Physical properties and bulk minerals from IODP Holes 308-U1322B, U1322D and U1324B

How the micro-scale fabric of clay-rich mudstone evolves during consolidation in early burial is critical to how they are interpreted in the deeper portions of sedimentary basins. Core samples from the Integrated Ocean Drilling Program Expedition 308, Ursa Basin, Gulf of Mexico, covering seafloor to 600 meters below sea floor (mbsf) are ideal for studying the micro-scale fabric of mudstones. Mudstones of consistent composition and grain size decrease in porosity from 80% at the seafloor to 37% at 600 mbsf. Argon-ion milling produces flat surfaces to image this pore evolution over a vertical effective stress range of 0.25 (71 mbsf) to 4.05 MPa (597 mbsf). With increasing burial, pores become elongated, mean pore size decreases, and there is preferential loss of the largest pores. There is a small increase in clay mineral preferred orientation as recorded by high resolution X-ray goniometry with burial.

Geochemistry of Qeqertaa xenoliths

This study presents electron microprobe data for dunite xenoliths from a lamprophyre dyke located on the island of Qeqertaa, West Greenland. The minimum age of this dyke is Palaeoproterozoic and it experienced amphibolite facies metamorphism and deformation during that era. The samples consist of nearly 200 xenoliths with a size range of 0.5-8 cm. These dunite xenoliths have olivine Mg#, that range from 80.3 to 94.6 (n = 579) with a mean of 92.6. Orthopyroxene is found in three xenoliths and garnet in five others. The latter suggests the depth of the Qeqertaa xenolith suite to be near the diamond stability-field, which is substantiated by the finding of diamonds in bulk samples of the Qeqertaa dyke. This further indicates the presence of a lithospheric mantle domain dominated by high-Mg# dunite to this depth in Palaeoproterozoic time. Cr-rich spinel, in the 0.1-0.2 mm size range, is found within and between olivine grains in individual xenoliths. These Cr-spinels yield Fe-Mg exchange temperatures of 400-600°C. However, the presence of intermediate spinel compositions spanning the lower temperature solvus suggests that equilibration temperatures were >550°C. Fe3+#, expressed as 100xFe3+/(Fe3++Al+Cr)), is shown to be a useful parameter in order to screen for altered spinel (Fe3+#>10) with disturbed Mg# and Cr#. The screened spinel data (Fe3+#<10) show a distinctly different trend in terms of spinel Cr# versus Mg#, compared to unmetamorphosed xenoliths in Tertiary lavas and dikes from Ubekendt Ejland and Wiedemann Fjord, respectively, also located within the North Atlantic craton. This difference likely reflects amphibolite facies metamorphic resetting of the Qeqertaa xenolith suite by Fe-Mg exchange. Given the similarity of the Qeqertaa xenolith suite with the Ubekendt and Wiedemann suites, in terms of their olivine Mg# and spinel Cr# distribution, high-Mg# dunite is likely to be an important component of the subcontinental lithospheric mantle beneath the North Atlantic craton and appears to have spanned a vertical distance of at least 150 km in this region, even during the Palaeoproterozoic.

Biosiliceous sedimentation at ODP Site 128-798

Upper Pliocene through Holocene sediments recovered at Site 798 in the Japan Sea (Oki Ridge) exhibit rhythmic variation in weight percent biogenic opal at intervals of ~5 m and periods equivalent to the 41-k.y. obliquity cycle. Variance at 17 and 100 k.y. is observed prior to 1.3 Ma. These cycles are also clearly defined by log data and correspond to clusters of decimeter-scale dark-colored sediment units alternating with clusters of light-colored units. Opal content varies between 3% and 22% between 0 and 1.3 Ma and from 3% to 43% between 1.3 and 2.6 Ma. Long-term opal accumulation rates average 1.8 g/cm**2/k.y. in the late Pliocene/early Pleistocene and decrease by about 60% at ~1.3 Ma. Rough calculations suggest that opal accumulation rates increased and terrigenous flux decreased during the Holocene relative to the last glacial period. Our age control is not yet sufficient to allow a similar analysis of the 41-k.y. cyclicity in opal content throughout the Pleistocene. Stable isotope results from planktonic foraminifers confirm previous suggestions of a strong surface-water freshening event during isotope stage 2; however, this episode appears to be unique during the Pleistocene. Benthic foraminifers are depleted in 18O during parts of glacial stages 2 and 6 relative to adjacent interglacials, suggesting unusual warming and/or freshening of deep waters. Collectively, the stable isotope and %opal data are consistent with continuing isolation of the Japan Sea during the Quaternary with important transitions occurring at 1.3, 0.7 to 1.0, and 0.2 to 0.3 Ma. Complex relationships among the stable isotope results, %opal data, and sediment characteristics such as color and organic and inorganic carbon content preclude development of a simple model to explain cyclical sedimentation. Opal maxima occur within both light and dark intervals and the processes that control surface-water productivity are at times decoupled from the factors that regulate deep-water dysaerobia. We suggest that water column overturn is controlled largely by regional atmospheric circulation that must also have an as yet poorly understood effect on surface-water fertility.

Biomarker records of DSDP Hole 24-231 and terrestrial sediments

ntegrated terrestrial and marine records of northeast African vegetation are needed to provide long high resolution records of environmental variability with established links to specific terrestrial environments. In this study, we compare records of terrestrial vegetation preserved in marine sediments in the Gulf of Aden [Deep Sea Drilling Project (DSDP) Site 231] and an outcrop of lacustrine sediments in the Turkana Basin, Kenya, part of the East African Rift System. We analyzed higher plant biomarkers in sediments from both deposits of known equivalent age, corresponding to a ca. 50-100 ka humid interval prior to the b-Tulu Bor eruption ca. 3.40 Ma, when the Lokochot Lake occupied part of the Turkana Basin. Molecular abundance distributions indicate that long chain n-alkanoic acids in marine sediments are the most reliable proxy for terrestrial vegetation (Carbon Preference Index, CPI = 4.5), with more cautious interpretation needed for n-alkanes and lacustrine archives. Marine sediments record carbon isotopic variability in terrestrial biomarkers of 2-3 per mil, roughly equivalent to 20% variability in the C3/C4 vegetation contribution. The proportion of C4 vegetation apparently increased at times of low terrigenous dust input. Terrestrial sediments reveal much larger (2-10 per mil) shifts in n-alkanoic acid delta13C values. However, molecular abundance and isotopic composition suggest that microbial sources may also contribute fatty acids, contaminating the lacustrine sedimentary record of terrestrial vegetation.

Carbon and oxygen isotopic composition of benthic foraminifers from ODP Site 167-1014 and Hole 167-1020C

Benthic foraminiferal stable isotope data are presented for Sites 1014 (Tanner Basin, 1176 m) and 1020 (Gorda Ridge, 3040 m) to constrain past changes in Pacific deep- and intermediate-water nutrient chemistry associated with the onset of large-amplitude 100-k.y. climate cycles after ~900 ka. The Site 1014 data were based on analyses of separate species of Cibicidoides, whereas only Cibicidoides wuellerstorfi was used to generate the Site 1020 record. The present data span 380-920 and 620-950 ka at Sites 1014 and 1020, respectively.