Investigaciones en Teotihuacan: redefiniendo los viejos problemas

Teotihuacan se encuentra en el sector noroeste de la Cuenca de México (19' 34'N, 99VO'W) entre los 2.240 y 3.100 mt s.n.m. Es una de las culturas de la Antigüedad más asombrosas; no tan sólo por el tamaño de sus pirámides y estructura habitacionales sino porque supone el desarrollo de un fenómeno urbano extremadamente complejo que marcará el desarrollo del periodo Clásico en el Altiplano mexicano a lo largo de setecientos años de historia humana. La arqueología teotihuacana es engañosamente poco complicada. Teotihuacan se encuentra en un área accesible y por varias razones en las que se mezclan aspectos culturales, económicos (es una de las zonas arqueológicas más visitadas del mundo) y también políticos ha gozado de proyectos de investigación más o menos continuados desde hace un siglo. Para el investigador foráneo, el primer impacto se deriva del tamaño y volumen de las estructuras y de la cantidad de material arqueológico que puede derivarse de cualquier excavación en esta zona. A nivel de trabajo de campo, y en comparación con otras culturas de la Antigüedad los teotihuacanos tenían una arquitectura muy bien definida con una traza urbana bien reticulada

SSPBE: um programa para solução numérica da equação de Poisson-Boltzmann em simetria esférica com modelo de adsorção

A Fortran77 program, SSPBE, designed to solve the spherically symmetric Poisson-Boltzmann equation using cell model for ionic macromolecular aggregates or macroions is presented. The program includes an adsorption model for ions at the aggregate surface. The working algorithm solves the Poisson-Boltzmann equation in the integral representation using the Picard iteration method. Input parameters are introduced via an ASCII file, sspbe.txt. Output files yield the radial distances versus mean field potentials and average molar ion concentrations, the molar concentration of ions at the cell boundary, the self-consistent degree of ion adsorption from the surface and other related data. Ion binding to ionic, zwitterionic and reverse micelles are presented as representative examples of the applications of the SSPBE program.

O ensino por problemas e trabalho experimental dos estudantes: reflexões teórico-metodológicas

This work focuses its attention in teaching through problems, as a methodological strategy in the system of chemistry learning situations. The philosophical and epistemological basis of our perspective are the works that were developed by M. Majmutov and M.M. Llantada, in the field of sciences didactics and in the social-historical context of the school, where the fundamental categories that structure teaching through problems are discussed: the problem, the problematic tasks and problematic, as main orientations in the process of construction of the knowledge by the students.

Modelo de calibração da concentração de metilmetacrilato em solução aquosa utilizando espectroscopia de absorção no ultravioleta

Dilutions of methylmetacrylate ranging between 1 and 50 ppm were obtained from a stock solution of 1 ml of monomer in 100 ml of deionised water, and were analyzed by an absorption spectrophotometer in the UV-visible. Absorbance values were used to develop a calibration model based on the PLS, with the aim to determine new sample concentrations. The number of latent variables used was 6, with the standard errors of calibration and prediction found to be 0,048 ml/100 ml and 0,058 ml/100 ml. The calibration model was successfully used to calculate the concentration of monomer released in water, where complete dentures were kept for one hour after polymerization.

Influência do agente precipitante na preparação do óxido de nióbio (V) hidratado pelo método da precipitação em solução homogênea

This work reports the preparation, characterization and study of the ion exchange behavior of hydrous niobium oxide prepared by a homogeneous precipitation method. The precipitating agent was obtained in aqueous solution by thermal decomposition of urea or ammonium carbonate. The compounds were chemically and physically characterized by X-ray diffractometry, thermal analysis (TG/DTG), surface area measurements and ion exchange behavior with sodium. The materials prepared with ammonium carbonate presented a higher degree of crystallinity and better ion exchange capacity with sodium than materials prepared with urea. In the homogeneous precipitation method, materials were obtained with specific surface area of 123 - 224 m² g-1. A variation of the preparation process produced hydrous niobium oxide with a different degree of hydration and specific surface area. This provided materials with different physico-chemical properties.

Adsorção de íons dicromato nos compósitos celulose/ZrO2.nH2O preparados pelos métodos da precipitação convencional e em solução homogênea

This article describes the preparation and characterization of the cellulose/ hydrated zirconium oxide composites prepared by conventional precipitation (PC) and homogeneous solution precipitation (PSH) methods. The composite obtained by the PC method was prepared by using an ammonia solution as the precipitating agent, while the composite obtained by the PSH method was prepared by using urea as the precipitating agent. The adsorption of dichromate ions on the composites was studied using factorial design 2³. The variables were: initial concentration, agitation time and mass of the composite. The data obtained agree better for the composite obtained by the PC method.

Polímeros biodegradáveis - uma solução parcial para diminuir a quantidade dos resíduos plásticos

The large use of plastics has generated a waste deposit problem. Today plastic wastes represent 20% in volume of the total waste in the municipal landfills. To solve the disposal problem of plastics methods have been employed such as incineration, recycling, landfill disposal, biodegradation and the use of biodegradable polymers. Incineration of plastic wastes provokes pollution due to the production of poisonous gases. Recycling is important to reduce final costs of plastic materials, but is not enough in face of the amount of discarded plastic. In landfills plastic wastes remain undegraded for a long time, causing space and pollution problems. Biodegradation is a feasible method to treat some plastics, but intensive research is necessary to find conditions for the action of microorganisms. All of these methods are important and the practical application of each one depends on the type and amount of the plastic wastes and the environmental conditions. Therefore, a great deal of research has focused on developing biodegradable plastics and its application because it is an important way for minimizing the effect of the large volume of plastic waste discarded in the world.

Indústria química: evolução recente, problemas e oportunidades

Chemical industry underwent a significant upturn in the past few years. In Brazil, the position of this industry has been continuously strengthened as the second largest industrial sector. Current circumstances are discussed, especially the need for increased innovation, the impacts of nanotechnology, biotechnology and information technologies. Some misconceptions on the Brazilian chemical industry are criticized and recent improvements are described, including those related to environmental protection, to conclude that its prospects are very good, considering both the availability of basic raw materials (oil, natural gas, agribusiness products and minerals), the growing demand and increased competitiveness.

Determinação teórica das conformações mais estáveis da trealose em solução aquosa

In this work the most abundant trehalose conformers for the isolated molecule as well as for the water solvated system are selected. The theoretical tecniques employed are ab initio calculations in the gas phase and in aqueous solution using the PCM model. A conformational map is built for the glycosidic angles (phi and psi) and the search for the most abundant structures is explained. The final structures are validated by the agreement found between experimental and theoretical values for ³J H,C along the glycosidic linkage.

Uma abordagem simplificada do método Monte Carlo Quântico: da solução de integrais ao problema da distribuição eletrônica

The paper presents an introductory and general discussion on the quantum Monte Carlo methods, some fundamental algorithms, concepts and applicability. In order to introduce the quantum Monte Carlo method, preliminary concepts associated with Monte Carlo techniques are discussed.

Proceso de transformación de las concepciones del profesorado sobre la resolución de problemas matemáticos

The aim of this study is to analyze the transformation of Primary School teachers’ conceptions about mathematical problem solving. We performed a study with 18 teachers from three public schools: in each class (from 1º to 6º) there were two interventions, and we were interviewed teachers before and after them. The results have show identified changes in: 1) teacher’s expectations about students’ abilities; classroom management; perception of diversity; mathematical strategies used by students; communication in the classroom; causes of the problems encountered; and relevance process of problem solving in mathematics teaching. The transformation of teachers’ conceptions is due to the following factors: a) awareness of the practice; b) systematic reflection; c) the contrast between different ways to work solving problems in math class

Políticas de acción comunitaria en las periferias urbanas : Problemas de transferibilidad

Las grandes ciudades europeas están experimentando en las últimas décadas importantes transformaciones. Una de ellas ha sido el aumento de la vulnerabilidad social y el debilitamiento de los lazos comunitarios concentrados en algunos barrios periféricos. La acción comunitaria se presenta como una metodología para reconstruir los lazos comunitarios y propiciar la coordinación entre los actores sociales que operan en los barrios, con el objetivo de mejorar las condiciones de vida de sus habitantes. Para conseguir ambos objetivos es indispensable la colaboración entre los agentes sociales y la movilización ciudadana. Las periferias de las grandes ciudades son lugares proclives a la emergencia de este tipo de metodologías, pero al mismo tiempo pueden ser contextos que presenten dificultades para la movilización ciudadana. Algunas explicaciones de esta dificultad son los procesos de fragmentación social y los procesos de invasión-sucesión que obstaculizan la organización social. Entre los temas de debate en torno a la acción comunitaria, destaca las relaciones entre los actores sociales implicados en los procesos de reconstrucción de la comunidad. El desequilibrio en la distribución de las responsabilidades y los papeles lleva a situaciones como la profesionalización del proceso, la desvinculación de la comunidad y la coerción institucional. En este artículo argumentamos que existe una paradoja entre los objetivos de la acción comunitaria y algunos procesos que contribuyen a la fragmentación de la comunidad. Esta paradoja puede explicarse por el excesivo liderazgo técnico e institucional y por una definición de la cohesión social que no considera el conflicto social.

Especiação redox de cromo em solo acidentalmente contaminado com solução sulfocrômica

Determination of Cr(VI) and Cr(III) was studied in soil samples accidentally contaminated with sulphochromic solution. Molecular absorption spectrophotometry based on the diphenylcarbazide method was used for the determination of Cr(VI) after its alkaline extraction. The total chromium concentration was determined using ICP OES. The quantification of Cr(III) was accomplished by subtracting the Cr(VI) concentration from the total chromium concentration. Regardless of the known contamination of the soil samples by sulphochromic solution, concentrations of Cr(VI) were below the detection limit. Addition and recovery experiments for Cr(VI) in soil samples with and without organic matter indicated its influence on the reduction of Cr(VI) to Cr(III).

La promoción del pensamiento crítico en el Aprendizaje Basado en Problemas (ABP). Un análisis a partir de los instrumentos de medición

[spa] La literatura científica sobre el Aprendizaje Basado en Problemas (ABP) ha dedicado una atención creciente a la cuestión del pensamiento crítico a lo largo de las dos últimas décadas. Los trabajos de investigación que se han llevado a cabo en los distintos contextos disciplinares de la educación superior presentan definiciones e instrumentos de medición del pensamiento crítico dispares. El presente artículo parte de dicha apreciación y trata de revisar sistemáticamente los mencionados trabajos con un doble objetivo: por un lado, esbozar una clasificación de los instrumentos de medición del pensamiento crítico de estudiantes de ABP y, por el otro, mostrar una panorámica de las evidencias hasta ahora obtenidas; todo ello con la finalidad de animar a profesores, estudiosos y autoridades académicas a seguir avanzando en esta línea de investigación. [eng] Critical thinking has received growing attention from scientific literature on Problem-Based Learning (PBL)during the last two decades. The research carried out in different disciplinary contexts of higher education presents disparate definitions and measuring instruments of critical thinking. This article aims to review systematically the mentioned literature with a dual purpose: on the one hand, to outline a classification of instruments measuring PBL students' critical thinking, on the other, to show an overview of the evidence so far obtained; all of this with the ultimate purpose of encouraging teachers, scholars and academical authorities to proceed further in this line of research.

¿Para qué sirven los problemas en la clase de matemáticas? = What is the use of problems in Mathematics lessons?

The results obtained in several yield tests, at an international level (mainly the famous PISA 2003 report, by the OCDE), have raised a multiplicity of performances in order to improve the students' yield regarding problem solving. In this article we set a clear guideline on how problems should be used in Mathematics lessons, not for obtaining better scores in the yield tests but for improving the development of Mathematical thinking in students. From this perspective, the author analyses, through eight reflections, how the concept of problem, transmitted both in the school and from society, influences the students