Influência da intensidade de aeração na formação do floco de lodo ativado e na eficiência de remoção de matéria orgânica

In wastewater treatment, activated sludge systems have been a technology widely applied as secondary treatment. During this step, which has a strong biological aspect, it is necessary to introduce oxygen supply for the maintenance of metabolic activity of the bacteria through the aerators. Aeration devices are responsible for most of the energy consumption in this stage. In this background, the influence of three aeration intensities (atmospheric air flow 3.5, 7.0 and 10.5 L.min-1) and the concentration of dissolved oxygen (DO) on the dimension of activated sludge flocs as well as on the efficiency of organic matter removal were assessed using a traditional activated sludge system which was fed with synthetic domestic wastewater. Samples were taken weekly from the three units that make up the system feed, aeration and storage tank in order to verify the Chemical Oxygen Demand (COD). It was established the process efficiency through a comparison between the initial and final COD. Besides the parameters already mentioned, this monitoring work on activated sludge batch system was also observed by Mixed Liquor Suspend Solids (MLSS), Volatile Suspend Solids (VSS), pH and temperature measures. The results have showed a maximum removal efficiency around 75% in the first aeration sequence and approximately 85% for the second and third one. For the first aeration, the DO concentration remained higher than 3.0 mg.L-1 and a diameter range from 10 to 60 μm was observed. In the second e third sequence, the DO concentration remained higher than 4.0 mg.L-1 with a diameter range of 10 until 200 μm. Although the sequence 1 and 2 have presented similar performances for organic matter removal, the sequence 2 promoted a regular floc size distribution and with lower values of Sludge Volumetric Index (SVI) meaning a better flocculating ability. In addition, the results reaffirmed what the literature has reported: higher DO concentrations produce flocs with greater dimensions

Estudo da influência de compostos recalcitrantes na remoção de matéria orgânica biodegradável no tratamento de efluente de refinarias de petróleo

Petroleum Refinery wastewaters (PRW) have hart-to-degrade compounds, such as: phenols, ammonia, cyanides, sulfides, oils and greases and the mono and polynuclear aromatic hydrocarbons: benzene, toluene and xylene (BTX), acenaphthene, nitrobenzene and naphtalene. It is known that the microrganisms activity can be reduced in the presence of certain substances, adversely affecting the biological process of wastewater treatment. This research was instigated due the small number of studies regarding to this specific topic in the avaiable literature. This body of work ims to evaluate the effect of toxic substances on the biodegradability of the organic material found in PRW. Glucose was chosen as the model substrate due to its biodegradable nature. This study was divided into three parts: i) a survey of recalcitants compounds and the removal of phenol by using both biological and photochemical-biological processes; ii) biomass aclimation and iii) evaluation of the inhibitory effect certain compounds have on glucose biodegradation. The phenol degradation experiments were carried out in an activity sludge system and in a photochemical reactor. The results showed the photochemical-biological process to be more effective on phenol degradation, suggesting the superioruty of a combined photochemical-biological treatment when compared with a simple biological process for phenol removal from industry wastewaters. For the acclimation step, was used an activated sludge from industrial wastewaters. A rapid biomass aclimation to a synthetic solution composed of the main inhibitory compouns fpund in a PRW was obtained using the following operation condition: (pH = 7,0; DO ≥ 2,0 mg/L; RS = 20 days e qH = 31,2 and 20,4 hours), The last part was consisted of using respirometry evaluation toxicity effects of selected compounds over oxygen uptake rate to adaptated and non adaptated biomass in the presence of inhibitory compounds. The adaptated sludge showed greater degration capacity, with lower sensibility to toxic effects. The respirometry has proved to be very practical, as the techiniques used were simple and rapid, such as: Chemical Oxygen Demand (COD), Dissolved Oxygen (DO), and Volatile Suspended Solids (VSS). Using the latter it is possible to perform sludge selection to beggingthe process; thus allowing its use for aerobic treatment system`s behacior prediction

Eficiência de uma ETE em escala real composta por reator UASB seguido de lodo ativado

In the state of Rio Grande do Norte (RN), Brazil, there are about 80 sewage treatment systems being the predominant technology waste stabilization ponds. The Baldo s WWTP , due to its location and low availability of area, was designed as a hybrid conventional system (UASB reactor followed by activated sludge with biodiscs) at a tertiary level, being the most advanced WWTP in the State and also with the larger treatment capacity (1620 m3/h) .The paper presents the results of its performance based on samples collections from May to December 2012. Composite samples of the effluent of the grit chamber, UASB reactors, anoxic chambers, aeration tanks and treated effluent were collected weekly, every 4 hours for 24 hours. The results showed that the WWTP effluent presented adequate ranges of temperatures, pH and DO, however removal efficiencies of BOD and TSS were below the predicted by design. The UASB reactors also showed removals of BOD and TSS less than expected, due to the accumulation of sludge in the reactors, which eventually, was washed out in the effluent. The nitrification process was not satisfactory mainly due to problems in the oxygen distribution in the aeration tanks. The removal of ammonia and TKN were high, probably by the assimilation process

Microbiological and physicochemical treatments applied to metallurgic industry aiming water reuse

Estudou-se o reuso de água de um sistema composto por estação de tratamento de esgoto (ETE) com aeração prolongada e lodo ativado, e em uma estação compacta de tratamento de água (ECTA) de uma indústria metalúrgica. Os processos para obtenção da água de reuso foram: microbiológico e físico-químico. O esgoto doméstico foi bombeado para a ETE, onde houve formação de flocos biológicos e água clarificada. Avaliou-se a eficiência do processo microbiológico da ETE mediante a remoção de demanda bioquímica de oxigênio (DBO), demanda química de oxigênio (DQO) e sólidos sedimentáveis (SS). A eficiência do processo físico-químico de clarificação e desinfecção foi avaliada mediante análises de pH, turbidez, cor, contagem de bactérias heterotróficas aeróbias, cloro livre, dureza, alcalinidade, cloretos, sulfatos, sólidos totais dissolvidos (STD). Na água de reuso além desses parâmetros avaliou-se a toxicidade aguda ao microcrustáceo Daphnia similis.

Aplicabilidad del proceso de nitritación/desnitritación en el tratamiento de lixiviado de relleno sanitario

The biological nitritation/denitritation process in the removal of organic matter and nitrogen in a landfill leachate was studied, using an activated sludge sequencing batch reactor. Treatment cycles were formed by an anoxic and an aerobic phases, in which the conditions for oxidation of the influent N load and the prevalence of nitrite concentration at the end of aerobic treatment cycles were determined, as well as the use of organic matter present in the leachate as a carbon source for denitrifying organisms in the anoxic stage. The removal efficiencies of N-NO 2-at the end of the anoxic process (48h) ranged between 14 and 30%, indicating low availability of biodegradable organic matter in the leachate. As for the accumulation of N-NO 2-at the end of the aerobic phase (48h) of treatment cycles, imbalances were not observed, while 100% removal efficiencies of N and specific nitritation rates from 0.095 to 0.158kgN-NH 3/kgSSV per day were recorded, demonstrating the applicability of simplified nitrification in the treatment of effluents with low C/N ratios.

Evaluation of the microbial diversity of denitrifying bacteria in batch reactor

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo da lixiviação bacteriana de metais presentes em lodo de esgoto sanitário

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Projeto de um controlador Fuzzy Takagi-Sugeno para uma estação de tratamento de esgoto por lodos ativados

Este trabalho propõe o projeto de um controlador Fuzzy do tipo Takagi-Sugeno em uma estação de tratamento de esgoto por lodos ativados. Este tipo de tratamento ocorre na presença de oxigênio, pois microorganismos aeróbios presentes no licor misto irão proporcionar a remoção tanto da matéria carbonácea quanto nutrientes formados por compostos à base de nitrogênio. O controlador atua via mecanismo de aeração e foi projetado para interpolar os ganhos proporcionais e integrativos de três controladores fixos locais que, por sua vez, foram projetados a partir da linearização de um modelo contínuo de balanço de massa de oxigênio. O controlador auxiliará manter a concentração de oxigênio dissolvido desejável na faixa de operação do processo para que ocorra a nitrificação, reação química de oxiredução que transforma amônio em nitrito, que é fundamental para o sucesso do processo, e poderá também economizar energia elétrica utilizada pelo mecanismo de aeração. Os ensaios foram realizados via simulação computacional em quatro cenários idealizados comparando o desempenho do controlador fuzzy e o desempenho de um controlador fixo projetado em um ponto de operação diferente do qual se utilizou como valor de referência na planta. Ao aplicar um degrau no valor de referência estabelecido no cenário de análise, observou-se o tempo de subida, o tempo de acomodação e o erro em regime. Após os ensaios, observou-se que o desempenho do controlador fuzzy nos quesitos tempo de subida e tempo de acomodação em relação ao controlador fixo foi melhor, enquanto nos quesitos sobressinal e erro em regime foi semelhante. Após as análises, concluiu-se que a estratégia de controle escolhida neste trabalho é viável, pois de acordo com o valor auferido de oxigênio dissolvido na entrada da planta, o controlador fuzzy irá interpolar os ganhos proporcionais e integrativos de um controlador fixo projetado na vizinhança deste valor e assim, atuar de forma bastante satisfatória.

Resíduos de indústria de celulose e papel na fertilidade do solo e no desenvolvimento de eucalipto

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Avaliação do potencial pozolânico da cinza de lodo de águas residuárias por meio de técnicas instrumentais

Pós-graduação em Engenharia Civil - FEIS

Estudo de dinâmicas populacionais aplicado a processos de tratamento biológico de efluentes

The purpose of this work is to perform studies of mathematical modeling of the relationship of interaction occurring between microrganisms participants from wastewater treatment processes aimed at understanding, through simulations, such as inter-relationships can affect the performance of such units. The methodology was the implementation in FORTRAN computer language of mathematical models of microbial interactions. The first model addresses the interaction of bacteria-forming flakes and filamentous bacteria in activated sludge systems, which seeks to strike a balance between these bacteria to improve efficiency of the process. Another model is studied the interaction between bacteria and protozoa in activated sludge systems and analyzing the efficiency of the process, observing the changes in daily load. Microbial interactions in anaerobic reactors were dealt a third model, in which there is the mutualistic interaction between acidogenic and methanogenic bacteria. In a fourth and final model was examined the relationship between the bacteria Acinetobacter sp. and Gordonia sp., which are present in activated sludge systems, showing the competitive capacity of Acinetobacter sp. can control the growth of unwanted bacteria.

Tratamento de efluentes provenientes de abatedouro de bovinos por meio de reator enzimático seguido de reator aeróbio operado em bateladas sequenciais

Brazil has one of the largest cattle herds in the world, so the cattle slaughter is one of the most important economic activities in the Brazilian market. But this activity requires a high demand of water, resulting in serious problems about the correct disposal of wastewater generated in the process. This effluent has a high pollution load, becoming its receiving bodies (streams and rivers) unfit for various activities such as public water supply, recreation, fisheries. To minimize the environmental impacts of its industrial wastewater and fallow the local environmental legislation, refrigerators must make the treatment of these effluents. This study aimed to verify the efficiency of a enzymatic reactor, when occur hydrolysis of lipids present in the effluent industrial of an cattle slaughter industry. The treatment system used was composed of two separate reactors: one being the anaerobic fluidized bed reactor (AFBR), inoculated with immobilized enzymes on the matrix support, and the other by sequential batch reactor (SBR) inoculated with activated sludge. Whereas, the reactors have been developed and installed at the Wastewater Treatment Laboratory, Faculdade de Ciências e Tecnologia, UNESP, campus Presidente Prudente. The procedure operating occurred differently for each reactor: preparation and inoculation of enzyme granules, filling the reactor, hydrolysis, and AFBR emptying, filling, aerobic reaction, sedimentation, and emptying the SBR. We performed three experimental stages, with the first and second stage of the work were done reactor analyzes separately, and the third step of the analysis were made with the interconnected reactors... (Complete abstract electronic access below)

Comparação da eficiência de reatores aeróbios com paralisações escalonadas de aeração em diferentes concentrações de matéria orgânica no tratamento de águas residuárias do processamento de farinha de mandioca

Cassava wastewater, generated during cassava processing, is a highly polluting and toxic waste. This study aimed to assess the relationship of cassava treatment efficiency in two aerobic sequencing batch reactors, cylindrical plastics (31cm height x 9cm diameter), with 2.0 liters capacity and 1.5 liters of work volume, a ratio of diameter and height of the liquid 1:2.5, with a running time of 24 hours and stoppage aeration for 16 hours with average feed of 2,500 and 6,000 mg COD. L -1. COD, pH, SVI and F/M were analyzed. The results obtained in the two reactors showed an average reduction of 94.1% and 76.8% organic content, respectively; pH values showed a rising in the output pH values compared to entry ones; SVI values obtained: 54.1 mL/g, 99.3 mL/g, respectively in a F/M ratio values worked out of 0.4 d-1 and 1,1 d-1 , respectively. The results demonstrated that the process has generated considerable saving in energy consumption compared to traditional continuous systems, was efficient and did not affect the efficiency overly of the reactor.

Avaliação do efeito da paralisação da aeração no tratamento biológico aeróbio da água residuária da indústria de farinha de mandioca

The cassava wastewater, generated during the cassava processing, is a pollutant and toxic waste. This study compared the efficiency of the cassava wastewater treatment in three batch aerobic systems with a ru1nning time of 24 hours, and aeration stoppage of 12h with 2,500, 6,000 and 10,000 mg COD L-1 . The systems were evaluated for COD, pH, SVI and F/M. The results showed that the reactor with aeration stoppage for 12 hours, with 2,500 mg COD L-1 , presented the best reduction in a process with considerable energy consumption saving compared to traditional continuous systems.

Potential of a bacterial consortium to degrade azo dye Disperse Red 1 in a pilot scale anaerobic-aerobic reactor

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)