Geochemistry of dikes and lavas from the north wall of the Hess Deep Rift

An investigation of ~1-m.y.-old dikes and lavas from the north wall of the Hess Deep Rift (2°15'N, 101°30'W) collected during Alvin expeditions provides a detailed view of the evolution of fast spreading oceanic crust. The study area encompasses 25 km of an east-west flow line, representing ~370,000 years of crustal accretion at the East Pacific Rise. Samples analyzed exhibit depleted incompatible trace element abundances and ratios [(La/Sm)N < 1]. Indices of fractionation (MgO), and incompatible element ratios (La/Sm, Nb/Ti) show no systematic trends along flow line. Rather, over short (<4 m) and long (~25 km) distances, significant variations are observed in major and trace element concentrations and ratios. Modeling of these variations attests to the juxtaposition of dikes of distinct parental magma compositions. These findings, combined with studies of segmentation of the subaxial magma chamber and lateral magma transport in dikes along rift-dominated systems, suggest a more realistic model of the magmatic system underlying the East Pacific Rise relative to the commonly assumed twodimensional model. In this model, melts from a heterogeneous mantle feed distinct portions of a segmented axial magma reservoir. Dikes emanating from these distinct reservoirs transport magma along axis, resulting in interleaved dikes and host lavas with different evolutionary histories. This model suggests the use of axial or flow line lava compositions to infer the evolution of axial magma chambers should be approached with caution because dikes may never erupt lava or may transport magma significant distances along axis and erupt lavas far from their axial magma chamber of origin.

Deep drilling of glaciers: Russian projects in the Arctic (1975-1995)

The data collection "Deep Drilling of Glaciers: Soviet-Russian projects in Arctic, 1975-1995" was collected by the following basic considerations: - compilation of deep (>100 m) drilling projects on Arctic glaciers, using data of (a) publications; (b) archives of IGRAN; (c) personal communication of project participants; - documentation of parameters, references. Accuracy of data and techniques applied to determine different parameters are not evaluated. The accuracy of some geochemical parameters (up to 1984 and heavy metalls) is uncertain. Most reconstructions of ice core age and of annual layer thickness are discussed; - digitizing of published diagrams (in case, when original numerical data were lost) and subsequent data conversion to equal range series and adjustment to the common units. Therefore, the equal-range series were calculated from original data or converted from digitized chart values as indicated in the metadata. For the methodological purpose, the equal-range series obtained from original and reconstructed data were compared repeatedly; the systematic difference was less then 5-7%. Special attention should be given to the fact, that the data for individual ice core parameters varies, because some parameters were originally measured or registered. Parameters were converted in equal-range series using 2 m steps; - two or more parameter values were determined, then the mean-weighted (i.e. accounting the sample length) value is assigned to the entire interval; - one parameter value was determined, measured or registered independently from the parameter values in depth intervals which over- and underlie it, then the value is assigned to the entire interval; - one parameter value was determined, measured or registered for two adjoining depth intervals, then the specific value is assigned to the depth interval, which represents >75% of sample length ; if each of adjoining depth intervals represents <75% of sample length, then the correspondent parameter value is assigned to both intervals of depth. This collection of ice core data (version 2000) was made available through the EU funded QUEEN project by S.M. Arkhipov, Moscow.

Germanium contents, Ge/Si ratios, and Sr isotopic composition in deep-sea cherts

Nineteen chert samples from a continuous core of the DSDP (Leg 17, Hole 167) were analysed for Ge; in addition we analysed five samples from other cores. The ages range between Late Jurassic, and Late Eocene. The concentration of Ge changes with age from 0.87 ppm in the oldest samples to 0.23 ppm in the youngest (equivalent to a Ge/Si decrease from 0.00000072 to 0.00000019). The decrease in Ge/Si is well correlated with the 87Sr/86Sr ratio in sea water of the relevant age. The interpretation of this trend may reflect: (a) different levels of Ge/Si in sea water as a result of a different ratio between hydrothermal and riverine input, (b) a diagenetic trend in siliceous sediments, (c) recording (by radiolaria) a transition between a radiolaria dominated ocean (with relatively high Ge/Si ratios in sea water) and diatom domination or (d) a combination of the above.

Global habitat suitability of deep-water Antipatharia

Antipatharia are a diverse group of corals with many species found in deep water. Many Antipatharia are habitat for associates, have extreme longevity and some species can occur beyond 8500 m depth. As they are major constituents of 'coral gardens', which are Vulnerable Marine Ecosystems (VMEs), knowledge of their distribution and environmental requirements is an important pre-requisite for informed conservation planning particularly where the expense and difficulty of deep-sea sampling prohibits comprehensive surveys. This study uses a global database of Antipatharia distribution data to perform habitat suitability modelling using the Maxent methodology to estimate the global extent of black coral habitat suitability. The model of habitat suitability is driven by temperature but there is notable influence from other variables of topography, surface productivity and oxygen levels. This model can be used to predict areas of suitable habitat, which can be useful for conservation planning. The global distribution of Antipatharia habitat suitability shows a marked contrast with the distribution of specimen observations, indicating that many potentially suitable areas have not been sampled, and that sampling effort has been disproportionate to shallow, accessible areas inside marine protected areas (MPAs). Although 25% of Antipatharia observations are located in MPAs, only 7-8% of predicted suitable habitat is protected, which is short of the Convention on Biological Diversity target to protect 10% of ocean habitats by 2020.

Physical properties of deep sea sediments

Erstmals quantitativ bearbeitete Rutschungen aus dem Tiefseebereich des äquatorialen Ostatlantiks liegen auf Hängen von 0,4 Grad und 0,7 Grad - das ist sehr viel flacher als die für statische Rutschungsauslösung benötigte kritische Hangneigung (14 Grad bis 16 Grad ). Im Gegensatz zu Flachwassergebieten kann bei Wassertiefen von über 4000 m natürlich der Einfluß von Wellenwirkung und Tidenhub auf die Hangstabilität vernachlässigt werden. Die Sedimentationsraten sind in diesem Bereich zur Bildung eines Porenwasserüberdruckes vielfach zu niedrig. Nach den Hangstabilitätsanalysen bilden hier Erdbeben den wirksamsten Auslösemechanismus für die Rutschungen. Dies gilt auch für Rutschungen an den Kontinentalrändern von Nordwest- und Westafrika sowie für das europäische Nordmeer und für Rutschungen im nördlichen Fidji-Becken. Das Alter der besonders gut datierten Rutschungen vom nordwestafrikanischen Kontinentalrand und der Tiefsee des äquatorialen Ostatlantiks schwankt zwischen 16,000 J.v.h. und 18,000 J.v.h. sowie etwa 130,000 J.v.h.. Es handelt sich dabei um Phasen des Beginns besonders starker Meeresspiegelschwankungen. Ein Vergleich der Meeresspiegelkurve mit dem Alter älterer Rutschungen zeigt ebenfalls eine Parallele mit Zeiten von Regressionen und Transgressionen. Durch die Meeresspiegelschwankungen werden isostatische Vertikalbewegungen des Tiefseebodens von bis zu 30 m bewirkt, die Spannungen in den Lithosphärenplatten erzeugen. Sie allein sind jedoch nicht groß genug, um Brüche in intakten Plattenbereichen zu verursachen. Entlang alter, ehemals aktiver Transform-Bruchzonen (Fracture Zones) können jedoch die aufgebauten Spannungen eher wieder abgebaut werden. Dabei entstehen kleinere Erdstösse und führen zur Auslösung von Rutschungen. Ein Vergleich der Verbreitung von Transform-Störungen und Rutschungen vor Norwegen, Nordwest- und Westafrika sowie vor dem südlichen Afrika zeigt, daß in diesen Gebieten Rutschmassen tatsächlich besonders häufig entlang und in der Verlängerung von Fracture Zones auftreten. Modellrechnungen, die mit typischen Werten für Hangwinkel (0,5 Grad bis 3 Grad) von Tiefseeböschungen und passive Kontinentalränder sowie für häufig ermittelte Scherfestigkeitsgradienten im Sediment (0,5 kPa/m bis 1,7 kPa/m) durchgeführt wurden, ergaben, daß in Gebieten mit normal konsolidierten Sedimenten (ohne Porenwasserüberdruck) nur Erdbeben Rutschungen ausgelöst haben können.

Response of deep-sea benthic foraminifera to Late Quaternary climate changes, southeast Indian Ocean, offshore Western Australia

The Late Quaternary benthic foraminifera of four deep-sea cores off Western Australia (ODP 122-760A, ODP 122-762B, BMR96GC21 and RC9-150) have been examined for evidence of increased surface productivity to explain the anomalously low sea-surface paleotemperatures inferred by planktic foraminifera for the last and penultimate glaciations. The delta13C trends of Cibicidoides wuellerstorfi, and differences between the delta13C trends of planktics (Globigerinoides sacculifer) and benthics (C. wuellerstorfi) in the four cores indicate that during stage 6 bottom waters were significantly depleted in delta13C, and strong delta13C gradients were established in the water column, while during stage 2 and the Last Glacial Maximum, delta13C trends did not differ greatly from that of the Holocene. Two main assemblages of benthic foraminifera were identified by principal component analyses: one dominated by Uvigerina peregrina, another dominated by U. proboscidea. Abundance of these Uvigerinids, and of taxa preferring an infaunal microhabitat, and of Epistominella exigua and Bulimina aculeata indicate that episodes of high influx of particulate organic matter were established in most sites during glacial episodes, and particularly so during stage 6, while evidence for upwelling during the Last Glacial Maximum is less strong. The Penultimate Glaciation upwellings were established within the areas of low sea-surface paleotemperature indicated by planktic foraminifera. During the Last Interglacial Climax, upwelling appears to have been established in an isolated region offshore from a strengthened Leeuwin Current off North West Cape. Last Glacial Maximum delta13C values of C. wuellerstorfi at waterdepths of less than 2000 m show smaller than global mean glacial-interglacial changes suggesting the development of a deep hydrological front. A similar vertical stratification/bathyal front was also established during the Penultimate Glaciation.

Gotland Deep (Baltic Sea) independent age model based on Palaeomagnetic Secular Variation (PSV) and lead (Pb) deposition profiles

Dating of sediment cores from the Baltic Sea has proven to be difficult due to uncertainties surrounding the 14C reservoir age and a scarcity of macrofossils suitable for dating. Here we present the results of multiple dating methods carried out on cores in the Gotland Deep area of the Baltic Sea. Particular emphasis is placed on the Littorina stage (8 ka ago to the present) of the Baltic Sea and possible changes in the 14C reservoir age of our dated samples. Three geochronological methods are used. Firstly, palaeomagnetic secular variations (PSV) are reconstructed, whereby ages are transferred to PSV features through comparison with varved lake sediment based PSV records. Secondly, lead (Pb) content and stable isotope analysis are used to identify past peaks in anthropogenic atmospheric Pb pollution. Lastly, 14C determinations were carried out on benthic foraminifera (Elphidium spec.) samples from the brackish Littorina stage of the Baltic Sea. Determinations carried out on smaller samples (as low as 4 µg C) employed an experimental, state-of-the-art method involving the direct measurement of CO2 from samples by a gas ion source without the need for a graphitisation step - the first time this method has been performed on foraminifera in an applied study. The PSV chronology, based on the uppermost Littorina stage sediments, produced ten age constraints between 6.29 and 1.29 cal ka BP, and the Pb depositional analysis produced two age constraints associated with the Medieval pollution peak. Analysis of PSV data shows that adequate directional data can be derived from both the present Littorina saline phase muds and Baltic Ice Lake stage varved glacial sediments. Ferrimagnetic iron sulphides, most likely authigenic greigite (Fe3S4), present in the intermediate Ancylus Lake freshwater stage sediments acquire a gyroremanent magnetisation during static alternating field (AF) demagnetisation, preventing the identification of a primary natural remanent magnetisation for these sediments. An inferred marine reservoir age offset (deltaR) is calculated by comparing the foraminifera 14C determinations to a PSV & Pb age model. This deltaR is found to trend towards younger values upwards in the core, possibly due to a gradual change in hydrographic conditions brought about by a reduction in marine water exchange from the open sea due to continued isostatic rebound.

Geochemistry of continental slope and deep sea basin sediments off Uruguay

Pore water and solid phase from surface sediments of the continental slope off Uruguay and from the Argentine Basin (southwestern Atlantic) were investigated geochemically to ascribe characteristic early diagenetic reactions of iron and manganese. Solid-phase iron speciation was determined by extractions as well as by Mössbauer spectroscopy. Both methods showed good agreement (<6% deviation) for total-Fe speciation. The proportion of easy reducible iron oxyhydroxide relative to total-Fe oxides decreased from the continental slope to the deep sea which is attributed to an increase in crystallinity during transport as well as to a general decrease of iron mobilization. The product of iron reoxidation is Fe oxyhydroxide which made up less than 5% of total Fe. In addition to this fraction, a proportion of smectite bound iron was found to be redox reactive. This fraction made up to 10% of total Fe in sediments of the Argentine Basin and was quantitatively extracted by 1 N HCl. The redox reactive Fe(+II) fraction of smectite was almost completely reoxidized within 24 h under air atmosphere and may therefore considerably contribute to iron redox cycling if bioturbation occurs. In the case of the slope sediments we found concurrent iron and manganese release to pore water. It is not clear whether this is caused by dissimilatory iron and manganese reduction at the same depth or dissimilatory iron reduction alone inducing Mn(+IV) reduction by (abiotic) reaction with released Fe2+. The Argentine Basin sediment showed a significant manganese solid-phase enrichment above the denitrification depth despite the absence of a distinct pore-water gradient of Mn. This implies a recent termination of manganese mobilization and thus a non-steady-state situation with respect to sedimentation or to organic carbon burial rate.