brief von Max Horkheimer an United States of America Commissioner for Immigration and Naturalisation, 01.11.1940; 1 Brief von Max Horkheimer an das United States of America Department of Agriculture, 15.01.1940; 1 Brief von Max Horkheimer an das United States of America Department of State, 07.10.1941; 1 Brief von Herbert Marcuse an das United States of America Department of State, 07.10.1941; 1 Brief von Max Horkheimer an das Universität Frankfurt Kuratorium der Johann Wolfgang Goethe Universität, 05.07.1935; 1 Briefkopie von Max Horkheimer an die Universität Frankfurt, Der Rektor, 28.07.1933; 1 Brief und 1 Beilage von der University of Buffalo an Max Horkheimer, 06.03.1940; 5 Briefe zwischen der University of California Berkeley und Max Horkheimer, 1940; 2 Briefe zwischen der University of Colorado Libraries und Max Horkheimer, 17.10.1940, 25.10.1940; 3 Briefe zwischen der University of Newark und Max Horkheimer, 1935, 08.04.1938, 1938; 6 Briefe zwischen Jiri Veltruský und Max Horkheimer, 1948-1949; 1 Brief von Leon Verhille an Max Horkheimer, 19.12.1949; 5 Briefe zwischen Salka Viertel und Max Horkheimer, 1938, 1940; 1 Heiratsanzeige von Edward Walter Violin, 1949; 1 Notiz von Max Horkheimer an Edward Walter Violin; 1 Brief von Stitschan Voehard an Max Horkheimer, 03.01.1950;

Chemistry of interstitial waters of samples from DSDP Leg 25

Interstitial water analyses from sediments collected during Leg 25 of the Deep Sea Drilling Project have revealed that in the southwest Indian Ocean, great chemical activity exists in sediments in various depositional environments. Variable sedimentation rates allow us to set some interesting boundary conditions on chemical and transport processes in these interstitial waters, particularly with regard to the distribution of dissolved sulfate. In terrigenous rapidly deposited sediments, large depletions are observed in magnesium and potassium, whereas relatively small decreases in dissolved calcium occur. In slowly deposited detrital sediments, also, large decreases in potassium and magnesium coincide with very large calcium increases. In truly pelagic sediments, a one to one replacement of magnesium by calcium is observed in the interstitial waters, presumably due to reactions in the basal sediment layers. Biogenous deposits have great influence on dissolved silica (sponge spicules and radiolarians) and on dissolved strontium (carbonate recrystallization). Otherwise, dissolved silica reflects the clay mineralogy and shows variations which seem particularly dependent on the presence or absence of kaolinite. Variable dissolved manganese values reflect reducing conditions and/or availability of manganese in the solid phases for mobilization in reducing sediments.

Amino acid in Deep Sea Drilling Project cores

Several amino acid diagenetic reactions, which take place in the deep-sea sedimentary environment, were investigated, using various Deep Sea Drilling Project (DSDP) cores. Initially it was found that essentially all the amino acids in sediments are bound in peptide linkages; but, with increasing age, the peptide bonds undergo slow hydrolysis that results in an increasingly larger fraction of amino acids in the free state. The hydrolysis half-life in calcareous sediments was estimated to be ~1-2 million years, while in non-carbonate sediment the hydrolysis rate may be considerably slower. The amino acid compositions and the extent of racemization of several amino acids were determined in various fractions isolated from the sediments. These analyses demonstrated that the mechanism, kinetics, and rate of amino acid diagenesis are highly dependent upon the physical state (i.e., free, bound, etc.) in which the amino acids exist in the sedimentary environment. In the free state, serine and threonine were found to decompose primarily by a dehydration reaction, while in the bound state (residue or HCl-insoluble fraction) a reversible aldol-cleavage reaction is the main decomposition pathway of these amino acids. The change in amino acid composition of the residue fraction with time was suggested to be due to the hydrolysis of peptide bonds, while in foraminiferal tests the compositional changes over geological time are the result of various decomposition reactions. Reversible first-order racemization kinetics are not observed for free amino acids in sediments. The explanation for these anomalous kinetics involves a complex reaction series which includes the hydrolysis of peptide bonds and the very rapid racemization of free amino acids. The racemization rates of free amino acids in sediments were found to be many orders of magnitude faster than those predicted from elevated temperature experiments using free amino acids in aqueous solution. The racemization rate enhancement of free amino acids in sediments may be due to the catalysis of the reaction by trace metals. Reversible first-order kinetics are followed for amino acids in the residue fraction isolated from sediments; the rate of racemization in this fraction is slower than that predicted for protein-bound amino acids. Various applications of amino acid diagenetic reactions are discussed. Racemization and the decomposition reaction of serine and threonine can both be used, with certain limitations, to make rough age estimates of deep-sea sediments back to several million years. The extent of racemization in foraminiferal tests which have been dated by some other independent technique can be used to estimate geothermal gradients, and thus heat flows, and to evaluate the bottom water temperature history in certain oceanic areas.