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铈掺杂稀土焦硅酸盐系列晶体Re2Si2O7(其中Re=Lu3+、Y3+、Gd3+等)作为新型无机闪烁晶体材料,近来引起科研人员的关注。本文阐述了稀土焦硅酸盐系列晶体Re2Si2O7的结构、晶体生长方法、闪烁性能和有待进一步研究的问题。

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作为发射在1μm波段的二极管抽运全固态激光器的增益介质,掺Yb离子的晶体备受关注。掺Yb晶体具有能级结构简单,量子缺陷低(〈0.1),量子效率高等优点。目前成功使用掺Yb的晶体作为增益介质的飞秒激光振荡器已有很多报道,如Yb:BOYSE,Yb:KYW,Yb:SYSE等。

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Raman spectroscopy was used to study the molecular structure of a series of selected rare earth (RE) silicate crystals including Y2SiO5 (YSO), LU2SiO5 (LSO), (Lu0.5Y0.5)(2)SiO5 (LYSO) and their ytterbium-doped samples. Raman spectra show resolved bands below 500 cm(-1) region assigned to the modes of SiO4 and oxygen vibrations. Multiple bands indicate the nonequivalence of the RE-O bonds and the lifting of the degeneracy of the RE ion vibration. Low intensity bands below 500 cm(-1) are an indication of impurities. The (SiO4)(4-) tetrahedra are characterized by bands near 200 cm(-1) which show a separation of the components of nu(4) and nu(2), in the 500-700 cm(-1) region which are attributed to the distorting bending vibration and in the 880-1000 cm(-1) region which are attributed to the symmetric and antisymmetric stretching vibrational modes. The majority of the bands in the 300-610 cm(-1) region of Re2SiO5 were found to arise from vibrations involving both Si and RE ions, indicating that there is considerable mixing of Si displacements with Si-O bending modes and RE-0 stretching modes. The Raman spectra of RE silicate crystals were analyzed in terms of the molecular structure of the crystals, which enabled separation of the bands attributed to distinct vibrational units. Copyright (C) 2007 John Wiley & Sons, Ltd.

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[ES] La industria ósea postpaleolítica, por lo general, pocas veces ha merecido la atención que se le ha concedido a la fabricada durante el Paleolítico Superior. No obstante una de dichas excepciones serán los denominados ídolos-espátulas con decoración acanalada en su mitad proximal, trabajados sobre tibias de "Capra/Ovis" y procedentes por lo que hasta ahora conocemos de contextos sepulcrales megalíticos. En su morfología deben de señalarse el extremo activo romo, al modo de otras espátulas tan comunes en contextos neolíticos, y el extremo proximal decorado con profundos acanalamientos que conforman motivos geométricos más o menos complejos (espiral, zig-zag, etc.) en unos casos y en menos alguna figura antropomorfa femenina. Los primeros hallazgos se realizaron en la provincia de Álava durante la década de los sesenta, destacando entre ellos los procedentes del sepulcro de corredor de San Martín (Laguardia), a los que se sucedieron otros como los de Kurtzebide, Los Llanos, etc. en el mismo territorio y los importantes conjuntos hallados en distintas provincias de la Meseta Norte y en La Rioja. Todos ellos debido al tipo de contexto del que proceden y las características de los ídolos-espátula ritual dan cierto grado de homogeneidad ideológico o religioso a todo el territorio. No obstante, fuera de este territorio y muy alejados desde el punto de vista geográfico existen otros ejemplares (Tell Halula -Siria-, Sesklo, Agios Petras -Grecia-) que muestran gran similitud tipológica aunque no un nexo de unión entre ambas zonas. Por otra parte, hay que subrayar la notable mayor antigüedad del foco oriental y que el contexto del que proceden no es funerario como en el caso de los ejemplares occidentales.

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Otter trawls are very effective at capturing flatfish, but they can affect the seaf loor ecosystems where they are used. Alaska f latf ish trawlers have very long cables (called sweeps) between doors and net to herd fish into the path of the trawl. These sweeps, which ride on and can disturb the seaf loor, account for most of the area affected by these trawls and hence a large proportion of the potential for damage to seaf loor organisms. We examined modifications to otter trawls, such that disk clusters were installed at 9-m intervals to raise trawl sweeps small distances above the seafloor, greatly reducing the area of direct seafloor contact. A critical consideration was whether flatfish would still be herded effectively by these sweeps. We compared conventional and modified sweeps using a twin trawl system and analyzed the volume and composition of the resulting catches. We tested sweeps raised 5, 7.5, and 10 cm and observed no significant losses of flatfish catch until sweeps were raised 10 cm, and those losses were relatively small (5–10%). No size composition changes were detected in the flatfish catches. Alaska pollock (Theragra chalcogramma) were captured at higher rates with two versions of the modified sweeps. Sonar observations of the sweeps in operation and the seaf loor after passage confirmed that the area of direct seafloor contact was greatly reduced by the modified sweep