Alteration and vein logs of ODP Holes 152-917A and 152-918D

This data report provides a systematic documentation of the low-temperature alteration associated with the formation of a volcanic-rifted margin by the quantification of alteration effects and vein mineralogy and distributions in basalts recovered on Leg 152 (Larsen, Saunders, Clift, et al., 1994, doi:10.2973/odp.proc.ir.152.1994). Basaltic rocks from Holes 917A and 918D have been investigated to provide a quantitative description of the extents of recrystallization and secondary mineral abundance resulting from low-temperature alteration and weathering. Only limited descriptions of alteration and secondary mineral distributions were undertaken on board ship during Leg 152, and the data presented here provide an essential complement to the shipboard logs of the limited amount of basalt recovered during Leg 163 from Sites 988, 989, and 990 (Duncan, Larsen, Allan, et al., 1996, doi:10.2973/odp.proc.ir.163.1996).

Chemical composition and fluxes of deep sea suspended matter within and over the 9°50'N hydrothermal field, EPR

Results of geochemical studies of suspended matter from the water mass over the hydrothermal field at 9°50'N on the East Pacific Rise are reported. The suspended matter was sampled in background waters, in the buoyant plume, and in the near-bottom waters. Contents of Si, Al, P, Corg, Fe, Mn, Cu, Zn, Ni, Co, As, Cr, Cd, Pb, Ag, and Hg were determined. No definite correlations were found between the elements in the background waters. Many of the chemical elements correlated with Fe and associated with its oxyhydroxides in the buoyant plume. In the near-bottom waters trace elements are associated with Fe, Zn, and Cu (probably, with their sulfides formed during mixing of hydrothermal fluids with seawater). Chemical composition of sediment matter precipitated in a sediment trap was similar to the near-bottom suspended matter.

Methane, helium isotope and hydrogen data from the Nibelungen hydrothermal area, Mid Atlantic Ridge

Hydrothermal emission of mantle helium appears to be directly related to magma production rate, but other processes can generate methane and hydrogen on mid-ocean ridges. In an on-going effort to characterize these processes in the South Atlantic, the flux and distribution of these gases were investigated in the vicinity of a powerful black smoker recently discovered at 8°17.9' S, 13°30.4' W. The vent lies on the shoulder of an oblique offset in the Mid-Atlantic Ridge and discharges high concentrations of methane and hydrogen. Measurements during expeditions in 2004 and 2006 show that the ratio of CH4 to 3He in the neutrally buoyant plume is quite high, 4 x 10**8. The CTD stations were accompanied by velocity measurements with lowered acoustic Doppler current profilers (LADCP), and from these data we estimate the methane transport to have been 0.5 mol/sec in a WSW-trending plume that seems to develop during the ebb tidal phase. This transport is an order of magnitude greater than the source of CH4 calculated from its concentration in the vent fluid and the rise height of the plume. From this range of methane fluxes, the source of 3He is estimated to be between 0.14 and 1.2 nmol/sec. In either case, the 3He source is significantly lower than expected from the spreading rate of the Mid-Atlantic Ridge. From the inventory of methane in the rift valley adjacent to the vent, it appears that the average specific rate of oxidation is 2.6 to 23/yr, corresponding to a turnover time between 140 and 16 days. Vertical profiles of methane in the surrounding region often exhibited Gaussian-like distributions, and the variances appear to increase with distance from the vent. Using a Gaussian plume model, we obtained a range of vertical eddy diffusivities between 0.009 and 0.08 m2m2/sec. These high values may be due to tidally driven internal waves across the promontory on which the vent is located.

Physical oceanography during METEOR cruise M60/3 at the Logatchev hydrothermal field in the mid-Atlantic

The R/V METEOR cruise M60/3 took place from January 13 through February 14, 2004. Target area was the Logatchev hydrothermal field situated on the Mid-Atlantic Ridge (MAR) with main spots around 14°45'N and 44°59'W and 14°55'N and 44°55'W. The active Logatchev hydrothermal field lies on a small plateau on the eastern flank of the inner rift valley in 2900 m to 3060 m water depth. It is characterized by sites of active, high-T fluid emanation and sulfide precipitation as well as by inactive sites. CTD data for 17 stations located in the vicinity of the Logatchev hydrothermal field were recorded using a SEABIRD CTD Type 911, mostly for the entire water column. CTD sensors had been calibrated by SEABIRD directly before the cruise; additional calibrations of the data obtained, e.g. by salinometer measurements of selected samples were not accomplished. For most stations, no indication of hydrothermal plumes could be identified within the CTD-profiles. An exception is station M60/3-37-CTD-R for which the S/T plot evidences the intrusion of a component relatively depleted in salinity for the depth area from 2600m to 2700m water depth.

(Table 1) Platinum group element abundanves in ODP Leg 135 samples

Ocean Drilling Program Leg 135 backarc basin lavas are characterized by anomalously high Au contents (1.0-11.4 ppb) and strongly fractionated relative platinum group element (PGE) abundances (Pd/Ir ratio, approximately 100). The Rh and Ir contents are very low, ranging from below detection (approximately 0.02 ppb) to 0.08 ppb. The Pd and Pt contents range from <0.3 to 4 ppb. Rh, Pd, and Pt values are consistently and significantly higher in Site 836 and 839 samples relative to those from Sites 834 and 835. Major, trace, and rare earth element (REE) data suggest Sites 836 and 839 have a more pronounced arc signature than Sites 834 and 835. No correlation exists between noble metal abundance and indices of alteration or fractionation (e.g., loss on ignition (LOI), Mg#, and Cr or Ni contents), suggesting that measured values and ratios are primary and reflect characteristics of the mantle source. The evaluation of Leg 135 noble metal data with respect to potential mantle-source components is hindered by the lack of data on magmas derived from such sources. However, analyses of the limited available data for the different magma types suggest that the characteristic enrichment of Leg 135 lavas in Au, relative to Pd and Cu, cannot be derived solely from simple MORB-type or ocean-island-type mantle, or mantle depleted by a previous melt extraction event. The Au-enriched signature of the Lau basin lavas could, however, be produced through the addition of a sedimentary component from the downgoing slab. Separation of Au from the PGE occurs within oceanic hydrothermal systems and gold values of the resultant precipitates are 2-3 orders of magnitude higher than other oceanic crustal components. Even small additions of this component from the downgoing oceanic crust to a supra-subduction zone mantle melt could account for the high mean Au/Pd ratios of the Leg 135 samples (Sites 834 and 835, Au/Pd = 5.04; Sites 836 and 839, Au/Pd = 2.26).

Trace metals in shells of mussels and clams from deep-sea hydrothermal vent fields of the Mid-Atlantic Ridge and East Pacific Rise

Bioaccumulation of trace metals in carbonate shells of mussels and clams was investigated at seven hydrothermal vent fields of the Mid-Atlantic Ridge (Menez Gwen, Snake Pit, Rainbow, and Broken Spur) and the Eastern Pacific (9°N and 21°N at the East Pacific Rise and the southern trough of Guaymas Basin, Gulf of California). Mineralogical analysis showed that carbonate skeletons of mytilid mussel Bathymodiolus sp. and vesicomyid clam Calyptogena m. are composed mainly of calcite and aragonite, respectively. The first data were obtained for contents of a variety of chemical elements in bivalve carbonate shells from various hydrothermal vent sites. Analyses of chemical compositions (including Fe, Mn, Zn, Cu, Cd, Pb, Ag, Ni, Cr, Co, As, Se, Sb, and Hg) of 35 shell samples and 14 water samples from mollusk biotopes revealed influences of environmental conditions and some biological parameters on bioaccumulation of metals. Bivalve shells from hydrothermal fields with black smokers are enriched in Fe and Mn by factor of 20-30 relative to the same species from the Menez Gwen low-temperature vent site. It was shown that essential elements (Fe, Mn, Ni, and Cu) more actively accumulated during early ontogeny of the shells. High enrichment factors of most metals (n x 100 - n x 10000) indicate efficient accumulation function of bivalve carbonate shells. Passive metal accumulation owing to adsorption on shell surfaces was estimated to be no higher than 50% of total amount and varied from 14% for Fe to 46% for Mn.