1501 BH17 NP 2014

Brown sediment with clasts ranging from small to large in size. Clast shape ranges from angular to sub-rounded. Lineations and comet structures are commonly seen throughout the sample. Rotation structures with and without central grains can also be seen.

1507 BH17 NP 2014

Brown sediment with clasts ranging from small to large in size. Clast shape ranges from angular to rounded. Lineations and rotation structures were abundant in this sample, Rotation structures were seen with and without central grains. Comet structures were also present in this sample along with minor amounts of grain stacking.

1520 BH17 NP 2014

Dark brown sediment with clasts ranging from small to large in size. Clast shape ranges from angular to sub-rounded. Lineations can be seen throughout the sample, along with a few rotation and comet structures. This sample also contains a fine grained clay domain that is relatively structure-less. It can be seen scattered throughout the sample.

1523 BH17 NP 2014

Brown sediment with clasts ranging from small to large in size. Clast shape ranges from angular to sub-rounded. Lineations and rotation structures are abundant throughout the sample. Comet structures can also be seen. Minor amounts of grains crushing/stacking are also present.

1526 BH17 NP 2014

Brown sediment with clasts ranging from small to medium in size. Clast shape ranges from angular to sub-rounded. Rotation structures and comet structures are commonly seen throughout this sample. Lineations are also common. Minor amounts of grain stacking can also be seen. Some grains appear to be fractured and/or weathered.

1539 BH17 NP 2014

Brown sediment with clasts ranging from small to large. Clast shape ranges from angular to sub-rounded. Lineations are common throughout the sample. This sample also contains a clay domain, that appears very fine grained. Edge-to-edge grain crushing, comet structures, and rotation structures are also present.

1542 BH17 NP 2014

Brown sediment with clasts ranging from small to large. Clast shape ranges from angular to sub-rounded. Lineations and rotation structures are scattered throughout the entire sample. Comet structures are also present. Minor amounts of grain stacking can also be seen.

1544 BH17 NP 2014

Brown sediment with inclusions of a clay rich domain. Clasts range from small to medium in size and angular to sub-rounded in shape. Lineations can be commonly seen throughout the sample, along with water escape structures in the clay rich domain. Rotation structures, comet structures, and grain crushing are also present.

Processability, hardness, andmagnetic properties of rubber ferrite composites containingmanganese zinc ferrites

Rubber ferrite composites have the unique advantage of mouldability, which is not easily obtainable using ceramic magnetic materials. The incorporation of mixed ferrites in appropriate weight ratios into the rubber matrix not only modi es the dielectric properties of the composite but also imparts magnetic properties to it. Mixed ferrites belonging to the series of Mn(1 – x )Znx Fe2O4 have been synthesised with diVerent values of x in steps of 0·2, using conventional ceramic processing techniques. Rubber ferrite composites were prepared by the incorporation of these pre-characterised polycrystallineMn(1 – x )Znx Fe2O4 ceramics into a natural rubber matrix at diVerent loadings according to a speci c recipe. The processability of these elastomers was determined by investigating their cure characteristics. The magnetic properties of the ceramic llers as well as of the rubber ferrite composites were evaluated and the results were correlated. Studies of the magnetic properties of these rubber ferrite composites indicate that the magnetisation increases with loading of the ller without changing the coercive eld. The hardness of these composites shows a steady increase with the loading of the magnetic llers. The evaluation of hardness andmagnetic characteristics indicates that composites with optimummagnetisation and almost minimum stiVness can be achieved with a maximum loading of 120 phr of the ller at x=0·4. From the data on the magnetisation of the composites, a simple relationship connecting the magnetisation of the rubber ferrite composite and the ller was formulated. This can be used to synthesise rubber ferrite composites with predetermined magnetic properties

The hardness profile as a tool to detect spurious stationary points in the potential energy surface

The energy and hardness profile for a series of inter and intramolecular conformational changes at several levels of calculation were computed. The hardness profiles were found to be calculated as the difference between the vertical ionization potential and electron affinity. The hardness profile shows the correct number of stationary points independently of the basis set and methodology used. It was found that the hardness profiles can be used to check the reliability of the energy profiles for those chemical system

Are the maximum hardness and minimum polarizability principles always obeyed in nontotally symmetric vibrations?

An overview is given on a study which showed that not only in chemical reactions but also in the favorable case of nontotally symmetric vibrations where the chemical and external potentials keep approximately constant, the generalized maximum hardness principle (GMHP) and generalized minimum polarizability principle (GMPP) may not be obeyed. A method that allows an accurate determination of the nontotally symmetric molecular distortions with more marked GMPP or anti-GMPP character through diagonalization of the polarizability Hessian matrix is introduced

Degradation and plant uptake of nonylphenol (NP) and nonylphenol-12-ethoxylate (NP12EO) in four contrasting agricultural soils

Nonylphenol polyethoxylates (NPEOs) are surfactants found ubiquitously in the environment due to widespread industrial and domestic use. Biodegradation of NPEOs produces nonylphenol (NP), an endocrine disruptor. Sewage sludge application introduces NPEOs and NP into soils, potentially leading to accumulation in soils and crops. We examined degradation of NP and nonyl phenol-12-ethoxylate (NP12EO) in four soils. NP12EO degraded rapidly (initial half time 0.3-5 days). Concentrations became undetectable within 70-90 days, with a small increase in NP concentrations after 30 days. NP initially degraded quickly (mean half time 11.5 days), but in three soils a recalcitrant fraction of 26-35% remained: the non-degrading fraction may consist of branched isomers, resistant to biodegradation. Uptake of NP by bean plants was also examined. Mean bioconcentration factors for shoots and seeds were 0.71 and 0.58, respectively. Removal of NP from the soil by plant uptake was negligible (0.01-0.02% of initial NP). Root concentrations were substantially higher than shoot and seed concentrations. (C) 2008 Elsevier Ltd. All rights reserved.