Nuclear magnetic resonance studies of boron trihalide complexes of 1,1-BIS (dimethylamino) ethylene and related bases

Boron tribalide complexes of 1,1-bis(dimethylamino)ethylene (DME) , t etramethylurea (TMU), tetramethylguanidine (TMG) , and pentamethylguanidine (PMG) and also mixed boron t r ihalide adducts of DME have been investigated by 1H and 19F NMR spectroscopy. Both nitrogen and the C-Q-H carbon of DME are possible donor a toms to boron trihal ides but complexation has been found to occur only at carbon of DME. The initial adduct acts as a Bronsted acid and gives up a proton to free DME in solut ion. A side reaction in the DME-BF, system gives rise to trace amounts of a complex aSSigned as (DME)2BF2+. (DME)2BF2+ is produced in much larger quantities in t he DME-BF3-BC13 and DME-BF,-BBr, systems by reaction of free DME with DME:BF2X (X = Cl, Br). Restricted r otation about the C-N bonds of TMUlBC13 and n1U:BBr3 has been observed at low temperatures. This complements previous work in this system and confirms oxygen donation of TMU to boron trihalides . Restricted rotation at low temperatures also has been observed in DMEboron trihalide systems

Structural analysis of interior layered deposits in north and south Coprates Chasma, Mars

Interior layered deposits within an embayment in the northern as well as near the southern wall of Coprates Chasma in the Valles Marineris, Mars are studied using HRSC, CTX, HiRISE and CRISM data. In the northern embayment, layered deposits outcrop in three separate locations (a western deposit, a central deposit and an eastern deposit). The central layered deposit in the north has a stratigraphic thickness of 2 km. The western layered deposit abuts against the chasma wall appearing to have a relatively un-eroded depositional surface. The eastern deposit is near a landslide scar which appears to have exposed basement layering showing downward displacement. This northern embayment is suggested to have been an ancestral basin. The triangular edged deposit near the southern wall of Coprates Chasma has an elongated mound protruding from the central edge and is suggested to be the outer limits of a fault block which is back rotated 6° south. The rotation may be the result of the Valles Marineris opening.

Rotational analysis of the 5 1 0 6 1 0 band of formyl chloride

Please consult the paper edition of this thesis to read. It is available on the 5th Floor of the Library at Call Number: Z 9999 C54 L434 1989

HG 186.15-186.25 Thin Section

Coarse grained sample with multiple fine grained domains. Clasts range from small to medium and sub-angular to sub-rounded. Mainly contains grain crushing (with grains crushed into one another) and short distance lineations. A few rotation structures are seen and fine grained sand domains can also be seen.

HG 186.80-186.85 Thin section

A coarse grained sample with clay rich domains. Grains range from small to medium and are sub-angular. Rotation structures can be seen around sub-rounded clasts. Lineations can be seen throughout the image, mainly short distance lineations. Small comet structures can also be seen throughout the images.

HG 186.9-187.0 D.E.

Coarse grained sediment with a few fine grained matrices. Brown sediment with small to medium sized clasts. Clasts range from sub-angular to sub-rounded. Organic material present. It contains rotation structures throughout as well as edge-to-edge grain crushing. Fine grained clay domains are present and lineations can also be seen. Minor amounts of grain stacking can also be seen.

HG 195.45-195.55 Thin Section

Dark brown sediment with clasts ranging from small to large. The grains are sub-angular. Two main domains can be seen. Both are coarse grained, but one contains larger grains and potentially more clay material. Lineations are present throughout the sample in multiple directions. Minor rotation around a few larger clasts can be seen, as well as comet structures.

HG 216.35-216.45

Brown, coarse grained sample. Clasts range from small to medium in size and sub-angular to angular. Patched of clay rich domains can be seen throughout the sample. Rotation with and without a central grain can be seen throughout the sample. Edge-to-edge grain crushing and grain stacking can be seen throughout the sample.

HG 222.70-222.80 Thin Section

Coarse brown sediment with clasts ranging from small to medium. Clasts are sub-angular to sub-rounded. Rotation structures can be seen throughout the image. Multiple rotations can be seen around single clasts. Minor amounts of comet structures and grain stacking can also be seen.

HG 225.15-225.25 Thin Section

Dark brown sediment with sub-angular to sub-rounded grains, that range from small to medium in size. Lineations with fractured grains are abundant, and grain crushing can also be seen. Minor rotation can also be seen.

HG 230.75-230.85 Thin Section

Coarse grained sediment with fine grained domains, clay material, rotation structures and lineations. Clasts range from sub-angular to sub-rounded. Mainly brown sediment with darker patches of brown throughout. Major amounts of grain crushing can be seen in the coarse grained material.

HG 238.80-238.90 Thin Section

Dark brown sediment with clasts ranging from small to medium in size and sub-angular to angular. Contains lineations and grain stacking throughout the sample. Rotation and comet structures can also be seen. Rotation structures can be seen around mainly the sub-angular clasts. Patches of clay can also be seen throughout the sample.

HG 240.0-240.10 Thin Section

Dark brown sediment with sub-angular to rounded clasts. Contained areas of darker clay material. Contains rotation structures, mainly around rounded clasts. One side of the sample had significantly larger clasts than the other. Two different domains can be seen in this sample; a fine grained domain and a coarse grained domain.

HG 244.40-244.50-A Thin Section

Dark brown sediment with sub-angular to sub-rounded clasts. Rotation structures and lineations are common. Clasts ranging from small to large in size. Many large grains are fractured. Minor amounts of grain stacking and crushing can be seen. A few clay and organic rich domains can be seen.

HG 244.40-244.55-B Thin Section

Coarse grained sample with sub-angular to sub-rounded clasts ranging from small-large in size. Rotation structures, grain crushing and lineations were seen throughout the sample.