Los cuentos: aspectos psicológicos y su influencia en la formación de la personalidad

El present treball pretén demostrar que els contes són vàlids i beneficiosos en el creixement integral de la persona i que, de forma més especial, contribueixen al exercici i adquisició de la virtut de la prudència. En aquest estudi es fa menció concreta de quins són aquests beneficis des del punt de vista psicològic; es mencionen també algunes tècniques d’aplicació pràctica dels contes en el camp de la psicologia, així com diferents corrents psicològiques que les apliquen i de quina manera. Objecte del present treball és també insistir en la influència beneficiosa del conte en el creixement personal i la formació del caràcter.

Aspectos ambientales implicados en la construcción de la identidad en una muestra de adolescentes de la Universidad Intercultural de Chiapas

The general aim of this paper is to explore and illustrate the role of the physical and psychological surrounding in narrative making ofthe personal identity. A qualitative study is put forward. It consists of a reduced version of the autobiographical multi-methodology(Bagnoli, 2004). That has been applied to a sample of six students of the Universidad Intercultural de Chiapas. The specific goals are: a) to illustrate, through citations obtained from interviews and graphical material, the theoretical concepts of attachment to theplace (Pol, 2002; Vidal y colaboradores, 2004) and community sense (Kim y Kaplan, 2004); and b) to detect the most relevantfactors of such concepts manifested in the students. Data was analyzed through the Atlas.ti computer program, version 5.0 (Muñoz, 2005). The findings suggest that sense of connection and participation in the community (action - transformation) has been observed as the most significant factors in our studied sample

Alguns aspectos históricos da classificação periódica dos elementos químicos

A history of the periodic table of the elements is presented, from the first tentative classifications, passing through Meyer and Mendeleev, up to recent speculations on super-heavy elements still to be synthesized. Many of the discussions and discoveries related to chemical elements and their proper periodic classification are also presented.

Alguns aspectos da política nacional de ciência e tecnologia

The Brazilian industrialisation process, which occurred from World War II up to the early eighties, was almost totally based on imported technology and has thus not demanded local S&T capability. National S&T expenditures were limited to 0.7 % of the GNP, covering mainly expenses with basic research and training of scientists and engineers. Federal Government was then responsible for 90% of the national S&T expenditures. The globalisation of the economy, associated with the reduction of tariff barriers, has, since the early nineties, exposed Brazilian industries to international competition and, thus, forced them to invest in research and development. S&T policy fosters research activities, provides research infrastructure and human resources training. The goal is to raise national expenditures to 1.5% of GDP by 1999, with a share of the private sector of about 40%. In 1996, national S&T expenditures have already attained 1.1% of the GDP and private sector investments in this area reached a share of 30%.

Uma metodologia para o projeto teórico de conversores moleculares de luz

Recentlly, we have proposed the representation of lanthanides within AM1 as sparkles for the purpose of obtaing ground state geometries of their complexes. We tested our quantum chemical sparkle model (SMLC/AM1) for the prediction of the crystallographic structure of complexes with coordination number nine, eight and seven. A technique is introduced for the theoretical prediction of eletronic spectra of the organic part of lanthanide complexes by replacing the metal ion by a point charge with the ligands held in their positions as determined by the SMLC/AM1, and by computing the theoretical spectra via the intermediate neglect of differential overlap/spectroscopic-configuration interaction (INDO/S-CI).

Aspectos mecanísticos da adição de Michael

The Michael addition reaction has been reported as a conventional nucleophilic process. However, more recently, alternative mechanisms involving electron transfer between acceptor and donnor species have been proposed.

O emprego de lipases como agentes de resolução cinética de enantiômeros em síntese orgânica: aspectos gerais sobre a influência do solvente

In organic synthesis, lipases are the most frequently used biocatalysts. They are efficient stereoselective catalysts in the kinetic resolution of a wide variety of chiral compounds. The discovery that enzymes possess catalytic activity in organic solvents has made it possible to address the question of reaction medium influence on enzymatic specificity. Perhaps the most exciting and significant development in this emerging area is the discovery that enzyme specificity, in particular enantioselectivity, can be affected by changing from one organic solvent to another. This article discusses the scope and possible mechanistic models of this phenomenon in hydrolases, specially lipases, as well as directions of future research in the area.

Alguns aspectos de imunoensaios aplicados à química analítica

In the last years, the use of antibody-antigen interactions, has earned attention not only for clinical analysis, but also for food industry and environmental control. Since the scope and diversity of immunoassay technology have shown a wide development. Continuous advances in order to analyse complex matrices, to improve reliability, simplicity (nonseparation) and to get multiple simultaneous assays, and extreme sensitivity (lower than zeptomole detection limits) are increasing. Many strategies have been investigated including chemiluminescent enzyme immunoassays, DNA as label and development of flow injection and immunosensors techniques. This subject became very usefull and important in nowadays that are taught in the undergraduate courses of chemistry in the european universities. However in our country are still ignored in the chemistry course.

Construção de modelos para ilustração de estruturas moleculares em aulas de química

This paper describes the construction of a kit of molecular model for illustration of molecular structure in chemical class using cheap materials. The atoms were represented by plastic spheres and the bonds between the atoms were made from plastic straws which were cut in the required length using a scale of 1.6 cm corresponding to 100 pm. Examples of adaptations made in this kit for didactical application are given.

O ensino de aspectos históricos e filosóficos da Química e as teorias ácido-base do século XX

In this paper, an overview about philosophy of science, the concept of "theory" and some characteristics of a"good"theory (1- ordination and explanation of the facts, 2- proposal of problems, and 3- simplicity and funcionality) are initialy introduced. Following, some historical landmarks of acidity and basicity and a summary of the main acid-base theories of the XX century (Arrhenius, solvent systems, protonic, electronic, Lux, Usanovich and ionotropic) are presented. Historical and conceptual relations between these theories are discussed and the three characteristics of a "good" theory are applied. The results showed that the protonic and eletronic theories are the "best". Some discussion of the implications to chemical education are presented too.

Economia de átomos, engenharia molecular e catálise organometálica bifásica: conceitos moleculares para tecnologias limpas

For economical and ecological reasons, synthetic chemists are confronted with the increasing obligation of optimizing their synthetic methods. Maximizing efficiency and minimizing costs in the production of molecules and macromolecules constitutes, therefore, one of the most exciting challenges of synthetic chemistry. The ideal synthesis should produce the desired product in 100% yield and selectivity, in a safe and environmentally acceptable process. In this highlight the concepts of atom economy, molecular engineering and biphasic organometallic catalysis, which address these issues at the molecular level for the generation of "green" technologies, are introduced and discussed.

Estudo da adsorção de hidrogênio e sulfeto na superfície de paládio: aspectos experimentais (eletroquímica) e teóricos (ab initio e Teoria do Funcional da Densidade)

The adsorption of H and S2- species on Pd (100) has been studied with ab initio, density-functional calculations and electrochemical methods. A cluster of five Pd atoms with a frozen geometry described the surface. The computational calculations were performed through the GAUSSIAN94 program, and the basis functions adapted to a pseudo-potential obtained by using the Generator Coordinate Method adapted to the this program. Using the cyclic voltammetry technique through a Model 283 Potentiostat/Galvanostat E.G.&G-PAR obtained the electrochemical results. The calculated chemisorption geometry has a Pd-H distance of 1.55Å, and the potential energy surface was calculated using the Becke3P86//(GCM/DFT/SBK) methodology. The adsorption of S2- ions on Pd surface obtained both through comparison between the experimental and theoretical results, at MP2 level, suggest a S2- absorption into the metallic cluster. The produced Pd-(S2-) system was show to be very stable under the employed experimental conditions. The paper has shows the powerful aid of computational methods to interpret adsorption experimental data.

Consideraciones sobre la fundamentación psicopedagógica del ABP : aspectos esenciales

La metodología ABP respeta la tendencia innata al crecimiento y la autorrealización defendida desde la psicología humanista, y permite crear el contexto de desarrollo idóneo para satisfacer las necesidades psicológicas básicas propuestas desde la teoría de la autodeterminación. Por su contribución al desarrollo de las competencias personales y sociales, está indicada tanto para universitarios como para alumnado de niveles preuniversitarios

Aspectos práticos relacionados ao uso do Rincoforol, o feromônio de agregação da Broca-do-olho-do-coqueiro Rhynchophorus palmarum L. (Coleopterate: Curculionidae) no controle de pragas do coqueiro: análise de sua eficiência em campo

Rhynchophorol (6-Methyl-2-hepten-4-ol) is the major constituent of the aggregation pheromone of Rhynchophorus palmarum L. (Coleoptera: Curculionidae), which is released by males of this species. The racemic mixture has been produced in one step-simplified preparation. The pheromone is placed into ampoules and furnished to coconut farmers. In the field, traps baited with Rhynchophorol and pieces of sugarcane attract both males and females, reducing the population of R. palmarum. The best conditions for field application are showed.

Aspectos relacionados à utilização da equação logística quadrática em processos eletroquímicos

The concepts of dissipation and feedback are contained in the behavior of many natural dynamical systems. They have been used to predict the evolution of populations leading to the formulation of the quadratic logistic equation (QLE). More recently, the QLE has been used to provide a better understanding of physicochemical systems with promising results. Many physical, chemical and biological dynamic phenomena can be understood on the basis of the QLE and this work describes the main aspects of this equation and some recent applications, with emphasis on electrochemical systems. Also, it is illustrated the concept of potential energy as a convenient way of describing the stability of the fixed points of the QLE.