KLnP_4O_(12)晶体的热稳定性

对于不同晶体结构类型和不同Ln的差热分析结果表明,随着从稀土元素的原子序数增加、无论是a-KLnP_4O_(12)还是β-KLnP_4O_(12)晶体的吸热峰温度均降低。如a-KLaP_4O_(12)的吸热峰温度为894℃、a-KSmP_4O_(12)为887℃、a-KEuP_4O_(12)为878℃、a-KGdP_4O_(12)为870℃、

偏最小二乘法及主组分回归法用于药物组分的测定

本文研究了多元校准方法——偏最小二乘法(PLS)和主组份回归法(PCR)在药物多组份光度分析中的应用,获得了较满意的结果。而且在系列校准样品的实验设计、交叉证实法确定最佳因子数以及空缺组份体系的分析等方面进行了探讨。

聚苯乙烯-乙丙共聚物两嵌段共聚物的组成分析

本文用红外光谱(IR)的工作曲线法及傅里叶变换红外光谱(FT-IR)差谱法,分析了多单体嵌段共聚物聚苯乙烯-乙丙共聚物PS-b-EPR的组成,包括聚苯乙烯段的含量和乙丙共聚物段的乙丙组成。

Accumulation of petroleum hydrocarbons and heavy metals in clams (Ruditapes philippinarum) in Jiaozhou Bay, China

Accumulation and distributions of aliphatic and polyaromatic hydrocarbons (PAHs) and heavy metals were measured in tissues of the clam Ruditapes philippinarum collected from 5 sites in Jiaozhou Bay, Qingdao, China. The concentrations of total aliphatic hydrocarbon and PAHs ranged from 570 to 2 574 ng/gdw (gram dry weight) and from 276 to 939 ng/gdw, in the most and least polluted sites, respectively. The bio-accumulation of hydrocarbons and PAHs in the clams appeared to be selective. Aliphatic hydrocarbons were predominantly represented by short chain (< nC(23)) n-alkanes, suggesting that petroleum hydrocarbons were likely the major contamination source. The selective uptake of 3 and 4 ring PAHs, such as naphthalene, fluorene, phenanthrene, fluoranthene and pyrene, by the clams was probably related to the physiological and bio-kinetic processes that were energetically favorable for uptake of compounds with fewer rings. Accumulation of the metals Cd, Cu, Zn, Pb, Cr, Hg, and As in the clam tissues also showed high variability, ranging from 0.043 to 87 A mu g/gdw. Among the 7 detected metals, Zn, Cd, Cu, and As had a particularly high potential of accumulation in R. philippinarum. In general, a positive correlation was found between the tissue concentrations and sediment concentrations of hydrocarbons and of some metals. Our study suggests that moderate contamination with polyaromatic hydrocarbons, and low to moderate contamination with metals, currently exists for clam R. philippinarum in Jiaozhou Bay, in comparison with other regional studies. A long-term monitoring program is certainly needed for assessment of the potential ecological influence and toxicity of these contaminants of R. philippinarum in Jiaozhou Bay.

Long-term ecological interactions between nutrient and phytoplankton community in the Changjiang estuary

Both nitrate (NO (3) (-) ) and soluble reactive phosphate (PO (4) (3-) ) concentration in the freshwater end-member at the mouth of the Changjiang River have increased dramatically since the 1960s. Within the same period in the sea area, with surface salinity > 30, NO (3) (-) concentration has shown an obvious increase, PO (4) (3-) has not changed greatly and dissolved reactive silica (SiO (3) (2-) ) has deceased dramatically. An examination of the elemental ratio of NO (3) (-) to PO (4) (3-) at the mouth of the Changjiang River did not show a systematic trend from the 1960s to 2000s largely because both nutrients increased simultaneously. In comparison, the elemental ratio of dissolved inorganic nitrogen (DIN) to PO (4) (3-) in surface seawater, with salinity > 22, has shown a clearly increasing trend. Furthermore, an overall historical change of the SiO (3) (2-) :PO (4) (3-) ratio has undergone a reverse trend in this area. Based on the changes of SiO (3) (2-) :PO (4) (3-) and DIN:PO (4) (3-) ratios, we can conclude that an overall historical change of SiO (3) (2-) :DIN ratio has decreased in this area from the 1950-1960s to 2000s. The argument that phytoplankton productivity in the Changjiang estuary has been enhanced by increasing nutrient input from the riverine transport was supported by these results. A comparative study analyzing the shift of phytoplankton composition from the mid-1980s to 2000s was also made. The results indicated that the average yearly percentage of diatom species in the Changjiang estuary has decreased from 84.6% during 1985-1986 to 69.8% during 2004-2005. Furthermore, the average yearly percentage of diatom abundance in the Changjiang estuary decreased from 99.5% during to 75.5% over the same time period, while the abundance of dinoflagellates has increased dramatically, from 0.7% to 25.4%.

唐古特白刺果实花色苷体外清除自由基的活性

为探讨唐古特白刺（Nitraria tangutomn Bobr.）果实花色苷体外清除自由基活性，研究了其对超氧阴离子（O_2~-•）体系、羟基自由基（•OH）体系和二苯代苦味酰基自由基（DPPH•）体系的清除效果，并与抗坏血酸（Vc）进行了比较。结果表明，该花色苷对O_2~-•、•OH、DPPH•均具有清除作用，且与浓度呈量效关系。对•OH和DPPH•清除效果相对较好，优于Vc。

高寒草甸藏嵩草种群繁殖对策的研究

对高寒草甸藏嵩草 (Kobresiatibetica)种群的繁殖对策进行了初步研究 .结果表明 :藏嵩草属寒冷中生密丛短根茎地下芽植物 ,在高寒生境中采用了以营养繁殖为主、有性繁殖为辅的繁殖策略 ,具体体现在以下几个方面 :藏嵩草种子产量nA=2 0 0 .1m-2 ,但种子萌发率较低 ,室内和野外萌发率分别仅有 4%和 2 % ,经氢氧化钠溶液和赤霉素溶液处理后的种子萌发率分别为 1%和 6 .7% ,而剥去种皮后种子萌发率达 47.3% ,所以种皮坚硬是造成种子萌发率低的主要原因 ;进入种子库、保留至返青期且具有活性的种子仅占种子总数的 31.49% ;单位面积上理论实生苗数仅为1.2 6m-2 ,与此相反 ,藏嵩草营养繁殖所形成的新个体数为 10 1.32m2 ,远远多于种子萌发所形成的实生苗数 .此外 ,藏嵩草营养繁殖效力也远高于有性繁殖效力，营养繁殖效力占总繁殖效力的83.46%（167）。

青海湖北岸植物群落与环境因子关系的初步研究

依据对青海湖北岸 1 8个群落的样方调查和环境因子原始数据 ,用主分量分析 ( PCA)排序技术和回归模型 ,定量分析湖滨平原植物群落在空间地理上的分布格局 ,以及群落结构特征和环境梯度之间的关系。结果表明 :植物群落的类型分布主要决定于环境中的土壤水分含量及土壤全盐含量。代表植物群落结构特征的生物多样性 ( X1)和生态优势度 ( X2 )分别与环境梯度没有显著的相关性 ,但是 ,这两个指标和第一主分量排序轴 (土壤水分度 ,Y)的二元线性回归关系显著 ,回归模型为 :Y =- 4 .85 + 1 .4 7X1+ 1 0 .71 X2 ( P <0 .0 1 )。

隐爆角砾岩筒型矿床成矿流体演化趋势曲线特征

阐述了隐爆角砾岩筒型矿床及其成矿过程中的隐爆流体演化趋势曲线的一般特征，在此基础上，讨论了凹山铁矿床、祁雨沟金矿床、七宝山铜金矿床等典型矿床的矿体产出特征与隐爆流体演化趋势曲线之间存在的耦合关系，结合隐爆角砾岩筒型矿床成矿流体演化的一般特征和特殊情况，对轻微剥蚀岩筒、中等剥蚀岩筒和深度剥蚀岩筒的成矿性进行了分析。

Separation of acidic compounds by strong anion-exchange capillary electrochromatography

Separation of the acidic compounds in the ion-exchange capillary electrochromatograph (IE-CEC) with strong anion-exchange packing as the stationary phase was studied. It was observed that the electroosmotic flow (EOF) in strong anion-exchange CEC moderately changed with increase of the eluent ionic strength and decrease of the eluent pH, but the acetonitrile concentration in the eluent had almost no effect on the EOF. The EOF in Strong anion-exchange CEC with eluent of low pH value was much larger than that in RP-CEC with Spherisorb-ODS as the stationary phase. The retention of acidic compounds on the strong anion-exchange packing was relatively weak due to only partial ionization of them, and both chromatographic and electrophoretic processes contributed to separation. It was observed that the retention values of acidic compounds decreased with the increase of phosphate buffer and acetonitrile concentration in the eluent as well as the decrease of the applied voltage, and even the acidic compounds could elute before the void time. These factors also made an important contribution to the separation selectivity for tested acidic compounds, which could be separated rapidly with high column efficiency of more than 220 000 plates/m under the optimized separation conditions. (C) 2000 Elsevier Science BN. All rights reserved.

Asesoría en diseño y gestión para la producción Regional Centro Oriente; departamento de Cundinamarca; municipios de Bogotá y Guaduas. Oficios de cerámica y alfarería, mimbre y trabajos en bambú, trabajos en tagua, carpintería y oficios varios.

73 hojas : ilustraciones.