3-Mercaptopropionic Acid Capped Gold Nanoclusters: Quantized Capacitance in Aqueous Media

3-Mercaptopropionic add monolayer protected gold nanoclusters (MPA-MPCs) were synthesized and characterized by transmission electron microscopy, UV-Vis spectroscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The exact value of quantized double-layer capacitance of MPCS in aqueous media was obtained by differential pulse voltammograms.

Studies of electrochemical quantized capacitance charging of surface ensembles of silver nanoparticles

CTAB-stabilized silver nanoparticles were synthesized by NaBH4 reduction. The as-prepared nanoparticles can be self-assembled on 3-mercaptopropionic acid (MPA) modified gold electrode, which was supported strongly by XPS measurements. Exceptional long-term stability of the as-prepared colloidal silver aqueous solution and the desorption of silver nanoparticle ensemble on MPA after alcohol rinsing proved that these CTAB molecules adsorbed on silver core formed interdigitated bilayer structure. DPV and differential capacitance measurements were performed to characterize the as-prepared silver nanoparticle ensemble. and the interesting quantized capacitance charging behaviors were observed.

Relation algebra operations on formal contexts.

This paper discusses the use of relation algebra operations on formal contexts. These operations are a generalisation of some of the context operations that are described in the standard FCA textbook (Ganter & Wille, 1999). This paper extends previous research in this area with respect to applications and implementations. It also describes a software tool (FcaFlint) which in combination with FcaStone facilitates the application of relation algebra operations to contexts stored in many formats.

Algebra Llinol - Cyflwyniad

Cyfieithiad yw'r llyfr hwn o Linear Algebra - An Introduction a ymddangosodd gyntaf yn 1978 ac a gyhoeddwyd gan y cwmni Van Nostrand Reinhold. Cafwyd Ail Argraffiad yn 1982 a dros y blynyddoedd bu nifer o ail brintiadau. Yn y cyfamser cyfieithwyd y llyfr i'r Groeg a Thwrceg. Er i'r llyfr gael ei ddefnyddio dros y blynyddoedd gan nifer o fyfyrwyr yn Aberystwyth a oedd yn cyflwyno eu gwaith yn Gymraeg, nid oedd ar gael yn y Gymraeg. Dyma, o'r diwedd, ymgais i wneud rhyw fath o iawn am hynny. Er bod y llyfr wedi bod allan o brint yn y Saesneg ers rhai blynyddoedd yn awr, mae'n amlwg ei fod yn dal i gael ei gymeradwyo mewn nifer o brifysgolion. Felly, y gobaith yw y bydd o ddefnydd. Efallai mai'r peth nesaf bydd ei gyfiethu'n ?l i'r Saesneg! Mae nifer o newidiadau yn y fersiwn hwn. Mae'n siwr bod nifer o gamgymeriadau ac efallai gwelliannau posibl i'r cyfieithu - byddwn yn ddiolchgar dderbyn unrhyw awgrymiadau. Gellir eu cyflwyno hefyd drwy Dr Gwion Evans o'r Adran Fathemateg, Prifysgol Aberystwyth.

A Biomechanical Model of Human Oculomotor Plant Kinematics Based Upon Geometric Algebra

A biomechanical model of the human oculomotor plant kinematics in 3-D as a function of muscle length changes is presented. It can represent a range of alternative interpretations of the data as a function of one parameter. The model is free from such deficits as singularities and the nesting of axes found in alternative formulations such as the spherical wrist (Paul, l98l). The equations of motion are defined on a quaternion based representation of eye rotations and are compact atnd computationally efficient.

Magnetically quantized continuum distorted-wave theory in atomic and molecular collisions

The continuum distorted-wave eikonal initial-state (CDW-EIS) theory of Crothers and McCann (J Phys B 1983, 16, 3229) used to describe ionization in ion-atom collisions is generalized (G) to GCDW-EIS to incorporate the azimuthal angle dependence of each CDW in the final-state wave function. This is accomplished by the analytic continuation of hydrogenic-like wave functions from below to above threshold, using parabolic coordinates and quantum numbers including magnetic quantum numbers, thus providing a more complete set of states. At impact energies lower than 25 keVu(-1), the total ionization cross-section falls off, with decreasing energy, too quickly in comparison with experimental data. The idea behind and motivation for the GCDW-EIS model is to improve the theory with respect to experiment by including contributions from nonzero magnetic quantum numbers. We also therefore incidentally provide a new derivation of the theory of continuum distorted waves for zero magnetic quantum numbers while simultaneously generalizing it. (C) 2004 Wiley Periodicals, Inc.