Biomarker records of DSDP Hole 24-231 and terrestrial sediments

ntegrated terrestrial and marine records of northeast African vegetation are needed to provide long high resolution records of environmental variability with established links to specific terrestrial environments. In this study, we compare records of terrestrial vegetation preserved in marine sediments in the Gulf of Aden [Deep Sea Drilling Project (DSDP) Site 231] and an outcrop of lacustrine sediments in the Turkana Basin, Kenya, part of the East African Rift System. We analyzed higher plant biomarkers in sediments from both deposits of known equivalent age, corresponding to a ca. 50-100 ka humid interval prior to the b-Tulu Bor eruption ca. 3.40 Ma, when the Lokochot Lake occupied part of the Turkana Basin. Molecular abundance distributions indicate that long chain n-alkanoic acids in marine sediments are the most reliable proxy for terrestrial vegetation (Carbon Preference Index, CPI = 4.5), with more cautious interpretation needed for n-alkanes and lacustrine archives. Marine sediments record carbon isotopic variability in terrestrial biomarkers of 2-3 per mil, roughly equivalent to 20% variability in the C3/C4 vegetation contribution. The proportion of C4 vegetation apparently increased at times of low terrigenous dust input. Terrestrial sediments reveal much larger (2-10 per mil) shifts in n-alkanoic acid delta13C values. However, molecular abundance and isotopic composition suggest that microbial sources may also contribute fatty acids, contaminating the lacustrine sedimentary record of terrestrial vegetation.

Geochemical investigation and determination of hiatuses on Voering Plateau sediment records

The sediments recovered on ODP Leg 104 have been reported to be characterized by hiatuses. The hiatuses were defined by biostratigraphy and were believed to be caused by erosion related to temporary changes of bottom current composition and velocity. They have been associated with major paleoenvironmental changes, reorganization of global deep water production, and increased bottom water flows. Because of the importance of hiatuses for ongoing research, we decided to closely investigate the sedimentation history for the most significant Pliocene and Miocene biostratigraphic hiatuses by sedimentologic and geochemical means. The sedimentologic studies include clay mineral distributions, grain size data, and organic carbon concentrations. The geochemical studies include determination of 87/86Sr ratios, 10Be and Ir concentrations. The results of the sedimentologic studies suggest either that paleoenvironmental changes associated with hiatuses are not represented in the preserved sediments, or that the hiatuses are an artifact of interpretation of the biostratigraphic data. Strontium isotopes indicate continuous sedimentation for the interval investigated at Site 642, an interpretation confirmed by the steady decline in 10Be. 87/86Sr ratios in the interval from above and below proposed hiatuses H 2.2/2.3 and H2.1/2.2 at Site 643 display stronger changes with depth than expected by steady sedimentation. Ir data for this same interval indicate reduced sedimentation rates. Combining both, sedimentologic and geochemical evidence, the proposed hiatuses could not be confirmed and may represent preservation artifacts.