降雨条件下碎石土滑坡稳定性研究

Debris Landslide is one of the types of landslides with the widest distribution, largest quantity, and the closest relationship with engineering construction. It is also one of the most important types of landslides that can cause disaster. This kind of landslide often occurs in the loose slopes which are made up of loose congeries formed by earth filling, residual soil, slope wash, dilapidation, landslide or full weathered material of hard rock. Rainfall is always the chief inducing factor of debris Landslide. Therefore, to research stability of debris Landslide during rainfall not only has important theoretical significance for understanding developing law and deformation and failure mechanism of debris landslide, but also has important practical significance for investigating, appraising, forecasting, preventing and controlling debris landslides. This thesis systematically summarized the relationships between rainfall and landslide, the method to survey water table in the landslides, the deformation and failure mechanism of debris landslide, and the progress in the stability analysis of landslides based on the analyses of data collected widely at home and abroad. The problems in the study of the stability of debris landslide during rainfall was reviewed and discussed. Due to the complicated geological conditions and the random rainfall conditions, the research on the landslides' stability must be based on engineering geological qualitative analysis. Through the collection of the data about the Panxi region and the Three Gorges Reservoir region, the author systematically summarized the engineering geological conditions, hydro-geological condition, distribution characteristics of stress field in the slope, physical and mechanical properties and hydro-mechanical properties of debris. In the viewpoint of dynamics of soil water and hydromechanics, physical process of rainfall to supply groundwater of debris landslides can be divided into two phases, i.e. non-saturated steady infiltrating phase and saturated unsteady supplying phase. The former can be described by mathematical model of surface water infiltration while the latter can be described by equivalent continuous medium model of groundwater seepage. With regard to specific hydrological geology system, we can obtain the dynamic variation law of water content, water table, landslide stability of rock and soil mass, along with quantity and duration of rainfall after the boundary condition on hydrological geology has been ascertained. This is a new way to study the response law of groundwater in the landslides during rainfall. After wet face of rock and soil mass connects with ground water table, the raising of water table will occur due to the supply of rainfall. Then interaction between ground water and rock and soil mass will occur, such as the action of physics, water, chemistry and mechanics, which caused the decrease of shearing strength of sliding zone. According to the action of groundwater on rock and soil mass, a concise mechanical model of debris landslide’s deformation was established during rainfall. The static equilibrium condition of landslide mass system was achieved according to the concise mechanical model, and then the typical deformation and failure process and failure mode of debris landslide during rainfall were discussed. In this thesis, the former limiting equilibrium slice method was modified and improved based on shearing strength theory of , a stability analysis program of debris landslide was established and developed taking account of the saturated-unsaturated seepage, by introducing the shearing strength theory of unsaturated soil mass made by (1978). The program has reasonable data storage and simple interface and is easy to operate, and can be perfectly used to carry out sensitivity analysis of influencing factors of landslides' stability, integrated with the program of Office Excel. The design of drainage engineering are always bases on empirical methods and is short of effective quantitative analysis and appraise, therefore, the conception of critical water table of debris landslide was put forward. For debris landslides with different kinds of slide face in the engineering practice, a program to search the critical water table of debris landslide was developed based on native groundwater table. And groundwater table in the slope should be declined below the critical water table in the drainage works, so the program can be directly used to guide drainage works in the debris landslide. Taking the slope deformation body in the back of former factory building of Muli Shawan hydroelectric power station as an example, a systematic and detailed research on debris landslides' stability during rainfall was researched systematically, the relationship among quantity of rainfall, water table and stability of slope was established, the debris landslides' stability in process of rainfall from dynamic viewpoint was analyzed and researched.

非饱和膨胀土力学特性及其工程处置研究

The unsaturated expansive soil is a hotspot and difficulty in soil mechanics inland and outland. The expansive soil in our China is one of the widest in distributing and greatest in area, and the disaster of expansive soil happens continually as a result. The soil mechanics test, monitor, numerical simulation and engineering practice are used to research swell and shrinkage characteristic, edge strength characteristic and unsaturated strength characteristic of Mengzi expansive soil. The seep and stability of the slope for expansive soil associated with fissure are analyzed and two kinds of new technique are put forward to be used in expansive soil area, based on disaster mechnics proposed of the slope.The technique of reinforcement in road embankment is optimized also. Associated with engineering geology research of Mengzi expansive soil, mineral composition, chemical composition, specific area and cation content, dissolubility salt and agglutinate, microcosmic fabric characteristic, cause of formation and atmosphere effect depth are analyzed to explain the intrinsic cause and essence of swell and shrinkage for expansive soil. The rule between swell-shrinkage and initial state, namely initial water content, initial dry density and initial pressure, can be used to construction control. Does Response model is fit to simulate the rule, based on ternary regression analysis. It has great meaning to expansive soil engineering in area with salt or alkali. The mechanics under CD, CU and GCU of expansive soil is researched by edge surface theory to explain the remarkable effect of consolidation pressure, initial dry density, initial water content, cut velocity, drainage and reinforcement to the edge strength characteristic. The infirm hardening stress strain curves can be fitted with hyperbola model and the infirm softening curves can be fitted with exponential model. The normalization theory can be used to reveal the intrinsic unity of the otherness which is brought by different methods to the shear strength of the same kinds of samples. The unsaturated strain softening characteristic and strength envelope of remolding samples are researched by triaxial shear test based on suction controlled, the result of which is simulated by exponential function. The strength parameters of the unsaturated samples are obtained to be used in the unsaturated seep associated with rainfall. The elasticity and plasticity characters of expansive soil are researched to attain the model parameters by using modified G-A model. The humidification destroy characteristic of expansive soil is discussed to research the disaster mechanism of the slope with the back pressure increasing and suction decreasing under bias pressure consolidation. The indoor and outdoor SWCCs are measured to research the effect factors and the rule between different stress and filling environment. The moisture absorption curves can express the relationship between suction and water content in locale. The SWCCs of Mengzi expansive soil are measured by GDS stress path trixial system. The unsaturated infiltration function is gained to research seep and stability of the slope of expansive soil. The rainfall infiltration and ability of slope considering multifarious factors are studied by analyzing fissure cause of Mengzi expansive soil. The mechanism of the slope disaster is brought forward by the double controlling effect between suction and fissure. Two new kinds of technique are put forward to resolve disaster of expansive soil and the technique of reinforcement on embankment is optimized, which gives a useful help to solving engineering trouble.

晚中新世以来中国北方风成沉积的磁性地层学和沉积学研究

The past two decades have witnessed an unprecedented growth of interest in the palaeoenvironmental significance of the Pleistocene loess deposits in northern China. However, it is only several years ago that the Tertiary red clay sequence underlying Pleistocene loess attracted much attention. One of the major advances in recent studies of eolian deposits on the Loess Plateau is the verification of the eolian origin for the Tertiary red clay sediments. The evidence of the eolian origin for the red clay is mainly from geochemical and sedimentological studies. However, sedimentological studies of the red clay deposits are still few compared with those of the overlying loess sediments. To date, the red clay sections located near Xifeng, Baoji, Lantian, Jiaxian, and Lingtai have been studied, with an emphasis on magnetostratigraphy. These sections have a basal age ranging from ～4.3 Ma to ～7.0 Ma. The thickness of the sections varies significantly, depending perhaps on the development of local geomorphological conditions and the drainage system. Although the stratigraphy of the red clay sections has been recorded in some detail, correlation of the red clay sequences has not yet been undertaken. Geological records (Sun J. et al., 1998) have shown that during glacial periods of the Quaternary the deserts in northem China were greatly expanded compared with modern desert distribution. During interglacial periods, desert areas contracted and retreated mostly to northwestern China because of the increase in inland penetration of monsoonal precipitation. According to pedogenic characteristics of the red clay deposits, the climatic conditions of the Loess Plateau is warmer and wetter generally in the Neogene than in the late Pleistocene. Panicle analyses show that grain size distribution of the red clay sequence is similar to that of the paleosols in the Pleistocene loess record, thus implying a relatively remote provenance of the red clay materials. However, the quantitative or semiquantitative estimates of the distance from the source region to the Loess Plateau during the red clay development remains to be investigated. In this study, magnetostratigraphic and sedimentological studies are conducted at two thick red clay sequences-Jingchuan and Lingtai section. The objectives of these studies are focused on further sedimentological evidence for the eolian origin of the red clay, correlation of red clay sequences, provenance of the red clay, and the palaeoclimate reconstruction in the Neogene. Paleomagnetic studies show that the Jingchuan red clay has a basal age of 8.0 Ma, which is 1 million years older than the previously studied Lingtai section. The Lingtai red clay sequence was divided into five units on the basis of pedogenica characteristics (Ding et al., 1999a). The Jingchuan red clay sequence, however, can be lithologically divided into six units according to field observations. The upper five units of the Jingchuan red clay can generally correlate well with the five units of the Lingtai red clay. Comparison of magnetic susceptibility and color reflectance records of four red clay sections suggests that the Lingtai red clay sequence can be the type-section of the Neogene red clay deposits in northern China. Pleistocene loess and modem dust deposits have a unimodal grain-size distribution. The red clay sediments at Jingchuan and Lingtai also have a unimodal grain-size distribution especially similar to the paleosols in the Pleistocene loess record. Sedimentological studies of a north-south transect of loess deposits above S2 on the Loess Plateau show that loess deposits had distinct temporal and spatial sedimentary differentiation. The characteristics of such sedimentary differentiation can be well presented in a triangular diagram of normalized median grain size, normalized skewness, and normalized kurtosis. The triangular diagrams of the red clay-loess sequence at Lingtai and Jingchuan indicate that loess-paleosol-red clay may be transported and sorted by the same agent wind, thus extending the eolian record in the Loess Plateau from 2.6 Ma back to about 8.0 Ma. It has been recognized that during the last glacial maximum (LGM) the deserts in northern China had a distribution similar to the present, whereas during the Holocene Optimum the deserts retreated to the area west of the Helan Mountains. Advance-retreat cycles of the deserts will lead to changes in the distance of the Loess Plateau to the dust source regions, thereby controlling changes in grain size of the loess deposited in a specific site. To observe spatial changes in sedimentological characteristics of loess during the last glacial-interglacial cycle, the texture of loess was measured along the north-south transect of the Loess Plateau. Since the southern margin of the Mu Us desert during the LGM is already known, several models of grain size parameters versus the minimum distance from the source region to depositional areas were developed. According to these semiquantitative models, the minimum distance from the source region to Lingtai and Jingchuan areas is about 600 km during the Neogene. Therefore the estimated provenance of the Tertiary red clay deposits is the areas now occupied by the Badain Jaran desert and arid regions west of it. The ratio of the free iron to total iron concentration attests to being a good proxy indicator for the summer monsoon evolution. The Lingtai Fe_20_3 ratio record shows high values over three time intervals: 4.8-4.1 Ma, 3.4-2.6 Ma, and during the interglacial periods of the past 0.5 Ma. The increase in summer monsoon intensity over the three intervals also coincides with the well-developed soil characteristics. It is therefore concluded that the East-Asia summer monsoon has experienced a non-linear evolution since the late Miocene. In general, the East Asia summer monsoon was stronger in Neogene than in Quaternary and the strongest East Asia summer monsoon may occur between 4.1 and 4.8 Ma. The relatively small ice volume and high global temperature may be responsible for the strong summer monsoon during the early Pliocene.

工程地质三维建模与可视化技术应用开发

Synthetic Geology Information System (SGIS) is an important constituent part of the theory of Engineering Geomechanics Mate-Synthetic (EGMS), and is the information system more suited for the collection, storage, management, analysis and processing to the information coming from engineering geology,' geological engineering and geotechnical engineering. Its contents involve various works and methods of the investigation, design, and construction in different stages of the geological engineering. Engineering geological and three-dimensional modeling and visualization is the fundamental part of the SGIS, and is a theory, method and technique by which, adopting the computer graphics and image processing techniques, the data derived from engineering geological survey and the calculated results obtained from the geomechanical numerical simulation and analysis are converted to the graphics and images displayed on the computer screen and can be processed interactively. In this paper, the significance and realizing approaches of the three-dimensional modeling and visualization for the complex geological mass in the engineering geology are discussed and the methods of taking advantage of the interpolation and fitting for the scattered and field-surveyed data to simulate the geological layers, such as the topography and earth surface, the groundwater table and the stratum boundary, are researched into. At the mean time, in mind the characteristics of the structure of the basic data for three-dimensional modeling, its visual management can be resolved into the engineering surveyed database management module, plot parameter management module and data output module and the requirement for basic data management can be fulfilled. In the paper, the establishment and development of the three-dimensional geological information system are probed tentatively, and an instance of three-dimensional visual Engineering Distribution Information System (EDIS), theConstruction Management Information System for an airport, in which the functions, such as the real-time browse among the three-dimensional virtual-reality landscapes of the airport construction from start to finish, the information query to the airport facility and the building in the housing district and the recording and playback of the animation sets for the browse and the takeoff and landing of the planes, is developed by applying the component-mode three-dimensional virtual-reality geological information system (GIS) software development kits (SDK), so the three-dimensional visual management platform is provided for the airport construction. Moreover, in the gaper, integrated with the three-dimensional topography visualization and its application in the Sichuan-Tibet Highways, the method of the digital elevation model (DEM) data collection from the topographic maps is described, and the three-dimensional visualization and the roaming about the terrain along the highway are achieved through computer language programming. Understanding to the important role played by the varied and unique topographical condition in the gestation and germination of the highly-dense, frequently-arising and severely-endangered geological hazards can be deepened.

西江流域环境河水地球化学研究

River is a major component of the global surface water and CO2 cycles. The chemistry of river waters reveals the nature of weathering on a basin-wide scale and helps us understand the exogenic cycles of elements in the continent-river-ocean system. In particular, geochemical investigation of large river gives important information on the biogeochemical cycles of the elements, chemical weathering rates, physical erosion rates and CO2 consumption during the weathering of the rocks within the drainage basin. Its importance has led to a number of detailed geochemical studies on some of the world's large and medium-size river systems. Flowing in the south of China, the Xijiang River is the second largest river in the China with respect to its discharge, after the Yangtze River. Its headwaters drain the YunGui Plateau, where altitude is approximately 2000 meters. Geologically, the carbonate rocks are widely spread in the river drainage basin, which covers an area of about 0.17xl06 km2, i.e., 39% of the whole drainage basin. This study focuses on the chemistry of the Xijiang river system and constitutes the first geochemical investigation into major and trace elements concentrations for both suspended and dissolved loads of this river and its main tributaries, and Sr isotopic composition of the dissolved load is also investigated, in order to determine both chemical weathering and mechanical erosion rates. As compared with the other large rivers of the world, the Xijiang River is characterized by higher major element concentration. The dissolved major cations average 1.17, 0.33, 0.15, and 0.04 mmol I"1 for Ca, Mg, Na, and K, respectively. The total cation concentrations (TZ+) in these rivers vary between 2.2 and 4.4 meq I'1. The high concentration of Ca and Mg, high (Ca+Mg)/(Na+K) ratio (7.9), enormous alkalinity and low dissolved SiO2/HCO3 ratio (0.05) in river waters reveal the importance of carbonate weathering and relatively weak silicate weathering over the river drainage basin. The major elements in river water, such as the alkalis and alkaline-earths, are of different origins: from rain water, silicate weathering, carbonate and evaporite weathering. A mixing model based on mass budget equation is used in this study, which allows the proportions of each element derived from the different source to be calculated. The carbonate weathering is the main source of these elements in the Xijiang drainage basin. The contribution of rainwater, especially for Na, reaches to approximately 50% in some tributaries. Dissolved elemental concentration of the river waters are corrected for rain inputs (mainly oceanic salts), the elemental concentrations derived from the different rock weathering are calculated. As a consequence, silicate, carbonate and total rock weathering rates, together with the consumption rates of atmospheric CO2 by weathering of each of these lithologies have been estimated. They provide specific chemical erosion rates varying between 5.1~17.8 t/km2/yr for silicate, 95.5~157.2 t/km2/yr for carbonate, and 100.6-169.1 t/km2/yr for total rock, respectively. CO2 consumptions by silicate and carbonate weathering approach 13><109and 270.5x10 mol/yr. Mechanical denudation rates deduced from the multi-year average of suspended load concentrations range from 92-874 t/km2/yr. The high denudation rates are mainly attributable to high relief and heavy rainfall, and acid rain is very frequent in the drainage basin, may exceed 50% and the pH value of rainwater may be <4.0, result from SO2 pollution in the atmosphere, results in the dissolution of carbonates and aluminosilicates and hence accelerates the chemical erosion rate. The compositions of minerals and elements of suspended particulate matter are also investigated. The most soluble elements (e.g. Ca, Na, Sr, Mg) are strongly depleted in the suspended phase with respect to upper continent crust, which reflects the high intensity of rock weathering in the drainage basin. Some elements (e.g. Pb, Cu, Co, Cr) show positive anomalies, Pb/Th ratios in suspended matter approach 7 times (Liu Jiang) to 10 times (Nanpan Jiang) the crustal value. The enrichment of these elements in suspended matter reflects the intensity both of anthropogenic pollution and adsorption processes onto particles. The contents of the soluble fraction of rare earth elements (REE) in the river are low, and REE mainly reside in particulate phase. In dissolved phase, the PAAS-normalized distribution patterns show significant HREE enrichment with (La/Yb) SN=0.26~0.94 and Ce depletion with (Ce/Ce*) SN=0.31-0.98, and the most pronounced negative Ce anomalies occur in rivers of high pH. In the suspended phase, the rivers have LREE-enriched patterns relative to PAAS, with (La/Yb) SN=1 -00-1 .40. The results suggest that pH is a major factor controlling both the absolute abundances of REE in solution and the fractionation of REE of dissolved phase. Ce depletion in river waters with high pH values results probably from both preferential removal of Ce onto Fe-Mn oxide coating of particles and CeC^ sedimentation. This process is known to occur in the marine environment and may also occur in high pH rivers. Positive correlations are also observed between La/Yb ratio and DOC, HCO3", PO4", suggesting that colloids and (or) adsorption processes play an important role in the control of these elements.

松辽盆地河流-三角洲体系高分辩率层序地层学、储层构形及非均质模型研究

This dissertation tries to combine the new theories of high-resolution sequence stratigraphy and reservoir architecture with fine sedimentology to form a integral theory system -"high-resolution sequence sedimentology", which can be applied widely ranging from the early petroleum exploration to the tertiary recovery stage in marine and terrestrial basin. So the west slope area in south of Songliao basin, in which, early-fine exploration have been developed, and Xingnan area of Daqing placantictine in high water-bearing and tertiary recovery stage, are selected as target areas to research and analyze. By applying high-resolution sequence stratigraphy theory as well as analysis of source area-facies, the west slope area has been divided into two source areas and three drainage systems and the following conclusions have been drawn: three high values sandstone areas, two sandstone pinchout zones and one stratigraphic pinchout overlap; the facies between Baicheng-Tongyu drainage system is frist ascertained as large-scale argillaceous filled plain facies; fine-grained braided channel-delta depositional system has been found; plane sedimentary facies and microfacies maps of different-scale sequence have been completed, and then twenty-eight lithologic traps have been detected in the east of Taobao-Zhenlai reverse fault zone; In no exploration area of the west, large-scale stratigraiphic overlap heavy oil reservoirs has first been found, which has become an important prograss. In Xingnan area, in the view of high-resolution sequence stratigraphy, the surface of unconformity (the bottom of SSC13) in P I group has been identified, and the following method and technique have been advanced: the division and correlation methods of short-scale base-level cycle sequence (SSC); the comprehensive research methods of SSC plane microfacies; the division technique of hierarchy and type of flow unit, the origin of large-scale composite sandbody and flow unit; And ,on the basis of these, 103 monosandstone bodies and 87 flow units of the third levels have been identified, and four levels of flow units model of five sandstone-bodies types have been established. Because it is a very difficult task all over the world to research architecture in subsurface monosandstone body, brings forward a series of techniques as follows: technique of researching architecture of thin interbed in subsurface monosandstone body; classification, type and liquid-resisting mechanism of thin interbed; multiple-remember vertical subsequence model of remaining oil in monosadstone body. Models of heterogeneity and architecture of thin interbed in five types of monosandstone body have been established. Applying these techniques, type and distribution of remaining oil in different types of monosandstone bodies have been predicated.

龙滩工程左岸边坡监测资料分析与稳定性评价研究

On the basis of the geological analysis and rock mass toppling deformation and failure mechanism analysis of Longtan engineering left bank slope, the synthetic space-time analysis and influence factors analysis on the surface monitoring data and deep rock mass monitoring data of B-zone of left bank slope are carried on. At the same time, based on the monitoring data analysis in conjunction with the predecessor's mechanics analysis results, the deformation state of B-zone of the left bank slope is discussed and its stability is synthetically evaluated. The detailed research contents and results are as following: According to the monitoring drill histogram analysis of Longtan engineering left bank slope, numerical simulation analysis and model experimentation analysis of bedded counter-inclined steep slope, a new type of toppling deformation and failure mode is proposed, that is "up-slope warping". Then the deformation and failure mode of bedded counter-inclined steep slope is summarized as "down-slope toppling" type, "up-slope warping" type and "complex fold" type. On the basis of synthetic space-time analysis to surface monitoring data and deep rock mass deformation monitoring data of B-zone of Longtan left bank slope;, we can get the conclusion that there exists potential instability rock mass over 520m altitude, especially over 560m altitude of slope B, and the rock mass of around strong-weathering line or creep rock mass breaking band controls the deformation of the whole slope. 1. According to the synthetic space-time analysis and influence factors analysis to the surface monitoring data of B-zone of Longtan left bank slope, a dynamical index, accumulative total acceleration index, which is used to analyze the influence factors of slope surface deformation, is raised. The principle and method of accumulative acceleration index are explained, and the index can be used for the influence factors analysis of the similar slope. 2. Summarize the results of geologic analysis, monitoring analysis and mechanics analysis, the following conclusion can be gotten: the stability of B-zone of the slope is basically good. However, on the condition of drainage and slope toe loading engineering, there is still some creep deformation in the rock mass over 520m altitude, especially over 560m altitude. So, better measures of the monitoring and timely maintenance of the drainage system are suggested in the paper.

工程地质三维可视化技术及其工程应用研究

Study of 3D visualization technology of engineering geology and its application to engineering is a cross subject which includes geosciences, computer, software and information technology. Being an important part of the secondary theme of National Basic Research Program of China (973 Program) whose name is Study of Multi-Scale Structure and Occurrence Environment of Complicated Geological Engineering Mass(No.2002CB412701), the dissertation involves the studies of key problems of 3D geological modeling, integrated applications of multi-format geological data, effective modeling methods of complex approximately layered geological mass as well as applications of 3D virtual reality information management technology.The main research findings are listed below:Integrated application method of multi-format geological data is proposed,which has solved the integrated application of drill holes, engineering geology plandrawings, sectional drawings and cutting drawings as well as exploratory trenchsketch. Its application can provide as more as possible fundamental data for 3Dgeological modeling.A 3D surface construction method combined Laplace interpolation points withoriginal points is proposed, so the deformation of 3D model and the crossing error ofupper and lower surface of model resulted from lack of data when constructing alaminated stratum can be eliminated.3D modeling method of approximately layered geological mass is proposed,which has solved the problems of general modeling method based on the sections or points and faces when constructing terrain and concordant strata.The 3D geological model of VII dam site of Xiangjiaba hydropower stationhas been constructed. The applications of 3D geological model to the auto-plotting ofsectional drawing and the converting of numerical analysis model are also discussed.3D virtual reality information integrated platform is developed, whose mostimportant character is that it is a software platform having the functions of 3D virtualreality flying and multi-format data management simultaneously. Therefore, theplatform can load different 3D model so as to satisfy the different engineeringdemands.The relics of Aigong Cave of Longyou Stone Caves are recovered. Thereinforcement plans of 1# and 2# cave in phoenix hill also be expressed. The intuitiveexpression provided decision makers and designers a very good environment.The basic framework and specific functions of 3D geological informationsystem are proposed.The main research findings in the dissertation have been successfully applied to some important engineering such as Xiangjiaba hydropower station, a military airport and Longyou Stone Caves etc.

地质与生态环境影响下的地表水化学以及碳同位素地球化学特征——以贵州境内珠江水系为例

河流是连接海洋和陆地生态系统的重要途径，也是全球碳循环研究的重要环节。因此，河水的水文地球化学研究是获得有关流域侵蚀、风化以及元素在大陆- 河流- 海洋系统中外生循环过程等的重要途径。由于碳酸盐岩风化作用的产物在很大程度上控制着地表水系的地球化学组成, 因此对碳酸盐岩地区河流的水文地球化学特征的研究, 对于了解碳酸盐岩地区的侵蚀、风化强度以及河流地球化学组成变化的多种控制因素有很大的意义。 单就珠江水系而言，目前该方面的研究范围较窄，主要集中于珠江流域水文气候监测、水体有机污染物的迁移转化以及珠江三角洲与河口水体的同位素示踪研究等几个方面，而对于典型气候、地质地貌区域内的各支流的系统的水文地球化学研究少之又少。事实上，对于珠江水系的干流西江而言，流域内由于喀斯特地貌广泛发育，具有极强的地理特异性，因而各支流在不同地质地貌特征、土壤、气候、植被等条件下的水文地球化学的系统研究以及同位素示踪流域侵蚀状况等方面的研究，不仅对于更好地了解中国西南地区典型喀斯特岩溶区域内土壤、岩石的化学风化、水土流失、水文地球化学特征以及环境污染等方面具有极其重要的意义，同时也对全球碳循环的系统研究有着极其重要的研究价值。 本研究在导师刘丛强研究员主持的国家重大基础规划“973”计划项目“西南喀斯特山地石漠化与适应性生态系统调控”课题的支持下开展完成，选择贵州境内珠江水系干流西江及其支流（红水河流域），以及一级支流柳江源头都柳江及其支流为研究对象，分别通过对流域内，变质碎屑岩以及海相碳酸盐岩两大岩性区域内不同植被覆盖状况下各地表水体中水文地球化学特征以及碳同位素地球化学特征分析，得出以下结论： 1、流域岩性特征是控制流域内各地表水体水文地球化学特征以及流域风化侵蚀程度的重要影响因素。与此同时，研究区内由于人为活动造成的水体污染对于地表水体离子组成特征的变化，也有一定的影响。 2、研究区珠江流域内的地表水体来源主要为大气降水和地下水。研究区内的受西南季风影响下的频繁的降雨过程，是研究区地表水体的主要补给源。研究区内大气降水大多透过表层土壤，进入深部土壤含水层后，或以地表径流的形式冲刷土壤岩石表层后汇入流域内地表河流；或参与地下水体循环，最终以地下水补给地表河流。研究区内NNE方向褶皱断裂构造极其发育，地表河网与地下河网相互连接，转换频繁。 3、研究区内地表水体的离子组成特征以及物理化学性质，主要受流域内土壤岩石化学风化过程的控制。不同岩性特征区域内，地表水体的离子组成特征以及水化学参数有着显著的差异。 4、通过对贵州境内珠江水系75个地表水体中三种不同形态碳DIC、DOC、POC及其部分稳定碳同位素的分析测试，发现研究区内地表水体中的DIC主要来源于研究区内土壤CO2对不同流域内土壤、岩石矿物的化学风化过程。一般而言，植被覆盖状况较好的区域，土壤CO2较为丰富，化学风化作用较为强烈；碳酸盐岩比硅酸盐类易于风化，并且不同岩性区域化学风化过程可以使得地表水体具有不同的离子组成特征与水化学特性。 5、研究区各流域地表水体中的有机碳主要与流域内植被状况相关。地表水体中DOC浓度在一定程度上反映了流域内的植被状况，而TSS以及POC则反映了流域内土壤有机质的情况。研究区地表水体中DOC、POC含量变化情况，是探讨喀斯特地区碳的源汇关系及循环模式的重要依据。 6、河流悬浮物中的POC主要来源于土壤有机质和陆地植物，是研究流域侵蚀问题的重要指标。研究区内变质碎屑岩以及海相碳酸盐岩区域内各地表水体均表现出δ13CPOC 与TOC/TN之间的负相关关系，且地表水体中颗粒有机物具有较低的TOC/TN，表明研究区内各地表水体中POC很可能来源于深层土壤。水动力越强，流域侵蚀越强烈，因而TSS中TOC/TN越低。

长江流域的锂及锂同位素地球化学研究

锂的两个同位素（6Li和7Li）之间相对大的质量差导致它们在自然界的分馏强烈，仅在表生环境就达到了35‰。因而，作为一种有效的示踪剂被广泛地应用于研究宇宙事件、洋壳蚀变及海底热液活动、板块活动、壳幔演化以及示踪卤水来源等地球化学过程。近年来则以大陆风化过程的锂同位素地球化学研究为热点，主要研究方向包括流域尺度大空间范围的总体研究、风化壳剖面的精细研究以及实验室的模拟研究，均涉及水/岩作用过程的锂同位素分馏机理研究。但是，现有的研究结果有的需要进一步论证，有的相互之间存在矛盾，还有部分结论不能自圆其说。 因此，本项论文工作以地表环境过程的锂同位素地球化学研究为切入点，选择长江水系干流和主要支流的地表水、悬浮物和沉积物为研究对象。在低含量样品锂同位素分析方法研究和完善的基础上，就河流体系锂的来源、流域体系的锂同位素组成变化特征及其主要受控因素等方面开展探索性研究。 通过以上研究，本论文得出以下几点认识： 1、采用单一的阳离子树脂柱分离、提纯样品锂，MC-ICP-MS测定其同位素组成。其分析结果的准确度和精确度可以达到现阶段报道的最高水平。海水的锂同位素组成为+31.3±1.0‰（2σ）与前人测定结果的平均值（+31.2‰）接近；样品分析误差约为0.5‰（2σ），与TIMS的分析结果相似。 2、长江水系河水以富含HCO3-、Ca2+为主要特征，两者分别占阴、阳离子总量的70%和50%；其中，以Na+、Cl-含量的变化最大。长江河水的主要离子组成主要受流域岩石风化作用影响，蒸发结晶作用只在少数点起次要作用，而大气沉降的输入十分微弱。岩石风化作用以碳酸盐岩风化的影响最为显著，蒸发盐岩和硅酸岩的影响较小，仅限于长江流域的局部地区。 3、长江水系悬浮物的锂含量及δ7Li值变化较小，分别为41 µg/g~92 µg/g和-4.7‰~+0.7‰。沉积物的锂含量在13.26 µg/g~46.32 µg/g之间，略低于悬浮物的锂含量，而δ7Li较高，在+0.9‰和+9.1‰之间变化。悬浮物和沉积物的锂含量与Al2O3/SiO2、Fe2O3/SiO2、MnO/SiO2及K2O/SiO2等比值之间存在明显的正相关关系，与δ7Li值存在一定的负相关关系，主要表现为粘土矿物对锂的吸附作用，尤其是6Li。 4、长江水系河水的锂含量在1.04 µg/L和31.72 µg/L之间，平均为8.87 µg/L，呈现出从上游至下游逐渐降低的趋势，最高值出现在长江上游的攀枝花段（CJ1）。其锂同位素组成变化也较大，δ7Li值在+7.6‰和+28.1‰之间，但是却呈现出与锂含量变化相反的特征，即从上游至下游逐渐增加，最小值出现在长江上游的攀枝花段(CJ1)。 5、长江干流水体的锂摩尔浓度的倒数（1/Li）和δ7Li值之间存在明显的正相关关系，可能是两个端员组分混合的结果。综合考虑雨水、人为输入和碳酸盐岩对长江干流河水的贡献后，我们认为长江干流河水的锂应该是来自于流域岩石风化的贡献，即蒸发盐岩的溶解和硅酸岩的风化，两者对长江河水锂的贡献在78%和99%之间。 6、悬浮物总是比相应水体富集6Li，导致两者之间的锂同位素分馏明显。悬浮物和河水之间的锂同位素分馏系数（α矿物-流体）在0.976和0.993之间比变化，落在不同粘土矿物吸附产生的分馏范围内。长江上游地区的α矿物-流体落在室温下水铝矿和蒙脱石对锂吸附产生的分馏范围内，下游地区的α矿物-流体则与蛭石和高岭石对水体锂的吸附分馏范围内。除此之外，α矿物-流体还与悬浮物的量密切相关，尤其是在河水进入三峡库区之前。这种相关性同样是粘土矿物对6Li的优先吸附引起的。

Metallic foam processing from the liquid state

Cox, S.J., Bradley, G. and Weaire, D. (2001) Metallic foam processing from the liquid state: the competition between solidification and drainage. Eur. Phys. J. AP 14:87-97. Sponsorship: This research was supported by the Prodex programme of ESA, and is a contribution to ESA contract C14308/AO-075-99. SJC was supported by Enterprise Ireland and a Marie Curie fellowship. GB was supported by the HPC Programme of TCD.

Phosphorus export from a restored wetland ecosystem in response to natural and experimental hydrologic fluctuations

Wetland restoration is a commonly used approach to reduce nutrient loading to freshwater and coastal ecosystems, with many wetland restoration efforts occurring in former agricultural fields. Restored wetlands are expected to be effective at retaining or removing both nitrogen and phosphorus (P), yet restoring wetland hydrology to former agricultural fields can lead to the release of legacy fertilizer P. Here, we examined P cycling and export following rewetting of the Timberlake Restoration Project, a 440 ha restored riverine wetland complex in the coastal plain of North Carolina. We also compared P cycling within the restored wetland to two minimally disturbed nearby wetlands and an adjacent active agricultural field. In the restored wetland we observed increased soluble reactive phosphorus (SRP) concentrations following initial flooding, consistent with our expectations that P bound to iron would be released under reducing conditions. SRP concentrations in spring were 2.5 times higher leaving the restored wetland than a forested wetland and an agricultural field. During two large-scale drawdown and rewetting experiments we decreased the water depth by 1 m in ∼10 ha of inundated wetland for 2 weeks, followed by reflooding. Rewetting following experimental drainage had no effect on SRP concentrations in winter, but SRP concentrations did increase when the experiment was repeated during summer. Our best estimates suggest that this restored wetland could release legacy fertilizer P for up to a decade following hydrologic restoration. The time lag between restoration and biogeochemical recovery should be incorporated into management strategies of restored wetlands. Copyright 2010 by the American Geophysical Union.

Rare targets are rarely missed in correctable search.

Failing to find a tumor in an x-ray scan or a gun in an airport baggage screening can have dire consequences, making it fundamentally important to elucidate the mechanisms that hinder performance in such visual searches. Recent laboratory work has indicated that low target prevalence can lead to disturbingly high miss rates in visual search. Here, however, we demonstrate that misses in low-prevalence searches can be readily abated. When targets are rarely present, observers adapt by responding more quickly, and miss rates are high. Critically, though, these misses are often due to response-execution errors, not perceptual or identification errors: Observers know a target was present, but just respond too quickly. When provided an opportunity to correct their last response, observers can catch their mistakes. Thus, low target prevalence may not be a generalizable cause of high miss rates in visual search.

On the multiple ecological roles of water in river networks

The distribution and movement of water can influence the state and dynamics of terrestrial and aquatic ecosystems through a diversity of mechanisms. These mechanisms can be organized into three general categories wherein water acts as (1) a resource or habitat for biota, (2) a vector for connectivity and exchange of energy, materials, and organisms, and (3) as an agent of geomorphic change and disturbance. These latter two roles are highlighted in current models, which emphasize hydrologic connectivity and geomorphic change as determinants of the spatial and temporal distributions of species and processes in river systems. Water availability, on the other hand, has received less attention as a driver of ecological pattern, despite the prevalence of intermittent streams, and strong potential for environmental change to alter the spatial extent of drying in many regions. Here we summarize long-term research from a Sonoran Desert watershed to illustrate how spatial patterns of ecosystem structure and functioning reflect shifts in the relative importance of different 'roles of water' across scales of drainage size. These roles are distributed and interact hierarchically in the landscape, and for the bulk of the drainage network it is the duration of water availability that represents the primary determinant of ecological processes. Only for the largest catchments, with the most permanent flow regimes, do flood-associated disturbances and hydrologic exchange emerge as important drivers of local dynamics. While desert basins represent an extreme case, the diversity of mechanisms by which the availability and flow of water influence ecosystem structure and functioning are general. Predicting how river ecosystems may respond to future environmental pressures will require clear understanding of how changes in the spatial extent and relative overlap of these different roles of water shape ecological patterns. © 2013 Sponseller et al.

Morphological characteristics of urban water bodies: mechanisms of change and implications for ecosystem function.

The size, shape, and connectivity of water bodies (lakes, ponds, and wetlands) can have important effects on ecological communities and ecosystem processes, but how these characteristics are influenced by land use and land cover change over broad spatial scales is not known. Intensive alteration of water bodies during urban development, including construction, burial, drainage, and reshaping, may select for certain morphometric characteristics and influence the types of water bodies present in cities. We used a database of over one million water bodies in 100 cities across the conterminous United States to compare the size distributions, connectivity (as intersection with surface flow lines), and shape (as measured by shoreline development factor) of water bodies in different land cover classes. Water bodies in all urban land covers were dominated by lakes and ponds, while reservoirs and wetlands comprised only a small fraction of the sample. In urban land covers, as compared to surrounding undeveloped land, water body size distributions converged on moderate sizes, shapes toward less tortuous shorelines, and the number and area of water bodies that intersected surface flow lines (i.e., streams and rivers) decreased. Potential mechanisms responsible for changing the characteristics of urban water bodies include: preferential removal, physical reshaping or addition of water bodies, and selection of locations for development. The relative contributions of each mechanism likely change as cities grow. The larger size and reduced surface connectivity of urban water bodies may affect the role of internal dynamics and sensitivity to catchment processes. More broadly, these results illustrate the complex nature of urban watersheds and highlight the need to develop a conceptual framework for urban water bodies.