Nicht-wässrige Emulsionspolymerisationen

Die vorliegende Arbeit beschäftigt sich mit der Darstellung von Latexpartikeln in nicht-wässrigen Emulsionssystemen. Hintergrund der Untersuchungen war die Frage, ob es durch die Anwendung von nicht-wässrigen Emulsionen ermöglicht werden kann, sowohl wassersensitive Monomere als auch feuchtigkeitsempfindliche Polymerisationen zur Darstellung von Polymer-Latexpartikeln und deren Primärdispersionen einzusetzen. Das Basiskonzept der Arbeit bestand darin, nicht-wässrige Emulsionen auf der Basis zweier nicht mischbarer organischer Lösungsmittel unterschiedlicher Polarität auszubilden und anschließend die dispergierte Phase der Emulsion zur Synthese der Latexpartikel auszunutzen. Hierzu wurden verschiedene nicht-wässrige Emulsionssysteme erarbeitet, welche als dispergierte Phase ein polares und als kontinuierliche Phase ein unpolares Lösungsmittel enthielten. Auf Basis dieser Ergebnisse wurde in den nachfolgenden Untersuchungen zunächst die Anwendbarkeit solcher Emulsionen zur Darstellung verschiedener Acrylat- und Methacrylatpolymerdispersionen mittels radikalischer Polymerisation studiert. Um zu zeigen, dass die hier entwickelten nicht-wässrigen Emulsionen auch zur Durchführung von Stufenwachstumsreaktionen geeignet sind, wurden ebenfalls Polyester-, Polyamid- und Polyurethan-Latexpartikel dargestellt. Die Molekulargewichte der erhaltenen Polymere lagen bei bis zu 40 000 g/mol, im Vergleich zu wässrigen Emulsions- und Miniemulsions¬polymerisationssystemen sind diese um den Faktor fünf bis 30 höher. Es kann davon ausgegangen werden, dass hauptsächlich zwei Faktoren für die hohen Molekulargewichte verantwortlich sind: Zum einen die wasserfreien Bedingungen, welche die Hydrolyse der reaktiven Gruppen verhindern, und zum anderen die teilweise erfüllten Schotten-Baumann-Bedingungen, welche an der Grenzfläche zwischen dispergierter und kontinuierlicher Phase eine durch Diffusion kontrollierte ausgeglichene Stöchiometrie der Reaktionspartner gewährleisten. Somit ist es erstmals möglich, hochmolekulare Polyester, -amide und -urethane in nur einem Syntheseschritt als Primär¬dispersion darzustellen. Die Variabilität der nicht-wässrigen Emulsionen wurde zudem in weiteren Beispielen durch die Synthese von verschiedenen elektrisch leitfähigen Latices, wie z.B. Polyacetylen-Latexpartikeln, aufgezeigt. In dieser Arbeit konnte gezeigt werden, dass die entwickelten nicht-wässrigen Emulsionen eine äußerst breite Anwendbarkeit zur Darstellung von Polymer-Latexpartikeln aufweisen. Durch die wasserfreien Bedingungen erlauben die beschriebenen Emulsionsprozesse, Latexpartikel und entsprechende nicht-wässrige Dispersionen nicht nur traditionell radikalisch, sondern auch mittels weiterer Polymerisationsmechanismen (katalytisch, oxidativ oder mittels Polykondensation bzw. -addition) darzustellen.

Estudio de una red aislada de distribución de pequeña potencia y gran penetración eólica con la herramienta PSS/E

El objeto de este proyecto es realizar un análisis de estabilidad ante contingencias en una red aislada de pequeña potencia con alto grado de penetración eólica mediante la herramienta PSS/E con el fin de aportar conocimiento para, posteriormente, definir la forma de operación más adecuada de dicho sistema atendiendo a su eficacia y fiabilidad. La red considerada para el estudio es la de la isla de El Hierro, en el archipiélago de Canarias, donde se tiene previsto abastecer exclusivamente, a toda la isla, combinando la aportación energética de un parque eólico y una central hidráulica con grupos de bombeo. Para realizar los estudios de estabilidad se analizan una serie de escenarios considerados de interés desde el punto de vista técnico, bien sea abasteciendo la demanda con una sola fuente de generación o con varias a la vez. El interés principal de esta red radica en que es una red aislada, de pequeña potencia, por lo que el proceso de integración masiva de energías renovables en la misma presenta una serie de particularidades que se irán detallando a lo largo del trabajo. El modelado de la red se ha realizado utilizando PSS/E, un software comercial extendido para el análisis de los sistemas de potencia. Con el programa se han resuelto los regímenes estáticos de funcionamiento (flujos de cargas) y los dinámicos (estudios de contingencias). Los resultados mostrarán las tensiones o frecuencias en los nudos de interés, observándose cómo cambian los valores en la situación anormal de funcionamiento y cómo se recuperan cuando se despeja la falta considerada, retornándose a los valores que existían en la red previos al fallo. Se pretende concluir cuál debe ser el mínimo de energía convencional que se debe mantener en el sistema para asegurar el suministro de forma fiable y segura en cualquier circunstancia.

Electrochemical Behaviour of PSS-Functionalized Silica Films Prepared by Electroassisted Deposition of Sol–Gel Precursors

Porous, electrically insulating SiO2 layers containing polystyrene sulfonate (PSS) were deposited on glassy carbon electrodes by an electrochemically assisted deposition method. The obtained material was characterized by microscopic, spectroscopic and thermal techniques. Silica-PSS films modify the electrochemical response of the glassy carbon electrodes against selected redox probes. Positively charged species show reduced diffusivities across the SiO2-PSS pores, which resulted in a concentration ratio higher than 1 for these species. The opposite behaviour was found for negatively charged redox probes. These observations can be interpreted in terms of the different affinity of the GC/SiO2-PSS-modified electrode for the electroactive species, as a consequence of the negatively charged porous silica.

An interpretation of four regal Psalms (Pss. 2, 110, 45 and 92)

On cover: Quaternio.

Operator, organizational, and direct support maintenance manual : detecting set, mine, aural indication, 10V DC operating power, portable, transistorized, w/case AN/PSS-11 (Polan models P153 and P158) NSN 6665-00-966-9071, (Polan model P190) NSN 6665-00-181-0432, (Oregon Technical Products model MD-M) ... (The VP Company model VP200) ... (Fourdee model 4D5000) ....

Includes index.

Organizational, direct support maintenance, repair parts and special tools list : detecting set, mine, aural indication, 10V DC operating power, portable, transistorized, w/case AN/PSS-11 (Polan models P153 and P158) FSN 6665-966-9071, (Polan model P190) FSN 6665-181-0432, (Oregon Technical Products model MD-M) ...

"23 February 1974."

PSS as a service based strategy for western manufacturers

A product-service system (PSS) is a subtle blend of products and services that are offered as an integrated solution to customers. Much existing work on PSS has originated from Scandinavia and has been motivated by a sustainability agenda. Although valuable, this form has limited appeal to western manufacturers. However, by expanding the concepts of PSS to also embrace leading thinking on large scale complex service systems and informated products and services, it is possible to put forward the basis of a service business model that offers the means to differentiate from competitors who simply offer lower priced products. This paper aims to build this case. It reports the state-of-the-art of PSS, defines the concept, reports on its origin and features, discusses examples of applications, and finally proposes a research strategy for future work on this topic.

Developing a serious game for PSS

Purpose: This paper presents the system architecture of a serious game, which is going to be run in parallel to Rolls Royce tra ining on product-service systems (PSS). Design/methodology/approach: The original game is outlined, requirements for an onl ine version are defined, and the architecture is proposed. Findings: The games approach has proven its value in design for service tra ining but an online version is needed to improve the opportunit ies to deliver the game. Originality/value: Such a system presents opportunities for the acquisition and development of specific professional knowledge, skills, and competencies

Business-IT Alignment in PSS Value Networks: A Capability-Based Framework

Part 8: Business Strategies Alignment

Does psychological stress mediate social deprivation in tooth loss?

It is unclear which theoretical dimension of psychological stress affects health status. We hypothesized that both distress and coping mediate the relationship between socio-economic position and tooth loss. Cross-sectional data from 2915 middle-aged adults evaluated retention of < 20 teeth, behaviors, psychological stress, and sociodemographic characteristics. Principal components analysis of the Perceived Stress Scale (PSS) extracted 'distress' (a = 0.85) and 'coping' (a =0.83) factors, consistent with theory. Hierarchical entry of explanatory variables into age- and sex-adjusted logistic regression models estimated odds ratios (OR) and 95% confidence intervals [95% CI] for retention of < 20 teeth. Analysis of the separate contributions of distress and coping revealed a significant main effect of coping (OR = 0.7 [95% CI = 0.7-0.8]), but no effect for distress (OR = 1.0 [95% CI = 0.9-1.1]) or for the interaction of coping and distress. Behavior and psychological stress only modestly attenuated socio-economic inequality in retention of < 20 teeth, providing evidence to support a mediating role of coping.

Web-based public participatory GIS

Decision support systems (DSS) have evolved rapidly during the last decade from stand alone or limited networked solutions to online participatory solutions. One of the major enablers of this change is the fastest growing areas of geographical information system (GIS) technology development that relates to the use of the Internet as a means to access, display, and analyze geospatial data remotely. World-wide many federal, state, and particularly local governments are designing to facilitate data sharing using interactive Internet map servers. This new generation DSS or planning support systems (PSS), interactive Internet map server, is the solution for delivering dynamic maps and GIS data and services via the world-wide Web, and providing public participatory GIS (PPGIS) opportunities to a wider community (Carver, 2001; Jankowski & Nyerges, 2001). It provides a highly scalable framework for GIS Web publishing, Web-based public participatory GIS (WPPGIS), which meets the needs of corporate intranets and demands of worldwide Internet access (Craig, 2002). The establishment of WPPGIS provides spatial data access through a support centre or a GIS portal to facilitate efficient access to and sharing of related geospatial data (Yigitcanlar, Baum, & Stimson, 2003). As more and more public and private entities adopt WPPGIS technology, the importance and complexity of facilitating geospatial data sharing is growing rapidly (Carver, 2003). Therefore, this article focuses on the online public participation dimension of the GIS technology. The article provides an overview of recent literature on GIS and WPPGIS, and includes a discussion on the potential use of these technologies in providing a democratic platform for the public in decision-making.

Soil carbon saturation: Linking concept and measurable carbon pools

The soil C saturation concept suggests a limit to whole soil organic carbon (SOC) accumulation determined by inherent physicochemical characteristics of four soil C pools: unprotected, physically protected, chemically protected, and biochemically protected. Previous attempts to quantify soil C sequestration capacity have focused primarily on silt and clay protection and largely ignored the effects of soil structural protection and biochemical protection. We assessed two contrasting models of SOC accumulation, one with no saturation limit (i.e., linear first-order model) and one with an explicit soil C saturation limit (i.e., C saturation model). We isolated soil fractions corresponding to the C pools (i.e., free particulate organic matter POM], microaggregate-associated C, silt- and clay-associated C, and non-hydrolyzable C) from eight long-term agroecosystern experiments across the United States and Canada. Due to the composite nature of the physically protected C pool, we firactioned it into mineral- vs. POM-associated C. Within each site, the number of fractions fitting the C saturation model was directly related to maximum SOC content, suggesting that a broad range in SOC content is necessary to evaluate fraction C saturation. The two sites with the greatest SOC range showed C saturation behavior in the chemically, biochemically, and some mineral-associated fractions of the physically protected pool. The unprotected pool and the aggregate-protected POM showed linear, nonsaturating behavior. Evidence of C saturation of chemically and biochemically protected SOC pools was observed at sites far from their theoretical C saturation level, while saturation of aggregate-protected fractions occurred in soils closer to their C saturation level.

Fuzzy logic power system stabilizer in multimachine stability studies

Power system stabilizers (PSS) work well at the particular network configuration and steady state conditions for which they were designed. Once conditions change, their performance degrades. This can be overcome by an intelligent nonlinear PSS based on fuzzy logic. Such a fuzzy logic power system stabilizer (FLPSS) is developed, using speed and power deviation as inputs, and provides an auxiliary signal for the excitation system of a synchronous motor in a multimachine power system environment. The FLPSS's effect on the system damping is then compared with a conventional power system stabilizer's (CPSS) effect on the system. The results demonstrate an improved system performance with the FLPSS and also that the FLPSS is robust

Online urban information systems

Countless factors affect the inner workings of a city, so in an attempt to gain an understanding of place and making sound decisions, planners need to utilize decision support systems (DSS) or planning support systems (PSS). PSS were originally developed as DSS in academia for experimental purposes, but like many other technologies, they became one of the most innovative technologies in parallel to rapid developments in software engineering as well as developments and advances in networks and hardware. Particularly, in the last decade, the awareness of PSS have been dramatically heightened with the increasing demand for a better, more reliable and furthermore a transparent decision-making process (Klosterman, Siebert, Hoque, Kim, & Parveen, 2003). Urban planning as an act has quite different perspective from the PSS point of view. The unique nature of planning requires that spatial dimension must be considered within the context of PSS. Additionally, the rapid changes in socio-economic structure cannot be easily monitored or controlled without an effective PSS.

Effects of various power system stabilizers on improving power system dynamic performance

To ensure the small-signal stability of a power system, power system stabilizers (PSSs) are extensively applied for damping low frequency power oscillations through modulating the excitation supplied to synchronous machines, and increasing interest has been focused on developing different PSS schemes to tackle the threat of damping oscillations to power system stability. This paper examines four different PSS models and investigates their performances on damping power system dynamics using both small-signal eigenvalue analysis and large-signal dynamic simulations. The four kinds of PSSs examined include the Conventional PSS (CPSS), Single Neuron based PSS (SNPSS), Adaptive PSS (APSS) and Multi-band PSS (MBPSS). A steep descent parameter optimization algorithm is employed to seek the optimal PSS design parameters. To evaluate the effects of these PSSs on improving power system dynamic behaviors, case studies are carried out on an 8-unit 24-bus power system through both small-signal eigenvalue analysis and large-signal time-domain simulations.