Rheology and the breadmaking process

The applications of rheology to the main processes encountered during breadmaking (mixing, sheeting, fermentation and baking) are reviewed. The most commonly used rheological test methods and their relationships to product functionality are reviewed. It is shown that the most commonly used method for rheological testing of doughs, shear oscillation dynamic rheology, is generally used under deformation conditions inappropriate for breadmaking and shows little relationship with end-use performance. The frequency range used in conventional shear oscillation tests is limited to the plateau region, which is insensitive to changes in the HMW glutenin polymers thought to be responsible for variations in baking quality. The appropriate deformation conditions can be accessed either by long-time creep or relaxation measurements, or by large deformation extensional measurements at low strain rates and elevated temperatures. Molecular size and structure of the gluten polymers that make up the major structural components of wheat are related to their rheological properties via modern polymer rheology concepts. Interactions between polymer chain entanglements and branching are seen to be the key mechanisms determining the rheology of HMW polymers. Recent work confirms the observation that the dynamic shear plateau modulus is essentially independent of variations in MW of glutens amongst wheat varieties of varying baking performance and also that it is not the size of the soluble glutenin polymers, but the secondary structural and rheological properties of the insoluble polymer fraction that are mainly responsible for variations in baking performance. Extensional strain hardening has been shown to be a sensitive indicator of entanglements and long-chain branching in HMW polymers, and is well related to baking performance of bread doughs. The Considere failure criterion for instability in extension of polymers defines a region below which bubble walls become unstable, and predicts that when strain hardening falls below a value of around 1, bubble walls are no longer stable and coalesce rapidly, resulting in loss of gas retention and lower volume and texture. Strain hardening in doughs has been shown to reach this value at increasingly higher temperatures for better breadmaking varieties and is directly related to bubble stability and baking performance. (C) 2003 Elsevier Ltd. All rights reserved.

Resistance to the first and second generation anticoagulant rodenticides: a new perspective

Warfarin resistance was first discovered among Norway rat (Rattus norvegicus) populations in Scotland in 1958 and further reports of resistance, both in this species and in others, soon followed from other parts of Europe and the United States. Researchers quickly defined the practical impact of these resistance phenomena and developed robust methods by which to monitor their spread. These tasks were relatively simple because of the high degree of immunity to warfarin conferred by the resistance genes. Later, the second generation anticoagulants were introduced to control rodents resistant to the warfarin-like compounds, but resistance to difenacoum, bromadiolone and brodifacoum is now reported in certain localities in Europe and elsewhere. However, the adoption of test methods designed initially for use with the first generation compounds to identify resistance to compounds of the second generation has led to some practical difficulties in conducting tests and in establishing meaningful resistance baselines. In particular, the results of certain test methodologies are difficult to interpret in terms of the likely impact on practical control treatments of the resistance phenomena they seek to identify. This paper defines rodenticide resistance in the context of both first and second generation anticoagulants. It examines the advantages and disadvantages of existing laboratory and field methods used in the detection of rodent populations resistant to anticoagulants and proposes some improvements in the application of these techniques and in the interpretation of their results.

Genotoxic effects of X-rays on keratinized mucosa cells during panoramic dental radiography

Objectives: The aim of this study was to evaluate the genotoxic effects of X-rays on epithelial gingival cells during panoramic dental radiography using a differentiated protocol for the micronucleus test. Methods: 40 healthy individuals who underwent this procedure for diagnostic purposes on request from their dentists agreed to participate in this study. All of them answered a questionnaire before the examination. Epithelial gingival cells were obtained from the keratinized mucosa of the upper dental arcade by gentle scraping with a cervical brush immediately before exposure and 10 days later. Cytological preparations were stained according to the Feulgen-Rossenbeck reaction, counterstained with fast green 1% for 1 min and analysed under a light microscope. Micronuclei, nuclear projections (broken eggs) and degenerative nuclear alterations (pyknosis, karyolysis, karyorrhexis and condensed chromatin) were scored. Results: The frequency of micronuclei was significantly higher after exposure (P < 0.05), as were frequencies of nuclear alterations indicate of apoptosis (P < 0.001). Conclusions: These results indicate that X-ray radiation emitted during panoramic dental radiography induces a genotoxic effect on epithelial gingival cells that increases the frequency of chromosomal damage and nuclear alterations indicative of apoptosis.

Evaluation of surface treatment techniques for polypropylene andimplementation of a method for testing ink adhesion

If a plastic material is used as a print bearer there are a need of a special surface treatment to get agod and durable printing. The most used surface treatment technique for the moment is coronatreatment. This kind of treatment has unfortunately showed not to be so durable in the long term.Plasma treatment which in this case uses different kind of gases in the treatment of polypropyleneis shown as a more effective treatment in this project. When the plasma treated surface has beenprinted is the good quality last much longer and the adhesion between the ink and the surface isremained. To test this adhesion is for the moment a standard used (ASTM D3359). This standardhas appeared unstable and dependent at many different factors, which gives a big variation in thetest results. Because of this has new test methods been carried out to give a more even and morereliable result in the test of the adhesion.

Influence of surface texture on the galling characteristics of lean duplex and austenitic stainless steels

Two simulative test methods were used to study galling in sheet forming of two types of stainlesssteel sheet: austenitic (EN 1.4301) and lean duplex LDX 2101 (EN 1.4162) in different surface conditions. Thepin-on-disc test was used to analyse the galling resistance of different combinations of sheet materials and lubricants. The strip reduction test, a severe sheet forming tribology test was used to simulate the conditionsduring ironing. This investigation shows that the risk of galling is highly dependent on the surface texture of theduplex steel. Trials were also performed in an industrial tool used for high volume production of pumpcomponents, to compare forming of LDX 2101 and austenitic stainless steel with equal thickness. The forming forces, the geometry and the strains in the sheet material were compared for the same component.It was found that LDX steels can be formed to high strain levels in tools normally applied for forming ofaustenitic steels, but tool adaptations are needed to comply with the higher strength and springback of thematerial.

Thermal Performance of a Solarus CPC-Thermal Collector

The  aim  of  this  master  thesis  is  an  investigation  of  the  thermal  performance  of  a  thermal compound parabolic concentrating (CPC) collector from Solarus. The collector consists of two troughs with absorbers which are coated with different types of paint with  unknown  properties.  The  lower  and  upper  trough  of  the  collector  have  been  tested individually. In  order  to  accomplish  the  performance  of  the  two  collectors,  a  thorough  literature  study  in  the  fields  of  CPC  technology,  various  test  methods,  test  standards  for  solar thermal  collectors  as  well  as  the  latest  articles  relating  on  the  subject  were  carried  out. In addition, the set‐up of the thermal test rig was part of the thesis as well. The thermal  performance  was  tested  according  to  the  steady  state  test  method  as  described in the European standard 12975‐2. Furthermore, the thermal performance of  a  conventional  flat  plate  collector  was  carried  out  for  verification  of  the  test  method. The  CPC‐Thermal  collector  from  Solarus  was  tested  in  2013  and  the  results  showed  four  times  higher  values  of  the  heat  loss  coefficient  UL (8.4  W/m²K)  than  what  has been reported for a commercial collector from Solarus. This value was assumed to be too large and it was assumed that the large value was a result of the test method used that time. Therefore, another aim was the comparison of the results achieved in this work with the results from the tests performed in 2013. The results of the thermal performance showed that the optical efficiency of the lower trough of the CPC‐T collector is 77±5% and the corresponding heat loss coefficient UL 4.84±0.20  W/m²K.  The  upper  trough  achieved  an  optical  efficiency  of  75±6  %  and  a  heat loss coefficient UL of 6.45±0.27 W/m²K. The results of the heat loss coefficients  are  valid  for  temperature  intervals  between  20°C  and  80°C.  The  different  absorber paintings have a significant impact on the results, the lower trough performs overall better.  The  results  achieved  in  this  thesis  show  lower  heat  loss  coefficients UL and higher optical efficiencies compared to the results from 2013. 

Dynamic whole system testing of combined renewable heating systems : the current state of the art

Objective: For the evaluation of the energetic performance of combined renewable heating systems that supply space heat and domestic hot water for single family houses, dynamic behaviour, component interactions, and control of the system play a crucial role and should be included in test methods. Methods: New dynamic whole system test methods were developed based on “hardware in the loop” concepts. Three similar approaches are described and their differences are discussed. The methods were applied for testing solar thermal systems in combination with fossil fuel boilers (heating oil and natural gas), biomass boilers, and/or heat pumps. Results: All three methods were able to show the performance of combined heating systems under transient operating conditions. The methods often detected unexpected behaviour of the tested system that cannot be detected based on steady state performance tests that are usually applied to single components. Conclusion: Further work will be needed to harmonize the different test methods in order to reach comparable results between the different laboratories. Practice implications: A harmonized approach for whole system tests may lead to new test standards and improve the accuracy of performance prediction as well as reduce the need for field tests.

Annual CO-emissions of combined pellet and solar heating systems

Emissions are an important aspect of a pellet heating system. High carbon monoxide emissions are often caused by unnecessary cycling of the burner when the burner is operated below the lowest combustion power. Combining pellet heating systems with a solar heating system can significantly reduce cycling of the pellet heater and avoid the inefficient summer operation of the pellet heater. The aim of this paper was to study CO-emissions of the different types of systems and to compare the yearly CO-emissions obtained from simulations with the yearly CO-emissions calculated based on the values that are obtained by the standard test methods. The results showed that the yearly CO-emissions obtained from the simulations are significant higher than the yearly CO-emissions calculated based on the standard test methods. It is also shown that for the studied systems the average emissions under these realistic annual conditions were greater than the limit values of two Eco-labels. Furthermore it could be seen that is possible to almost halve the CO-emission if the pellet heater is combined with a solar heating system.

Emissions from realistic operation of residential wood pellets heating systems

Emissions from residential combustion appliances vary significantly depending on the firing behaviours and combustion conditions, in addition to combustion technologies and fuel quality. Although wood pellet combustion in residential heating boilers is efficient, the combustion conditions during start-up and stop phases are not optimal and produce significantly high emissions such as carbon monoxide and hydrocarbon from incomplete combustion. The emissions from the start-up and stop phases of the pellet boilers are not fully taken into account in test methods for ecolabels which primarily focus on emissions during operation on full load and part load. The objective of the thesis is to investigate the emission characteristics during realistic operation of residential wood pellet boilers in order to identify when the major part of the annual emissions occur. Emissions from four residential wood pellet boilers were measured and characterized for three operating phases (start-up, steady and stop). Emissions from realistic operation of combined solar and wood pellet heating systems was continuously measured to investigate the influence of start-up and stop phases on total annual emissions. Measured emission data from the pellet devices were used to build an emission model to predict the annual emission factors from the dynamic operation of the heating system using the simulation software TRNSYS. Start-up emissions are found to vary with ignition type, supply of air and fuel, and time to complete the phase. Stop emissions are influenced by fan operation characteristics and the cleaning routine. Start-up and stop phases under realistic operation conditions contribute 80 – 95% of annual carbon monoxide (CO) emission, 60 – 90% total hydrocarbon (TOC), 10 – 20% of nitrogen oxides (NO), and 30 – 40% particles emissions. Annual emission factors from realistic operation of tested residential heating system with a top fed wood pelt boiler can be between 190 and 400 mg/MJ for the CO emissions, between 60 and 95 mg/MJ for the NO, between 6 and 25 mg/MJ for the TOC, between 30 and 116 mg/MJ for the particulate matter and between 2x10-13 /MJ and 4x10-13 /MJ for the number of particles. If the boiler has the cleaning sequence with compressed air such as in boiler B2, annual CO emission factor can be up to 550 mg/MJ. Average CO, TOC and particles emissions under realistic annual condition were greater than the limits values of two eco labels. These results highlight the importance of start-up and stop phases in annual emission factors (especially CO and TOC). Since a large or dominating part of the annual emissions in real operation arise from the start-up and stop sequences, test methods required by the ecolabels should take these emissions into account. In this way it will encourage the boiler manufacturers to minimize annual emissions. The annual emissions of residential pellet heating system can be reduced by optimizing the number of start-ups of the pellet boiler. It is possible to reduce up to 85% of the number of start-ups by optimizing the system design and its controller such as switching of the boiler pump after it stops, using two temperature sensors for boiler ON/OFF control, optimizing of the positions of the connections to the storage tank, increasing the mixing valve temperature in the boiler circuit and decreasing the pump flow rate. For 85 % reduction of start-ups, 75 % of CO and TOC emission factors were reduced while 13% increase in NO and 15 % increase in particle emissions was observed.

Alterações neurológicas em lactentes submetidos à cirurgia cardíaca com circulação extra-corpórea

Objetivos: analisar o desenvolvimento neuropsicomotor antes e depois de cirurgia cardíaca em crianças através de dois instrumentos: exame neurológico e do teste de Denver II Métodos: foram randomicamente selecionadas os lactentes com indicação de cirurgia cardíaca com utilização de circulação extra-corpórea no período de abril de 2001 a setembro de 2002 Delineamento: coorte prospectivo não controlado Intervenções: Um dia antes da cirurgia eletiva, na alta da unidade de terapia intensiva pediátrica cardíaca e entre 3 a 6 meses após a cirurgia cardíaca os pacientes incluídos no estudo eram submetidos a um exame neurológico padronizado realizado pelo mesmo neurologista pediátrico e ao teste de Denver II aplicado por 2 pediatras de maneira independente, apresentando uma concordância de resultados entre 89-100% . Estatística: O test t student para amostras pareadas para os índices de Denver II . Teste do Qui-quadrado para as categorias do exame neurológico antes e depois de cirurgia. Foi estimado um tamanho amostral de 15 crianças. Resultados: Foram incluídas 20 crianças, com idade média no momento da correção de 6,7 ± 4,2 meses e peso médio 5,3± 2,2 quilogramas. Os defeitos septais ocorreram em 11 casos (55%). O tempo médio de circulação extra-corpórea era 67± 23,6 minutos, com o uso de ultrafiltração modificada. Quinze crianças tinham atraso no desenvolvimento de neuropsicomotor no momento da cirurgia, mas em seis foi observado normalização depois de 3 a 6 meses de seguimento (p=0,11). Quando os índices de Denver II, dentro de cada domínio, foram analisados (índices motor grosseiro, motor fino, linguagem, total e pessoal-social), observou-se um aumento em todos os domínios após a cirurgia, exceto o último (p < 0.05). O percentual médio de melhora nos índices oscilou entre 17 a 23%. Um tamanho de efeito grande foi calculado para linguagem e moderado nas habilidades de motoras. Conclusão: Apesar destas crianças estarem em risco de novos achados neurológicos, os resultados sugerem uma melhora precoce nos índices de desenvolvimento neuropsicomotor após cirurgia cardíaca com extra-corpórea.

Efeito da degradação ambiental nas propriedades de cisalhamento de compósitos PPS/fibra de carbono

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo da influência do biodiesel de mamona como aditivo antioxidante para o biodiesel de girassol e soja

Biodiesel is a fuel made up by mono-alkyl-esters of long chain fatty acids, derived from vegetable oils or animal fat. This fuel can be used in compression ignition engines for automotive propulsion or energy generation, as a partial or total substitute of fossil diesel fuel. Biodiesel can be processed from different mechanisms. Transesterification is the most common process for obtaining biodiesel, in which an ester compound reacts with an alcohol to form a new ester and a new alcohol. These reactions are normally catalyzed by the addition of an acid or a base. Initially sunflower, castor and soybean oil physicochemical properties are determined according to standard test methods, to evaluate if they had favorable conditions for use as raw material in the transesterification reaction. Sunflower, castor and soybean biodiesel were obtained by the methylic transesterification route in the presence of KOH and presented a yield above 93% m/m. The sunflower/castor and soybean/castor blends were studied with the aim of evaluating the thermal and oxidative stability of the biofuels. The biodiesel and blends were characterized by acid value, iodine value, density, flash point, sulfur content, and content of methanol and esters by gas chromatography (GC). Also studies of thermal and oxidative stability by Thermogravimetry (TG), Differential Scanning Calorimetry High Pressure (P-DSC) and dynamic method exothermic and Rancimat were carried out. Biodiesel sunflower and soybean are presented according to the specifications established by the Resolution ANP no 7/2008. Biodiesel from castor oil, as expected, showed a high density and kinematic viscosity. For the blends studied, the concentration of castor biodiesel to increased the density, kinematic viscosity and flash point. The addition of castor biodiesel as antioxidant in sunflower and soybean biodiesels is promising, for a significant improvement in resistance to autoxidation and therefore on its oxidative stability. The blends showed that compliance with the requirements of the ANP have been included in the range of 20-40%. This form may be used as a partial substitute of fossil diesel

Desempenho de escolares de 1ª série na bateria de identificação de erros de reversão e inversão na escrita: estudo preliminar

OBJETIVO: caracterizar o desempenho de escolares da 1ª série na bateria de identificação de erros de reversão e inversão na escrita. MÉTODOS: participaram deste estudo 30 escolares de 1ª série de ensino público do município da cidade de Marília-SP, de ambos os gêneros, na faixa etária de 7 anos a 7 anos e 11 meses de idade. Como procedimento foi realizada a adaptação brasileira da bateria de identificação dos erros de reversão e inversão na escrita. Esta bateria é composta por 3 testes: teste de desempenho contínuo, teste de memória de curto prazo e teste de controle de escrita. Cada teste é composto por subtestes que visam identificar a capacidade dos escolares em identificar as inversões e reversões de letras e números isolados e letras e números em sequências. RESULTADOS: os resultados revelaram que os escolares da 1ª série apresentaram desempenho superior para identificação de reversão e inversão de letras dentro de palavras do que isoladamente, identificação da reversão para letras e números com desempenho superior se comparado a inversão de letras na palavra. Além disso, os escolares deste estudo apresentaram menor tempo para identificação de reversão e inversão de letras e números isolados do que em sequência. CONCLUSÃO: a Bateria adaptada para este estudo permitiu conhecer o perfil dos escolares de 1ª série quanto a identificação dos erros de inversão e reversão, entretanto, é necessário novas aplicações para verificar a ocorrência de identificação destes erros em populações de diferentes fase de alfabetização.

Desempenho de escolares de 1ª a 4ª série do ensino fundamental nas provas de habilidades metafonológicas e de leitura - PROHMELE

OBJETIVO: Elaborar uma bateria de provas que se propõe a avaliar o processamento de habilidades necessárias para a aquisição do sistema de escrita alfabético do Português do Brasil, e caracterizar e comparar o desempenho dos escolares de 1ª a 4ª série do ensino fundamental nas provas desta bateria. MÉTODOS: Foram elaboradas provas específicas para este fim, seguindo os princípios fonológicos da língua portuguesa do Brasil. Foram avaliados 120 escolares de 1ª a 4ª séries, sendo 30 de cada série escolar divididos em quatro grupos, respectivamente GI, GII, GIII e GIV. As provas elaboradas e aplicadas foram: prova de habilidades metafonológicas (identificação e manipulação de sílabas e fonemas, além de repetição de não-palavras); prova de leitura (leitura de palavras reais e de pseudopalavras). RESULTADOS: Houve diferenças estatisticamente significantes entre os grupos nas habilidades metafonológicas com as médias diminuindo da 1ª à 4ª série sucessivamente. Também houve diferenças quanto ao tempo de leitura de palavras reais e de pseudopalavras, com as médias diminuindo da 1ª à 3ª série, mantendo-se igual ou próximo entre esta e a 4ª série. CONCLUSÃO: Os desempenhos foram se tornando superiores da 1ª à 4ª série, sendo que os escolares obtiveram desempenhos superiores nas provas de identificação em relação às provas de manipulação, assim como os desempenhos nas provas silábicas foram superiores aos das provas fonêmicas. Há uma prevalência da rota fonológica nas séries iniciais (1ª e 2ª) com as outras séries, especialmente a 4ª, usando mais a rota lexical.

Comparison of two bond strength testing methodologies for bilayered all-ceramics

Objectives. This study compared the shear bond strength (SBS) and microtensile (MTBS) testing methodologies for core and veneering ceramics in four types of all-ceramic systems.Methods. Four different ceramic veneer/core combinations, three of which were feldspathic and the other a fluor-apatite to their respectively corresponding cores, namely leucitereinforced ceramic ((IPS)Empress, Ivoclar), low leucite-reinforced ceramic (Finesse, Ceramco), glass-infiltrated alumina (In-Ceram Alumina, Vita) and lithium disilicate ((IPS)Empress 2, Ivoclar) were used for SBS and MTBS tests. Ceramic cores (N = 40, n = 10/group for SBS test method, N=5blocks/group for MTBS test method) were fabricated according to the manufacturers' instructions (for SBS: thickness, 3 mm; diameter, 5 mm and for MTBS: 10 mm x 10 mm x 2 mm) and ultrasonically cleaned. The veneering ceramics (thickness: 2 mm) were vibrated and condensed in stainless steel moulds and fired onto the core ceramic materials. After trying the specimens in the mould for minor adjustments, they were again ultrasonically cleaned and embedded in PMMA. The specimens were stored in distilled water at 37 degrees C for 1 week and bond strength tests were performed in universal testing machines (cross-head speed: 1mm/min). The bond strengths (MPa +/- S.D.) and modes of failures were recorded.Results. Significant difference between the two test methods and all-ceramic types were observed (P < 0.05) (2-way ANOVA, Tukey's test and Bonferroni). The mean SBS values for veneering ceramic to lithium disilicate was significantly higher (41 +/- 8 MPa) than those to low leucite (28 +/- 4 MPa), glass-infiltrated (26 +/- 4 MPa) and leucite-reinforced (23 +/- 3 MPa) ceramics, while the mean MTBS for low leucite ceramic was significantly higher (15 +/- 2 MPa) than those of leucite (12 +/- 2 MPa), glass-infiltrated (9 +/- 1 MPa) and lithium disilicate ceramic (9 +/- 1 MPa) (ANOVA, P < 0.05).Significance. Both the testing methodology and the differences in chemical compositions of the core and veneering ceramics influenced the bond strength between the core and veneering ceramic in bilayered all-ceramic systems. (c) 2006 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.