Sedimentological and pollen records from the fjord region of southern Chile

The position and intensity of the southern westerly wind belt varies seasonally as a consequence of changes in sea surface temperature. During the austral winter, the belt expands northward and the wind intensity in the core decreases. Conversely, during the summer, the belt contracts, and the intensity within the core is strengthened. Reconstructions of the westerly winds since the last glacial maximum, however, have suggested that changes at a single site reflected shifts throughout the entire southern wind belt. Here we use sedimentological and pollen records to reconstruct precipitation patterns over the past 12,500 yr from sites along the windward side of the Andes. Precipitation at the sites, located in the present core and northern margin of the westerlies, is driven almost entirely by the wind belt, and can be used to reconstruct its intensity. Rather than varying coherently throughout the Holocene epoch, we find a distinct anti-phasing of wind strength between the core and northern margin over multi-millennial timescales. During the early Holocene, the core westerlies were strong whereas the northern margin westerlies were weak. We observe the opposite pattern in the late Holocene. As this variation resembles modern seasonal variability, we suggest that our observed changes in westerly wind strength can best be explained by variations in sea surface temperature in the eastern South Pacific Ocean.

Sedimentation patters in the eastern equatorial Pacific Ocean

The post-middle Miocene evolution of sedimentary patterns in the eastern equatorial Pacific Ocean has been deduced from a compilation and synthesis of CaCO3, opal, and nannofossil assemblage data from 11 sites drilled during Leg 138. Improvements in stratigraphic correlation and time scale development enabled the construction of lithostratigraphic and chronostratigraphic frameworks of exceptional quality. These frameworks, and the high sedimentation rates (often exceeding 4 cm/k.y.) provided a detailed and synoptic paleoceanographic view of a large and highly productive region. The three highlights that emerge are: (1) a middle late Miocene "carbonate crash" (Lyle et al., this volume); (2) a late Miocene-early Pliocene "biogenic bloom"; and (3) an early Pliocene "opal shift". During the carbonate crash, an interval of dissolution extending from -11.2 to 7.5 Ma, CaCO3 accumulation rates declined to near zero over much of the eastern equatorial Pacific, whereas opal accumulation rates remained substantially unchanged. The crash nadir, near 9.5 Ma, was marked by a brief shoaling of the regional carbonate compensation depth by more than 1400 m. The carbonate crash has been correlated over the entire tropical Pacific Ocean, and has been attributed to tectonically-induced changes in abyssal flow through the Panamanian seaway. The biogenic bloom extended from 6.7 to 4.5 Ma, and was characterized by an overall increase in biogenic accumulation and by a steepening of the latitudinal accumulation gradient toward the equator. The bloom has been observed over a large portion of the global ocean and has been linked to increased productivity. The final highlight, is a distinct and permanent shift in the locus of maximum opal mass accumulation rate at 4.4 Ma. This shift was temporally, and perhaps causally, linked to the final closure of the Panamanian seaway. Before 4.4 Ma, opal accumulation was greatest in the eastern equatorial Pacific Basin (near 0°N, 107°W). Since then, the highest opal fluxes in the equatorial Pacific have occurred in the Galapagos region (near 3°S, 92°W).

Physical properties and abundance of diatoms of the ANDRILL AND1-1B drill core

In the austral summer of 2006/7 the ANDRILL MIS (ANtarctic geological DRILLing- McMurdo Ice Shelf) project recovered a 1285 m sediment core from beneath the Ross Ice Shelf near Hut Point Peninsula, Ross Island, Antarctica in a flexural moat associated with the volcanic loading of Ross Island. Contained within the upper ~600 m of this core are sediments recording 38 glacial to interglacial cycles of Early Pliocene to Pleistocene time, including 13 discrete diatomite units (DU). The longest of these, DU XI, is ~76 m thick, contains two distinct unconformities marked by layers of volcanic brecciated sands, and has been assigned an Early to Mid-Pliocene age (5-3 Ma). A detailed record (avg. sample spacing of 33 cm) of the siliceous microfossil assemblages have been generated for DU XI and used in conjunction with geochemical and sedimentological data to subdivide DU XI into four discrete subunits of continuous sedimentation. Within each unit, changes in diatom assemblages have been correlated with the d18O record, providing a temporal resolution as high as 600 yr, and allowing for the construction of a detailed age model and calculation of associated sediment accumulation rates within DU XI. Results indicate a productivity-dominated sedimentary record with higher sediment accumulation rates containing a greater proportion of hemipelagic mud occurring during relatively cool periods and reduced accumulation during warmer intervals. This implies that even during periods of substantial warmth, Milankovitch-paced changes in Antarctic ice volume can be linked to ecological changes recorded as shifts in diatom assemblages.

(Table 1) Density values of ODP Leg 126 samples

Sediment dry-bulk density values are essential components of mass accumulation rate calculations. This manuscript presents three equations to calculate dry-bulk density from laboratory measurements of physical properties that have been corrected for the salt content of the pore fluid. In addition, two equations for use with values not corrected for salt content are included. Derivations of the equations from first principles are presented. The second part of the manuscript briefly examines laboratory measurements of the various properties used in the dry-bulk density equations. A discussion of the problems inherent in the density measurements and recommendations are included. This work represents the first comprehensive compilation of equations of dry-bulk density and should prove useful to all scientists who investigate accumulation rates.

Benthic and fish community composition as well as water quality along the Thousand Islands north of the megacity Jakarta, Indonesia

Worldwide, coral reefs are challenged by multiple stressors due to growing urbanization, industrialization and coastal development. Coral reefs along the Thousand Islands off Jakarta, one of the largest megacities worldwide, have degraded dramatically over recent decades. The shift and decline in coral cover and composition has been extensively studied with a focus on large-scale gradients (i.e. regional drivers), however special focus on local drivers in shaping spatial community composition is still lacking. Here, the spatial impact of anthropogenic stressors on local and regional scales on coral reefs north of Jakarta was investigated. Results indicate that the direct impact of Jakarta is mainly restricted to inshore reefs, separating reefs in Jakarta Bay from reefs along the Thousand Islands further north. A spatial patchwork of differentially degraded reefs is present along the islands as a result of localized anthropogenic effects rather than regional gradients. Pollution is the main anthropogenic stressor, with over 80 % of variation in benthic community composition driven by sedimentation rate, NO2, PO4 and Chlorophyll a. Thus, the spatial structure of reefs is directly related to intense anthropogenic pressure from local as well as regional sources. Therefore, improved spatial management that accounts for both local and regional stressors is needed for effective marine conservation.

Geochemistry of tropical Atlantic sediments of Marine Isotope Stage 4

Antarctic Intermediate Water (AAIW) and Subantarctic Mode Water (SAMW) are the main conduits for the supply of dissolved silicon (silicic acid) from the deep Southern Ocean (SO) to the low-latitude surface ocean and therefore have an important control on low-latitude diatom productivity. Enhanced supply of silicic acid by AAIW (and SAMW) during glacial periods may have enabled tropical diatoms to outcompete carbonate-producing phytoplankton, decreasing the relative export of inorganic to organic carbon to the deep ocean and lowering atmospheric pCO2. This mechanism is known as the "silicic acid leakage hypothesis" (SALH). Here we present records of neodymium and silicon isotopes from the western tropical Atlantic that provide the first direct evidence of increased silicic acid leakage from the Southern Ocean to the tropical Atlantic within AAIW during glacial Marine Isotope Stage 4 (~60-70 ka). This leakage was approximately coeval with enhanced diatom export in the NW Atlantic and across the eastern equatorial Atlantic and provides support for the SALH as a contributor to CO2 drawdown during full glacial development.

Biosiliceous sedimentation at ODP Site 128-798

Upper Pliocene through Holocene sediments recovered at Site 798 in the Japan Sea (Oki Ridge) exhibit rhythmic variation in weight percent biogenic opal at intervals of ~5 m and periods equivalent to the 41-k.y. obliquity cycle. Variance at 17 and 100 k.y. is observed prior to 1.3 Ma. These cycles are also clearly defined by log data and correspond to clusters of decimeter-scale dark-colored sediment units alternating with clusters of light-colored units. Opal content varies between 3% and 22% between 0 and 1.3 Ma and from 3% to 43% between 1.3 and 2.6 Ma. Long-term opal accumulation rates average 1.8 g/cm**2/k.y. in the late Pliocene/early Pleistocene and decrease by about 60% at ~1.3 Ma. Rough calculations suggest that opal accumulation rates increased and terrigenous flux decreased during the Holocene relative to the last glacial period. Our age control is not yet sufficient to allow a similar analysis of the 41-k.y. cyclicity in opal content throughout the Pleistocene. Stable isotope results from planktonic foraminifers confirm previous suggestions of a strong surface-water freshening event during isotope stage 2; however, this episode appears to be unique during the Pleistocene. Benthic foraminifers are depleted in 18O during parts of glacial stages 2 and 6 relative to adjacent interglacials, suggesting unusual warming and/or freshening of deep waters. Collectively, the stable isotope and %opal data are consistent with continuing isolation of the Japan Sea during the Quaternary with important transitions occurring at 1.3, 0.7 to 1.0, and 0.2 to 0.3 Ma. Complex relationships among the stable isotope results, %opal data, and sediment characteristics such as color and organic and inorganic carbon content preclude development of a simple model to explain cyclical sedimentation. Opal maxima occur within both light and dark intervals and the processes that control surface-water productivity are at times decoupled from the factors that regulate deep-water dysaerobia. We suggest that water column overturn is controlled largely by regional atmospheric circulation that must also have an as yet poorly understood effect on surface-water fertility.

Late Miocene carbon isotope and paleoproductivity record

We examine whether or not a relationship exists between the late Miocene carbon isotope shift (~7.6-6.6 Ma) and marine productivity at four sites from the Indian and Pacific Oceans (Ocean Drilling Program Sites 721, 1146, 1172, and 846). We use a multiproxy approach based on benthic foraminiferal accumulation rates, elemental ratios, and dissolution indices, and we compare these data to benthic foraminiferal d13C values measured on the same samples. Although some of these sites have been targeted previously in studies of either the late Miocene/early Pliocene "biogenic bloom" (Sites 721 and 846) or the late Miocene carbon isotope shift (Site 1172), our records are the first to establish paired proxy records of carbon isotopes and paleoproductivity allowing a direct assessment of a potential link. Our results indicate that at all sites, productivity increased sometime during the d13C shift; at three sites (721, 1146, and 846), productivity increased at the beginning of the shift. The correlation coefficients derived from linear regression between micropaleontologically derived productivity and foraminiferal d13C values are relatively high during the time interval containing the late Miocene d13C shift (and statistically significant at three of the sites). Carbon flux and isotope mass balance considerations illustrate that transfer of organic matter between the terrestrial and marine reservoirs together with enhanced oceanic upwelling best approximates observed changes in carbon isotope records and paleoproductivity. We note that long-term trend in the Site 846 paleoproductivity record can be correlated to the long-term trend in the Site 848 eolian flux reconstructions of Hovan (1995, doi:10.2973/odp.proc.sr.138.132.1995) hinting at a link between strengthened wind regime and productivity during the late Miocene.

Density and stable oxygen isotope profiles of four snow pits from Berkner Island, Filchner-Ronne Ice Shelf, Antarctica

The ice cap on Berkner Island is grounded on bedrock within the Filchner-Ronne Ice Shelf and is, therefore, expected to be a well-suited place to retrieve long-term ice-core records reflecting the environmental situation of the Weddell Sea region. Shallow firn cores were drilled to 11 m at the two main summits of Berkner Island and analysed in high depth resolution for electrical d.c. conductivity (ECM), stable isotopes, chloride, sulphate, nitrate and methane-sulphonate (MSA). From the annual layering of dD and non-sea-salt (nss) sulphate, a mean annual snow accumulation of 26.6 cm water at the north dome and 17.4 cm water at the south dome are obtained. As a result of ineffective wind scouring indicated by a relatively low near-surface snow density, regular annual cycles are found for all species at least in the upper 4-5 m. Post depositional changes are responsible for a substantial decrease of the seasonal dD and nitrate amplitude as well as for considerable migration of the MSA signal operating below a depth of 3-4 m. The mean chemical and isotopic firn properties at the south dome correspond to the situation on the Filchner-Ronne Ice shelf at a comparable distance to the coast, whereas the north dome is found to be more influenced by maritime air masses. Persistent high sea-salt levels in winter snow at Berkner Island heavily obscure the determination of nss sulphate probably due to sulphate fractionation in the Antartic sea-salt aerosols. Estimated time-scales predict ages at 400 m depth to be ca. 2000 years for the north and ca. 3000 years for the south dome. Pleistocene ice is expected in the bottom 200 and 300 m, respectively.

Physical and chemical investigations on ice cores from the Filchner-Ronne Ice Shelf

The accumulation and distribution of the 2H content of near-surface layers in the eastern part of the Ronne Ice Shelf were determined from 16 firn cores drilled to about 10 m depth during the Filchner IIIa and IV campaigns in 1990 and 1992, respectively. The cores were dated stratigraphically by seasonal d2H variations in the firn. In addition, 3H and high-resolution chemical profiles were used to assist in dating. Both the accumulation rate and the stable-isotope content decrease with increasing distance from the ice edge: the d2H values range from about -195 per mil at the ice edge to -250 per mil at BAS sites 5 and 6, south of Henry Ice Rise, and the accumulation rates from about 210 to 90 kg/m**2/a. The d2H values of the near-surface firn and the 10 m firn temperatures (Theta) at individual sites are very well correlated: ddelta2H/dTheta=(10.3±0.6)per mil /K; r = 0.97. The d2H profiles of the two ice cores B13 and B15 drilled in 1990 and 1992 to 215 and 320 m depth, respectively, reflect the gradual depletion in 2H in the firn upstream of the drill sites. Comparison with tlie surface data indicates that the ice above 142 m in core B15 and above 137 m in core B13 was deposited on the ice shelf, whereas the deeper ice, down to 152.8 m depth, most probably originated from the margin of the Antarctic ice sheet.

X-ray fluorescence data (calcium and iron), bulk organic d13C, and dinoflagellate cysts of ODP Hole 189-1172D

The 'Paleocene/Eocene Thermal Maximum' or PETM (~55 Ma) was associated with dramatic warming of the oceans and atmosphere, pronounced changes in ocean circulation and chemistry, and upheaval of the global carbon cycle. Many relatively complete PETM sequences have by now been reported from around the world, but most are from ancient low- to midlatitude sites. ODP Leg 189 in the Tasman Sea recovered sediments from this critical phase in Earth history at Sites 1171 and 1172, potentially representing the southernmost PETM successions ever encountered (at ~70° to 65° S paleolatitude). Downhole and core logging data, in combination with dinoflagellate cyst biostratigraphy, magneto-stratigraphy, and stable isotope geochemistry indicate that the sequences at both sites were deposited in a high accumulation-rate, organic rich, marginal marine setting. Furthermore, Site 1172 indeed contains a fairly complete P-E transition, whereas at Site 1171, only the lowermost Eocene is recovered. However, at Site 1172, the typical PETM-indicative acme of the dinocyst Apectodinium was not recorded. We conclude that unfortunately, the critical latest Paleocene and PETM intervals are missing at Site 1172. We relate the missing section to a sea level driven hiatus and/or condensed section and recovery problems. Nevertheless, our integrated records provide a first-ever portrait of the trend toward, and aftermath of, the PETM in a marginal marine, southern high-latitude setting.

A 31,000-year high-resolution record from two sediment cores off northwest Africa

Benthic foraminiferal assemblage compositions and sedimentary geochemical parameters were analyzed in two radiocarbon dated sediment cores from the upwelling area off NW Africa at 12°N, to reconstruct productivity changes during the last 31 kyr. High-latitude cold events and variations in low-latitude summer insolation influenced humidity, wind systems, and the position of the tropical rain belt over this time period. This in turn caused changes in intensity and seasonality of primary productivity off the southern Northwest African continental margin. High accumulation rates of benthic foraminifera, carbonate, and organic carbon during times of north Atlantic melt water events Heinrich 2 (25.4 to 24.3 kyr BP) and 1 (16.8 to 15.8 kyr BP) indicate high productivity. Dominance of infaunal benthic foraminiferal species and high numbers of deep infaunal specimens during that time indicate a strong and sustained supply of refractory organic matter reworked from the upper slope and shelf. A more southerly position of the tropical rainbelt and the Northeast trade wind belt during Heinrich 2 and 1 may have enhanced wind intensity and almost permanent upwelling, driving this scenario. A phytodetritus-related benthic fauna indicates seasonally pulsed input of labile organic matter but generally low year-round productivity during the Last Glacial Maximum (23 to 18 kyr BP). The tropical rainbelt is more expanded to the North than during Heinrich Events, and relatively weak NE trade winds resulted in seasonal and weak upwelling, thus lower productivity. High productivity characterized by a seasonally high input of labile organic matter, is indicated for times of orbital forced warming, such as the African Humid Period (9.8 to 7 kyr BP). An intensified African monsoon during boreal summer and the northernmost position of the tropical rainbelt within the last 31 kyr resulted in enhanced river discharge from the northward-extended drainage area (or river basin) initiating intense phytoplankton blooms. In the late Holocene (4 to 0 kyr BP) strong carbonate dissolution may have been caused by even more enhanced organic matter fluxes to the sea floor. Increasing aridity on the continent and stronger NE trade winds induced intensive, seasonal coastal upwelling.