Rotational analysis of the 5 1 0 6 1 0 band of formyl chloride
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Department of Chemistry |
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| Data(s) |
02/01/2013
02/01/2013
02/01/2013
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| Resumo |
Please consult the paper edition of this thesis to read. It is available on the 5th Floor of the Library at Call Number: Z 9999 C54 L434 1989 The 5161 band of formyl chloride under the conditions of high resolution was analyzed. Prominent band heads were observed in the Pp sub-bands. Comparison with the computed spectrum indicates that it is principally a perpendicular band. A parallel band is also observed due to Herzberg-Teller interaction but at much lower intensity. The molecule is nonplanar in the first excited electronic state with a hydrogen out-of-plane displacement of 35 degrees and the OCCI bond angle reduced by 15 degrees. |
| Identificador | |
| Direitos |
Copyright ownership of this works resides with the Author. No electronic full-text of this work is available. |
| Palavras-Chave | #Formyl chloride #Chlorides #Molecular rotation |
