A reconstruction of atmospheric carbon dioxide and its stable carbon isotopic composition from the penultimate glacial maximum to the glacial inception

The reconstruction of the stable carbon isotope evolution in atmospheric CO2 (d13Catm ), as archived in Antarctic ice cores, bears the potential to disentangle the contributions of the different carbon cycle fluxes causing past CO2 variations. Here we present a new record of d13Catm before, during and after the Marine Isotope Stage 5.5 (155 000 to 105 000 years BP). The record was derived with a well established sublimation method using ice from the EPICA Dome C (EDC) and the Talos Dome ice cores in East Antarctica. We find a 0.4 permil shift to heavier values between the mean d13Catm level in the Penultimate (~ 140 000 years BP) and Last Glacial Maximum (~ 22 000 years BP), which can be explained by either (i) changes in the isotopic composition or (ii) intensity of the carbon input fluxes to the combined ocean/atmosphere carbon reservoir or (iii) by long-term peat buildup. Our isotopic data suggest that the carbon cycle evolution along Termination II and the subsequent interglacial was controlled by essentially the same processes as during the last 24 000 years, but with different phasing and magnitudes. Furthermore, a 5000 years lag in the CO2 decline relative to EDC temperatures is confirmed during the glacial inception at the end of MIS 5.5 (120 000 years BP). Based on our isotopic data this lag can be explained by terrestrial carbon release and carbonate compensation.

Planktic foraminiferal Mg/Ca and oxygen isotopes, plus estimated d18Oseawater and ice volume corrected d18Oseawater for the past 35000 years of sediment core GeoB10069-3

Evidence from geologic archives suggests that there were large changes in the tropical hydrologic cycle associated with the two prominent northern hemisphere deglacial cooling events, Heinrich Stadial 1 (HS1; ~19 to 15 kyr BP; kyr BP = 1000 yr before present) and the Younger Dryas (~12.9 to 11.7 kyr BP). These hydrologic shifts have been alternatively attributed to high and low latitude origin. Here, we present a new record of hydrologic variability based on planktic foraminifera-derived d18O of seawater (d18Osw) estimates from a sediment core from the tropical Eastern Indian Ocean, and using 12 additional d18Osw records, construct a single record of the dominant mode of tropical Eastern Equatorial Pacific and Indo-Pacific Warm Pool (IPWP) hydrologic variability. We show that deglacial hydrologic shifts parallel variations in the reconstructed interhemispheric temperature gradient, suggesting a strong response to variations in the Atlantic Meridional Overturning Circulation and the attendant heat redistribution. A transient model simulation of the last deglaciation suggests that hydrologic changes, including a southward shift in the Intertropical Convergence Zone (ITCZ) which likely occurred during these northern hemisphere cold events, coupled with oceanic advection and mixing, resulted in increased salinity in the Indonesian region of the IPWP and the eastern tropical Pacific, which is recorded by the d18Osw proxy. Based on our observations and modeling results we suggest the interhemispheric temperature gradient directly controls the tropical hydrologic cycle on these time scales, which in turn mediates poleward atmospheric heat transport.

Age determination and paleomagnetic investigations on a sediment profile from laguna Potrok Aike

Paleomagnetic inclination, declination and relative paleointensity were reconstructed from the sediments of Laguna Potrok Aike in the framework of the International Continental scientific Drilling Program (ICDP) Potrok Aike maar lake Sediment Archive Drilling prOject (PASADO). Here we present the u-channel-based full vector paleomagnetic field reconstruction since 51.2 ka cal BP. The relative paleointensity proxy (RPI) was built by normalising the natural remanent magnetisation with the anhysteretic remanent magnetisation using the average ratio at 4 demagnetisation steps part of the ChRM interval (NRM/ARM10e40 mT). A grain size influence on the RPI was removed using a correction based on the linear relationship between the RPI and the median destructive field of the natural remanent magnetisation (MDFNRM). The new record is compared with other lacustrine and marine records and stacks from the mid- to high-latitudes of the Southern Hemisphere, revealing consistent millennial-scale variability, the identification of the Laschamp and possibly the Mono Lake geomagnetic excursions, and a direction swing possibly associated to the Hilina Pali excursion at 20 ka cal BP. Nonetheless, a global-scale comparison with other high-resolution records located on the opposite side of the Earth and with various dipole field references hint at a different behaviour of the geomagnetic field around southern South America at 46 ka cal BP.

(Table 1) Seasonal sea ice concentration and the observed changes from 1972 to 2007 for the Southern Beaufort Sea

A reliable data set of Arctic sea ice concentration based on satellite observations exists since 1972. Over this time period of 36 years western arctic temperatures have increased; the temperature rise varies significantly from one season to another and over multi-year time scales. In contrast to most of Alaska, however, on the North Slope the warming continued after 1976, when a circulation change occurred, as expressed in the PDO index. The mean temperature increase for Barrow over the 36-year period was 2.9°C, a very substantial change. Wind speeds increased by 18% over this time period, however, the increase were non-linear and showed a peak in the early 1990s. The sea ice extent of the Arctic Ocean has decreased strongly in recent years, and in September 2007 a new record in the amount of open water was recorded in the Western Arctic. We observed for the Southern Beaufort Sea a fairly steady increase in the mean annual amount of open water from 14% in 1972 to 39% in 2007, as deduced from the best linear fit. In late summer the decrease is much larger, and September has, on average, the least ice concentration (22%), followed by August (35%) and October (54%). The correlation coefficient between mean annual values of temperature and sea ice concentration was 0.84. On a monthly basis, the best correlation coefficient was found in October with 0.88. However, the relationship between winter temperatures and the sea ice break-up in summer was weak. While the temperature correlated well with the CO2 concentration (r=0.86), the correlation coefficient between CO2 and sea ice was lower (r=-0.68). After comparing the ice concentration with 17 circulation indices, the best relation was found with the Pacific Circulation Index (r=-0.59).

Stable isotope stacks from GRIP and GISP ice cores

Recent efforts to link the isotopic composition of snow in Greenland with meteorological and climatic parameters have indicated that relatively local information such as observed annual temperatures from coastal Greenland sites, as well as more synoptic scale features such as the North Atlantic Oscillation (NAO) and the temperature seesaw between Jakobshaven, Greenland, and Oslo, Norway, are significantly correlated with d18O and dD values from the past few hundred years measured in ice cores. In this study we review those efforts and then use a new record of isotope values from the Greenland Ice Sheet Project 2 and Greenland Ice Core Project sites at Summit, Greenland, to compare with meteorological and climatic parameters. This new record consists of six individual annually resolved isotopic records which have been average to produce a Summit stacked isotope record. The stacked record is significantly correlated with local Greenland temperatures over the past century (r=0.471), as well as a number of other records including temperatures and pressures from specific locations as well as temperature and pressure patterns such as the temperature seesaw and the North Atlantic Oscillation. A multiple linear regression of the stacked isotope record with a number of meteorological and climatic parameters in the North Atlantic region reveals that five variables contribute significantly to the variance in the isotope record: winter NAO, solar irradiance (as recorded by sunspot numbers), average Greenland coastal temperature, sea surface temperature in the moisture source region for Summit (30°-20°N), and the annual temperature seesaw between Jakobshaven and Oslo. Combined, these variables yield a correlation coefficient of r=0.71, explaining half of the variance in the stacked isotope record.

Characteristics of the deep ocean carbon system during the past 150,000 years: ΣCO2 distributions, deep water flow patterns, and abrupt climate change

Studies of carbon isotopes and cadmium in bottom-dwelling foraminifera from ocean sediment cores have advanced our knowledge of ocean chemical distributions during the late Pleistocene. Last Glacial Maximum data are consistent with a persistent high-ΣCO2 state for eastern Pacific deep water. Both tracers indicate that the mid-depth North and tropical Atlantic Ocean almost always has lower ΣCO2 levels than those in the Pacific. Upper waters of the Last Glacial Maximum Atlantic are more ΣCO2-depleted and deep waters are ΣCO2-enriched compared with the waters of the present. In the northern Indian Ocean, δ13C and Cd data are consistent with upper water ΣCO2 depletion relative to the present. There is no evident proximate source of this ΣCO2-depleted water, so I suggest that ΣCO2-depleted North Atlantic intermediate/deep water turns northward around the southern tip of Africa and moves toward the equator as a western boundary current. At long periods (>15,000 years), Milankovitch cycle variability is evident in paleochemical time series. But rapid millennial-scale variability can be seen in cores from high accumulation rate series. Atlantic deep water chemical properties are seen to change in as little as a few hundred years or less. An extraordinary new 52.7-m-long core from the Bermuda Rise contains a faithful record of climate variability with century-scale resolution. Sediment composition can be linked in detail with the isotope stage 3 interstadials recorded in Greenland ice cores. This new record shows at least 12 major climate fluctuations within marine isotope stage 5 (about 70,000–130,000 years before the present).

Nuevo registro de Thorectes valencianus Baraud, 1966 (Coleoptera: Geotrupidae) para el sudeste iberolevantino (España)

En este trabajo se aporta una nueva cita para Thorectes valencianus (Coleoptera: Geotrupidae). Este coleóptero es un endemismo iberolevantino catalogado como Vulnerable en la lista roja de la UICN y localizado en la sierra de Escalona (Orihuela, Alicante).

Evolution of the stable carbon isotope composition of atmospheric CO₂ over the last glacial cycle

We present new δ¹³C measurements of atmospheric CO₂ covering the last glacial/interglacial cycle, complementing previous records covering Terminations I and II. Most prominent in the new record is a significant depletion in δ¹³C(atm) of 0.5‰ occurring during marine isotope stage (MIS) 4, followed by an enrichment of the same magnitude at the beginning of MIS 3. Such a significant excursion in the record is otherwise only observed at glacial terminations, suggesting that similar processes were at play, such as changing sea surface temperatures, changes in marine biological export in the Southern Ocean (SO) due to variations in aeolian iron fluxes, changes in the Atlantic meridional overturning circulation, upwelling of deep water in the SO, and long-term trends in terrestrial carbon storage. Based on previous modeling studies, we propose constraints on some of these processes during specific time intervals. The decrease in δ¹³C(atm) at the end of MIS 4 starting approximately 64 kyr B.P. was accompanied by increasing [CO₂]. This period is also marked by a decrease in aeolian iron flux to the SO, followed by an increase in SO upwelling during Heinrich event 6, indicating that it is likely that a large amount of δ¹³C-depleted carbon was transferred to the deep oceans previously, i.e., at the onset of MIS 4. Apart from the upwelling event at the end of MIS 4 (and potentially smaller events during Heinrich events in MIS 3), upwelling of deep water in the SO remained reduced until the last glacial termination, whereupon a second pulse of isotopically light carbon was released into the atmosphere.

Stable isotope ratios of epibenthic foraminifer Cibicidoides wuellerstorfi from sediment profile GeoB9526

Studies of temporal changes of ocean circulation and deep-water ventilation often rely on d13C records of epibenthic foraminifer Cibicidoides wuellerstorfi. However, primary productivity related overprints may distort the signal and simulate a chemical age of ambient water mass that is too old and simulates poorly ventilated ambient bottom waters. To further constrain the use of C. wuellerstorfi d13C records from high-productivity areas, we analyzed a 14CAMS-dated gravity core from the upwelling regime off northwest Africa at 12°N. We compare this new record with 37 radiocarbon dated d13C records from the eastern Atlantic Ocean between 45°N and 25°S that are bathed by the same water mass. Only during Heinrich events 1 and 2, when the investigated core site off northwest Africa experienced year-round, sustained deposition of organic matter, the d13C values at this site faithfully record deep-water ventilation states. During times of predominantly seasonal deposition of fresh phytodetritus, however, d13C values were significantly lower than at the reference sites. This underscores that reconstruction of paleocirculation and deep ocean ventilation using C. wuellerstorfi d13C from regions that experienced seasonal phytodetritus deposition needs to be validated by additional proxies that are not affected by local productivity.

Summary of boron isotope and Mg/Ca data

Biological productivity and carbon export in the equatorial Atlantic are thought to have been dramatically higher during the last glacial period than during the Holocene. Here we reconstruct the pH and CO2 content of surface waters from the eastern equatorial Atlantic Ocean over the past ~30 k.y. using the boron isotope composition of Globigerinoides ruber (a mixed-layer-dwelling planktic foraminifera). Our new record, combined with previously published data, indicates that during the last glacial, in contrast to today, a strong west to east gradient existed in the extent of air:sea equilibrium with respect to pCO2 (DeltapCO2), with the eastern equatorial Atlantic acting as a significant source of CO2 (+100 µatm) while the western Atlantic remained close to equilibrium (+25 µatm). This pattern suggests that a fivefold increase in the upwelling rate of deeper waters drove increased Atlantic productivity and large-scale regional cooling during the last glacial, but the higher than modern DeltapCO2 in the east indicates that export production did not keep up with enhanced upwelling of nutrients. However, the downstream decline of DeltapCO2 provides evidence that the unused nutrients from the east were eventually used for biologic carbon export, thereby effectively negating the impact of changes in upwelling on atmospheric CO2 levels. Our findings indicate that the equatorial Atlantic exerted a minimal role in contributing to lower glacial-age atmospheric CO2.

Stable isotopes and XRF data over the Paleocene-Eocene Thermal Maximum from IODP Sites U1403 and U1409

During the Paleocene-Eocene Thermal Maximum (PETM) about 56 million years ago, thousands of petagrams of carbon were released into the atmosphere and ocean in just a few thousand years, followed by a gradual sequestration over approximately 200,000 years. If silicate weathering is one of the key negative feedbacks that removed this carbon, a period of seawater calcium carbonate saturation greater than pre-event levels is expected during the event's recovery phase. In marine sediments, this should be recorded as a temporary deepening of the depth below which no calcite is preserved - the calcite compensation depth (CCD). Previous and new sedimentary records from sites that were above the pre-PETM calcite compensation depth show enhanced carbonate accumulation following the PETM. A new record from an abyssal site in the North Atlantic that lay below the pre-PETM calcite compensation depth shows a period of carbonate preservation beginning about 70,000 years after the onset of the PETM, providing the first direct evidence for an over-deepening of the calcite compensation depth. This record confirms an overshoot in ocean carbonate saturation during the PETM recovery. Simulations with two earth system models support scenarios for the PETM that involve both a large initial carbon release followed by prolonged low-level emissions, consistent with the timing of CCD deepening in our record. Our findings indicate that sequestration of these carbon emissions was most likely the result of both globally enhanced calcite burial above the calcite compensation depth and, at least in the North Atlantic, by a temporary over-deepening of the calcite compensation depth.

50 year means of oxygen isotope data from ice core NGRIP

Two deep ice cores from central Greenland, drilled in the 1990s, have played a key role in climate reconstructions of the Northern Hemisphere, but the oldest sections of the cores were disturbed in chronology owing to ice folding near the bedrock. Here we present an undisturbed climate record from a North Greenland ice core, which extends back to 123,000 years before the present, within the last interglacial period. The oxygen isotopes in the ice imply that climate was stable during the last interglacial period, with temperatures 5 °C warmer than today. We find unexpectedly large temperature differences between our new record from northern Greenland and the undisturbed sections of the cores from central Greenland, suggesting that the extent of ice in the Northern Hemisphere modulated the latitudinal temperature gradients in Greenland. This record shows a slow decline in temperatures that marked the initiation of the last glacial period. Our record reveals a hitherto unrecognized warm period initiated by an abrupt climate warming about 115,000 years ago, before glacial conditions were fully developed. This event does not appear to have an immediate Antarctic counterpart, suggesting that the climate see-saw between the hemispheres (which dominated the last glacial period) was not operating at this time.

Design principles of semantic binary database management systems

The Semantic Binary Data Model (SBM) is a viable alternative to the now-dominant relational data model. SBM would be especially advantageous for applications dealing with complex interrelated networks of objects provided that a robust efficient implementation can be achieved. This dissertation presents an implementation design method for SBM, algorithms, and their analytical and empirical evaluation. Our method allows building a robust and flexible database engine with a wider applicability range and improved performance. ^ Extensions to SBM are introduced and an implementation of these extensions is proposed that allows the database engine to efficiently support applications with a predefined set of queries. A New Record data structure is proposed. Trade-offs of employing Fact, Record and Bitmap Data structures for storing information in a semantic database are analyzed. ^ A clustering ID distribution algorithm and an efficient algorithm for object ID encoding are proposed. Mapping to an XML data model is analyzed and a new XML-based XSDL language facilitating interoperability of the system is defined. Solutions to issues associated with making the database engine multi-platform are presented. An improvement to the atomic update algorithm suitable for certain scenarios of database recovery is proposed. ^ Specific guidelines are devised for implementing a robust and well-performing database engine based on the extended Semantic Data Model. ^

O gênero Geastrum Pers. (Geastraceae, Basidiomycota): ocorrência, chave taxonômica e descrições de novas espécies do Nordeste brasileiro

Geastraceae is a monophyletic family included in the gomphoid-phalloid clade, it is composed only by two genus: Geastrum and Myriostoma. These genus are closely related in their morphology and phylogeny, both showing angiocarpic basidiomata, apical stoma, basidiospores passively released by the bellows mechanism and exoperidium dehiscent in rays, these genus are distinct by the number of stomas and pedicels. Because of dehiscense of exoperidium they are popularly known as “earthstars”. Usually they occur on decomposing leaf-litter and decaying wood. They are, thus, saprophytic, with rare exceptions of ectomycorrhizal species. Geastrum is the most diverse gasteroid genus in Brazil, with an estimated 51 records. However, there are large gaps in the geographic distribution and systematics studies about the Geastrum in this country, especially because of the characteristics found in the Brazilian territory (megadiverse, hotspots and continental size), which makes it a priority area for species inventory. Thus, this work was aimed at realizing inventory of species of Geastrum, which occur in Caatinga and Northeastern Atlantic Rainforest. At least two field expeditions were realized, during about four days on rainy season of 2013 and 2014 in the areas: Reserva Biológica de Guaribas, located in Atlantic Rainforest domain, Paraíba State and Reserva Ecológica Estadual Mata do Pau Ferro, located on “Brejos Paraibanos”, Paraíba State. Furthermore, specimens deposited in the Herbarium of the Universidade Federal do Rio Grande do Norte, which were collected in Parque Nacional Vale do Catimbau, Caatinga of Pernambuco State, were analyzed. The specimens were identified according to analysis of macro and micro morphology based on specific literature. Approximately 400 basidiomata, distributed in 73 exsiccates were analyzed. 21 species were identified, 19 are in specie level, which two are proposed to new species. (Geastrum magnosporum sp. nov. e G. pusillupilosum sp. nov.) and two in genera level (sp. e aff.). We emphasize one new record for Brazil, 12 new records for Paraíba State, four new records for semiarid region in Brazil and six new records to Atlantic Rainforest relicts “Brejo de Altitude”. So, the results improved the knowledge about Geastrum in Paraíba State by 200%, 24 % in Brazilian semiarid region and 55% in Atlantic Rainforest relicts “Brejo de Altitude”, evincing that Northeastern Brazil has high species richness.

CO2 concentration and stable isotope ratios of three Antarctic ice cores covering the period from 149.4 - 1.5 kyr before 1950

We present new d13C measurements of atmospheric CO2 covering the last glacial/interglacial cycle, complementing previous records covering Terminations I and II. Most prominent in the new record is a significant depletion in d13C(atm) of 0.5 permil occurring during marine isotope stage (MIS) 4, followed by an enrichment of the same magnitude at the beginning of MIS 3. Such a significant excursion in the record is otherwise only observed at glacial terminations, suggesting that similar processes were at play, such as changing sea surface temperatures, changes in marine biological export in the Southern Ocean (SO) due to variations in aeolian iron fluxes, changes in the Atlantic meridional overturning circulation, upwelling of deep water in the SO, and long-term trends in terrestrial carbon storage. Based on previous modeling studies, we propose constraints on some of these processes during specific time intervals. The decrease in d13C(atm) at the end of MIS 4 starting approximately 64 kyr B.P. was accompanied by increasing [CO2]. This period is also marked by a decrease in aeolian iron flux to the SO, followed by an increase in SO upwelling during Heinrich event 6, indicating that it is likely that a large amount of d13C-depleted carbon was transferred to the deep oceans previously, i.e., at the onset of MIS 4. Apart from the upwelling event at the end of MIS 4 (and potentially smaller events during Heinrich events in MIS 3), upwelling of deep water in the SO remained reduced until the last glacial termination, whereupon a second pulse of isotopically light carbon was released into the atmosphere.