Modificação superficial de filmes de poliéster usando plasma a baixa temperatura

A polyester film has a vast application field, due some properties that are inherent of this kind of material such as, good mechanical resistance, chemical resistance to acids and bases and low production cost. However, this material has some limitations as low superficial tension, flat surface, low affinity to dyers, and poor adhesion which impede the use of the same ones for some finality as good wettability. Among the existent techniques to increase the superficial tension, plasma as energy source is the more promising technique, because of their versatility and for not polluting the environment. The plasma surface polymeric modification has been used for many researchers, because it does not affect the environment with toxic agents, the alterations remains only at nanometric layers and this technique shows expressive results. Then, due to its good acceptance, polyester films were treated with oxygen plasma varying the treatment time from 10 to 60 min with an increase of 10 min to each subsequent treatment. Also, the samples were treated with a gas mixture (nitrogen + oxygen) varying the percentage of each gas the mixture from 0 to 100%, the treatment time remaining constant to all treatments (10 min). After plasma treatment the samples were characterized by contact angle, surface tension, Raman spectroscopy, Infrared attenuated total reflection (IR-ATR) and atomic force microscopy, with the aim to study the wettability increase of treated polyester films as its variables. In the (O2/N2) plasma treatment of polyester films can be observed an increase of superficial roughness superior to those treated by O2 plasma. By the other hand, the chemical modification through the implantation of polar groups at the surface is obtained more easily using O2 plasma treatment

Um espaço pioneiro de modernidade educacional: Grupo Escolar Augusto Severo -Natal/RN -1908-13

Cette recherche a pour but d analyser l Ecole Augusto Severo, située dans la ville de Natal dont la construction date de 1907,étant le premier établissement d enseignement primaire à l état du Rio Grande do Norte, pendant le processus de restructuration de l enseignement républicain. On cherche à comprendre la représentation de ce milieu scolaire, comme équipement urbain, dans le processus de modernisation de la ville et comme modèle éducationnel pour l état entre 1908 et 1913. En se servant des études historiographes sur le processus de modernisation de quelques villes brésiliennes et des innovations de l enseignement public primaire au pays, à la fin du dix-neuvième siècle et pendant la première décennie du vingtième siècle, comme source pour mieux saisir le contexte général et spécifique. On reconstitue les aspects économiques, sociaux et politiques déterminants des interventions publiques réalisées dans cette ville par les gouvernements républicains ayant comme obectif la construction d une ville embellie,hygiénique et civilisée. Située au quartier Ribeira, principal scénario de la modernité de Natal, l Ecole Augusto Severo est mise em relief comme symbole de civilité du paysage urbain de l époque pour le citoyen du Rio Grande do Norte. Elle disposait de services d énergie et d un tram électrique. Il y avait devant, un grand lac arborisé et une station ferroviaire. A côté, il y avait le théâtre Carlos Gomes (actuellement Alberto Maranhão). Par suíte de son imposante architecture, raffiné style éclectique,on reflète l idéal républicain des elites locales, avec une conception d espace symbolique et éducative de surveillance et contrôle, caractéristiques de l école graduée républicaine

Glaucoma técnicas de diagnóstico e interpretación – Cd interactivo

Tesis (Optómetra). -- Universidad de La Salle, Facultad de Ciencias de La Salud. Programa de Optometría, 2014

Descripción y análisis del OCT, HRT y GDX en glaucoma : un enfoque para la optometría clínica

Tesis (Optometra). -- Universidad de La Salle, Facultad de Ciencias de La Salud. Programa de Optometria, 2014

Análises de elementos arquitetônicos de proteção solar em edificações institucionais na cidade de Natal/RN Diretrizes projetuais

The present work concerns the use of shade elements as architectural elements to block sunlight in public buildings. In a city like Natal, (5o South) the incidence of sunrays in any type of design should be a constant concern for all the architects. Besides, this habit of avoiding insolation in the environment is not a common practice. Within this context, the present work has the objective to dig deep into the knowledge of solar control, studying some cases and verifying its function according to the orientation and the original design of the building, having in mind if the shade elements usually used in the region have achieved their purpose of providing protection against the incidence of direct sun rays. This study considers the position of the shade element (horizontal and vertical), the angle formed between them and the respective facades, and the local of the buildings in relation to their orientation during the summer, winter and equinox solstice. As supporting instruments the solar map of the city and the protractor, for measuring shade angles, were used. It was concluded that in all the cases studied, it was not possible to obtain the maximum use of the elements. It was verified that the best type of shade element (more efficient) for the city of Natal is the mixed type (horizontal and vertical) and that the vertical shade elements are more efficient in the early mornings and late afternoon. The horizontal shade elements are used more effective at midday. We intend to present the results of this study to the architects in the region in order to show them the correct ways of using the shade elements according to the possible orientation on the facade, as a supporting tool at the time of designing a project as well as a subsidy for further discussions on the elaboration of the new urban standards for the city of Natal/RN

Efeito antibacteriano de tecidos têxteis revestidos por prata através da técnica de deposição por plasma

In this study, it has been investigated the influence of silver film deposition onto 100% polyester woven and non-woven, on the survival of Escherichia coli and Staphylococcus aureus in contact with these surfaces. The treatment was performedin a chamber containing the working gas at low pressure (~ 10-2 mbar). Some process parameters such as as voltage: 470 V; pressure: 10-2 mbar; current : 0.40 A and gas flow: 6 and 10 cm3/min were kept constant. For the treatments with purêargon plasma using a flow of 6 and 10 cm3/min, different treatment times were evaluated, such as, 10 , 20, 30, 40, 50 and 60 minutes. Contact angle (sessile drop), measurements were used to determine the surface tension of the treated fabrics and its influence on the bacteria grow as weel as the possibilities of a biofilm formation. The formation of a silver film, as well as the amount of this element was verified byEDX technique. The topography was observed through scanning electron microscopy (SEM) to determine the size of silver grains formed on the surfaces of the fabric and assess homogeneity of treatment. The X-ray diffraction (XRD) was used to analyze the structure of silver film deposition. The woven fabric treatments enabled the formation of silver particulate films with particle size larger than the non-woven fabrics. With respect to bacterial growth, all fabrics were shown to be bactericidal for Staphylococcus aureus (S. aureus), while for the Escherichia coli (E. coli), the best results were found for the non-woven fabric (TNT) treated with a flow of 10 cm3/min to both bacteria

Pirólise de borras oleosas de petroleo utilizando nanomateriais

The oily sludge is a complex mix of hydrocarbons, organic impurities, inorganic and water. One of the major problems currently found in petroleum industry is management (packaging, storage, transport and fate) of waste. The nanomaterials (catalysts) mesoporous and microporous are considered promising for refining and adsorbents process for environment protection. The aim of this work was to study the oily sludge from primary processing (raw and treated) and vacuum residue, with application of thermal analyses technique (pyrolysis), thermal and catalytic pyrolysis with nanomaterials, aiming at production petroleum derived. The sludge and vacuum residue were analyzed using a soxhlet extraction system, elemental analysis, thin layer chromatography, thermogravimetry and pyrolysis coupled in gas chromatography/mass spectrometry (Py GC MS). The catalysts AlMCM-41, AlSBA-15.1 e AlSBA-15.2 were synthesized with molar ratio silicon aluminum of 50 (Si/Al = 50), using tetraethylorthosilicante as source of silicon and pseudobuhemita (AlOOH) as source of aluminum. The analyzes of the catalysts indicate that materials showed hexagonal structure and surface area (783,6 m2/g for AlMCM-41, 600 m2/g for AlSBA-15.1, 377 m2/g for AlSBA-15.2). The extracted oily sludge showed a range 65 to 95% for organic components (oil), 5 to 35% for inorganic components (salts and oxides) and compositions different of derivatives. The AlSBA-15 catalysts showed better performance in analyzes for production petroleum derived, 20% increase in production of kerosene and light gas oil. The energy potential of sludge was high and it can be used as fuel in other cargo processed in refinery

A Diagnostic Calculator for Detecting Glaucoma on the Basis of Retinal Nerve Fiber Layer, Optic Disc, and Retinal Ganglion Cell Analysis by Optical Coherence Tomography

Purpose: The purpose of this study was to develop and validate a multivariate predictive model to detect glaucoma by using a combination of retinal nerve fiber layer (RNFL), retinal ganglion cell-inner plexiform (GCIPL), and optic disc parameters measured using spectral-domain optical coherence tomography (OCT). Methods: Five hundred eyes from 500 participants and 187 eyes of another 187 participants were included in the study and validation groups, respectively. Patients with glaucoma were classified in five groups based on visual field damage. Sensitivity and specificity of all glaucoma OCT parameters were analyzed. Receiver operating characteristic curves (ROC) and areas under the ROC (AUC) were compared. Three predictive multivariate models (quantitative, qualitative, and combined) that used a combination of the best OCT parameters were constructed. A diagnostic calculator was created using the combined multivariate model. Results: The best AUC parameters were: inferior RNFL, average RNFL, vertical cup/disc ratio, minimal GCIPL, and inferior-temporal GCIPL. Comparisons among the parameters did not show that the GCIPL parameters were better than those of the RNFL in early and advanced glaucoma. The highest AUC was in the combined predictive model (0.937; 95% confidence interval, 0.911–0.957) and was significantly (P = 0.0001) higher than the other isolated parameters considered in early and advanced glaucoma. The validation group displayed similar results to those of the study group. Conclusions: Best GCIPL, RNFL, and optic disc parameters showed a similar ability to detect glaucoma. The combined predictive formula improved the glaucoma detection compared to the best isolated parameters evaluated. The diagnostic calculator obtained good classification from participants in both the study and validation groups.

Entre a arte e o engenho: a formação de professores do ensino primário em Évora (1884-1919)

O presente texto pretende dar um contributo para o estudo da formação de professores do ensino primário em Évora, nos finais do século XIX e as duas primeiras décadas do Século XX. Para tal, impõe-se-nos enquadrar a formação de professores do ensino primário em Portugal, caracterizar a rede escolar e os professores do distrito de Évora da segunda metade do Século XIX e, a partir daí, descrever o funcionamento da Escola Normal de 2a classe de Évora, estabelecida no edifício da Igreja de S. Pedro e inaugurada em 1884. Após uma curta existência de oito anos, esta escola foi encerrada e deu lugar à Escola Distrital de Habilitação para o Magistério Primário de Évora, criada em 1896. Apesar de alguma instabilidade institucional (com mudanças nos curricula e na duração da formação), entre 1884 e 1919, estas duas escolas habilitaram dezenas de professores do ensino primário que leccionaram no distrito de Évora. Between art and ability: The primary teachers' formation in Évora (1884 -1919). ABSTRACT: The following text has the purpose of contributing for the study of primary teachers' formation in Évora by the end of the nineteenth century and the first two decades of the twentieth century. Therefore, we first need to understand the frame given by the teachers' formation of the primary school in Portugal, to characterize the school network and the teachers of Évora district of the second half of the nineteenth century and, from that, describe the function of Escola Normal de 2a classe of Évora, established in the building of S. Pedro's church and first opened in 1884. After a short eight years of existence, this school was closed and gave place to Escola Distrital de Habilitação for the Magistério Primário of Évora, created in 1896. Despite some institutional instability (with changes in the curricula and length of the formation), between 1884 and 1919, this two schools qualified several primary teachers for the district of Évora.

Proposta de valorização de espaço aberto público da aldeia da Luz

A construção da barragem do Alqueva causou várias transformações na paisagem ao nível sócioeconómico e ecológico. A submersão da antiga aldeia da Luz foi resultado desta construção, com consequente construção de uma nova aldeia. Um acontecimento que é marcante na história do Alqueva. O objetivo do trabalho de projeto é valorizar os espaços abertos públicos da nova aldeia e espaço envolvente. Esta estratégia assentou no reconhecimento e valorização dos sistemas ecológicos e culturais aí presentes, e na valorização do potencial turístico que lhe está associada. A metodologia do trabalho inclui uma análise das aldeias e realização de um inquérito à população (habitantes, residentes ocasionais e visitantes) com o fim de melhor responder aos seus anseios no presente. O trabalho culmina com a Proposta de Valorização de Espaço Aberto Público para a aldeia da Luz e espaço próximo envolvente e com o Plano de Estrutura Ecológica e Cultural (urbana e rural); Aldeia da Luz: towards the open public spaces valorization ABSTRACT: The construction of the Alqueva dam has caused several landscape transformations, in the socioeconomical, ecological matter. The submersion of the old Luz village was a direct result of this construction, with the consequent construction of a new Luz village. An event, which is remarkable in the Alqueva history. The project work objective is to value the public open spaces of the new village and its surrounding space. This strategy settled on the recognition and appreciation of the existing ecological and cultural systems, and in the touristic potential that is associated with it. The work methodology includes analysis of the villages and a survey fulfilment targeting the population (habitants, occasional residents and visitors) with the intent of better answering their current desires. The work culminates with the Public Open Space Appreciation Proposal for the Luz village and nearby surrounding space, and with the Ecological and Cultural Structures Plan (urban and rural).

Monitoramento da temperatura e da concentração de dióxido de carbono em estufas de topo aberto.

A agricultura é extremamente dependente e relacionada às condições climáticas, portanto as variações do clima têm reflexos diretos sobre o manejo das culturas. Desse modo, as mudanças climáticas terão efeito sobre a ocorrência, o desenvolvimento e a severidade das doenças de plantas. Para a realização de estudos de impactos das mudanças climáticas, são utilizadas estufas de topo aberto com incrementos controlados da concentração de CO2. O presente trabalho teve como objetivo monitorar a concentração de CO2 e temperatura média diária no interior das estufas de topo aberto, em intervalos de 10 minutos. Os dados obtidos demonstraram que a estufa resultou num incremento médio de 1,5 °C e a concentração de CO2 manteve-se acima dos valores obtidos em ambiente aberto.

Efeito do aumento da concentração de CO2 atmosférico sobre a comunidade microbiana do filoplano da soja em estufa de topo aberto.

2008

Efeito do aumento da concentração de CO2 atmosférico sobre a incidência de Pyricularia grisea em sementes de arroz cultivado em estufas de topo aberto.

2008

Acesso aberto no contexto dos repositórios digitais educacionais: o caso da rede UNA-SUS

Com o intuito de estabelecer padrões mínimos de negociação de direitos autorais que viabilizem o acesso aberto de objetos de aprendizagem publicados no repositório educacional digital da UNA-SUS - o Acervo de Recursos Educacionais em Saúde - ARES -, foi iniciada a implementação de uma Política de Acesso Aberto da UNA-SUS. Para tanto, foi realizada uma pesquisa bibliográfica sobre os temas relacionados ao acesso aberto e direitos autorais, seguida do levantamento de necessidades da Rede UNA-SUS. A definição de instrumentos legais para assegurar o processo de gestão dos direitos autorais foi feita com o apoio de um consultor jurídico para validação por um grupo de trabalho constituído no âmbito da Rede e posterior implementação dos elementos que constituirão a Política de Acesso da UNA-SUS.

Política de acesso aberto UNA-SUS

Discorre sobre conceitos relacionados à propriedade intelectual, direito autoral e acesso aberto, abordados na Política de Acesso Aberto do Sistema UNA-SUS, para viabilizar a disseminação de recursos educacionais em seu repositório educacional - o Acervo de Recursos Educacionais em Saúde (ARES). A gestão de direitos autorais no âmbito da produção de recursos educacionais neste Sistema é destacada com a caracterização dos modelos de instrumentos adotados: Termo de Cessão Padrão de direitos autorais, Autorização para uso de voz e imagem, Termos de uso para usuários finais de recursos educacionais disponíveis em acervo. Além disso, documentos elaborados para orientação a cerca de direitos autorais também são apresentados.