Carbon film deposited by mass-selected low energy ion beam technique and ion bombardment effect

By mass-selected low energy ion beam deposition, amorphous carbon film was obtained. X-ray diffraction, Raman and Auger electron spectroscopy depth line shape measurements showed that such carbon films contained diamond particles. The main growth mechanism is subsurface implantation. Furthermore, it was indicated in a different way that ion bombardment played a decisive role in bias enhanced nucleation of chemical vapor deposition diamond.

A novel in-situ spectroelectrochemical technique with probe beam deflection: For study of the ion exchange between films on electrode surface and solutions

A novel in-situ spectroelectrochemical technique, the combination of probe beam deflection (PBD) with cyclic voltammetry (CV), was used to study the ion exchange process of prussian blue(PB) modified film electrode in contact with various electrolyte solutions. The ion exchange mechanism was verified as following: (K2Fe2+FeII)(CN)(6) -e(-)-k(+)reversible arrow +e(-)+k(+) (KFe3+FeII)(CN)(6) -ke(-)-xk(+)reversible arrow +xe(-)+kk(+) [(Fe3+FeIII)(CN)(6)](x)[(KFe3+FeII)(CN)(6)](1-x) where on reduction PB film in contact with an acidic KCl electrolyte, it was confirmed that protons enter into the PB film before K+ cations.

High-energy electron beam production by femtosecond laser interactions with exploding-foil plasmas

The interaction of an ultraintense, 30-fs laser pulse with a preformed plasma was investigated as a method of producing a beam of high-energy electrons. We used thin foil targets that are exploded by the laser amplified spontaneous emission preceding the main pulse. Optical diagnostics show that the main pulse interacts with a plasma whose density is well below the critical density. By varying the foil thickness, we were able to obtain a substantial emission of electrons in a narrow cone along the laser direction with a typical energy well above the laser ponderomotive potential. These results are explained in terms of wake-field acceleration.

Study of the application of the high performance liquid chromatography-particle beam interface-mass spectrometry technique on some pesiticides and the reduction phenomena in the system

This work includes two major parts. The first part of the work concentrated on the studies of the application of the highperfonnance liquid chromatography-particle beam interface-mass spectrometry system of some pesticides. Factors that have effects on the detection sensitivity were studied. The linearity ranges and detection limits of ten pesticides are also given in this work. The second part of the work concentrated on the studies of the reduction phenomena of nitro compounds in the HPLC-PB-MS system. Direct probe mass spectrometry and gas chromatography-mass spectrometry techniques were also used in the work. Factors that have effects on the reduction of the nitro compounds were studied, and the possible explanation is proposed. The final part of this work included the studies of reduction behavior of some other compounds in the HPLC-PB-MS system, included in them are: quinones, sulfoxides, and sulfones.

Study on the determination of molecular distance in organic dye mixtures using dual beam thermal lens technique

A sensitive method based on the principle of photothermal phenomena to study the energy transfer processes in organic dye mixtures is presented. A dual beam thermal lens method can be very effectively used as an alternate technique to determine the molecular distance between donor and acceptor in fluorescein–rhodamine B mixture using optical parametric oscillator.

Measurement of the absolute fluorescence quantum yield of rhodamine B solution using a dual-beam thermal lens technique

The dual-beam thermal lens technique has been found to be very effective for the measurement of fluorescence quantum yields of dye solutions. The concentration-dependence of the quantum yield of rhodamine B in methanol is studied here using this technique. The observed results are in line with the conclusion that the reduction in the quantum yield in the quenching region is essentially due to the non-radiative relaxation of the absorbed energy. The thermal lens has been found to become abberated above 40 mW of pump laser power. This low value for the upper limit of pump power is due to the fact that the medium is a resonantly absorbing one.

Studies on Fluorescence Efficiency and Photodegradation of Rhodamine 6G Doped PMMA Using a Dual Beam Thermal Lens Technique

In this paper we report the use of the dual beam thermal lens technique as a quantitative method to determine absolute fluorescence quantum efficiency and concentration quenching of fluorescence emission from rhodamine 6G doped Poly(methyl methacrylate) (PMMA), prepared with different concentrations of the dye. A comparison of the present data with that reported in the literature indicates that the observed variation of fluorescence quantum yield with respect to the dye concentration follows a similar profile as in the earlier reported observations on rhodamine 6G in solution. The photodegradation of the dye molecules under cw laser excitation is also studied using the present method.

Beam shaping of sectoral electromagnetic horn antennas using corner reflector technique

In the present thesis, possibility of beam shaping of sectoral horns and corner reflector systems'has been studied in detail. The experimental results obtained in the above two cases are compared. As far as the flanged sectoral horns are concerned, the special advantage is that the gain is increased without impairing impedance conditions. An intense study on corner reflector antennas shows that the been broadening or focussing will be possible by adjusting parameters involved. Beam tilting by imposing asymmetries is another interesting property of the systems. A comprehensive study of these fields has been presented in Chapter II. Chapter III is exclusively for describing the experimental techniques used in the present investigation. In Chapter IV, experimental results on flanged sectoral horns and corner reflector eyetses are presented. A comparative analysis of the experimental results obtained with flanged sectoral horns and corner reflector systems is presented in the Chapter V. The similarity and close resemblance in each aspects are shown by presenting typical results from these two eysteee. Theoretical aspects of both types of antennas are considered in Chapter VI. Attempts are made for co-ordinating the theoretical aspects and drawing a final conclusion. In Chapter VII. the final conclusion that the flanged sectoral horn may be considered as a corner reflector system has been drawn. The importance of the conclusions and usefulness are pointed out. The scope for further work in these lines has been indicated.

Corrugated flange technique for beam shaping of sectoral electromagnetic horn antennas

The need for improved feed systems for large reflector antennas employed in Radio Astronomy and Satellite tracking spurred the interest in horn antenna research in the 1960's. The major requirements were to reduce spill over, cross-polarisation losses,and to enhance the aperture efficiency to the order of about 75-8O%L The search for such a feed culminated in the corrugated horn. The corrugat1e 1 horn triggered widespread interest and enthusiasm, and a large amount of work(32’34’49’5O’52’53’58’65’75’79)has already been done on this type of antennas. The properties of corrugated surfaces has been investigated in detail. It was strongly felt that the flange technique and the use of corrugated surfaces could be merged together to obtain the advantages of both. This is the idea behind the present work. Corrugations are made on the surface of flange elements. The effect of various corrugation parameters are studied. By varying the flange parameters, a good amount of data is collected and analysed to ascertain the effects of corrugated flanges. The measurements are repeated at various frequencies, in the X— and S-bands. The following parameters of the system were studied: (a) beam shaping (b) gain (c) variation of V.S.U.R. (d) possibility of obtaining circularly polarised radiation from the flanged horn. A theoretical explanation to the effects of corrugated flanges is attempted on the basis of the line-source theory. Even though this theory utilises a simplified model for the calculation of radiation patterns, fairly good agreement between the computed pattern and experimental results are observed.