The formation of Co2C species in activated carbon supported cobalt-based catalysts and its impact on Fischer-Tropsch reaction

The cobalt carbide (Co2C) species was formed in some activated carbon supported cobalt-based (Co/AC) catalysts during the activation of catalysts. It was found that the activity of Fischer-Tropsch reaction over Co-based catalysts decreased due to the formation of cobalt carbide species. Some promoters and pretreatment of activated carbon with steam could restrain the formation of cobalt carbide.

Ligand modified real heterogeneous catalysts for fixed-bed hydroformylation of propylene

A novel ligand modified heterogeneous catalyst has been developed for hydroformylation of propylene, which showed excellent activity, selectivity and stability and need not be separated from the product after reaction in a fixed-bed reactor. The coordination bonds between triphenyl phosphine (PPh3) and Rh/SiO2 were confirmed by means of thermogravimetric (TG), solid-state P-31 NMR, XPS and FT-IR. Two types of active species for hydroformylation were formed, which were proved by in situ FT-IR techniques. The problem of metal leaching was greatly reduced by directly fastening Rh particles on the support, and the active Rh species that was responsible for the outstanding performance of propylene hydroformylation was tightly bound by the very strong metal-metal bonds. No sign of deactivation was observed over a period of more than 1000 h on the condition that PPh3 was added at 300-350 h of time on stream. (c) 2005 Elsevier B.V. All rights reserved.

Guia de instalação do sistema BDcana.

Introdução. Arquitetura do Sstema BDCana. Requisitos de hardware e software. Instalação e configuração dos software. Instalação do apache. Instalação do Apache. Instalação do PHP. Configuração do Apache. Configuração do PHP. Instalação do MySQL. Instalação do phpMyAdmin. Instalação do sistema BDCana.

Morphology transcription process from CMC micelles to inorganogel and its effect on the properties of alumina particle

In this study, a carboxymethyl cellulose (CMC)-mediated sol-gel process was developed to synthesize the alumina hydoxide whiskers. During the process, inexpensive inorganic salts were used as precursors and supercritical drying method was used to extract the water in hydrogel. The influences of CMC on the gel formation and the particle morphology were investigated. The results show that the formation of CMC-aluminium hydroxide organic-inorganic hybridgels led to a morphology transcription process from CMC micelles to aluminium hydroxide gel, as a result, the precursor with whiskerious morphology was obtained.

Application of capillary zone electrophoresis in the separation and determination of the curcuminoids in urine

The major components of the plant curcuma longa are the curcuminoids that include curcumin, demethoxycurcumin and bisdemethoxycurcumin. It has been reported the curcuminoids have some important activities. A new CZE method with diode array detection has been developed for the separation and determination of the curcumin, demethoxycurcumin and bisdemethoxycurcumin. Three curcuminoids could be readily separated within 7 min with a 15 mM sodium tetraborate buffer containing 10% methanol (v/v) at pH 10.8, 25 kV and 30 degrees C. The method has been validated and shows good performance with respect to selectivity, reproducibility, linearity, limits of detection and recovery. The proposed method was successfully applied to determine the curcuminoids in urine. (c) 2004 Elsevier B.V. All rights reserved.

Clinical significance and prognostic value of urinary nucleosides in breast cancer patients

Objective: Thirteen urinary nucleosides, primarily degradation products of tRNA, were evaluated as potential tumor markers for breast cancer patients.

Insight into permeability of protein through microcapsule membranes

The objective of this paper is to analyze the characteristics of protein permeability in alainate-polylysine-alginate (APA) and alginate-chitosan-alginate (ACA) microcapsules by mathematical models based on the balance of chemical potential. The comparison between calculated results and experimental data shows that the models can describe the process of protein diffusion from microcapsule and protein release into microcapsule successfully. The influences of membrane composition on the permeability of ACA microcapsule have been investigated and analyzed. The effect of resistance on the mass transfer is further analyzed theoretically with the aid of mathematical modeling. (c) 2005 Elsevier B.V. All rights reserved.

Clinical Use of the Volume-Time Curve for Endotracheal Tube Cuff Management

BACKGROUND: Previous investigation showed that the volume-time curve technique could be an alternative for endotracheal tube (ETT) cuff management. However, the clinical impact of the volume-time curve application has not been documented. the purpose of this study was to compare the occurrence and intensity of a sore throat, cough, thoracic pain, and pulmonary function between these 2 techniques for ETT cuff management: volume-time curve technique versus minimal occlusive volume (MOV) technique after coronary artery bypass grafting. METHODS: A total of 450 subjects were randomized into 2 groups for cuff management after intubation: MOV group (n = 222) and volume-time curve group (n = 228). We measured cuff pressure before extubation. We performed spirometry 24 h before and after surgery. We graded sore throat and cough according to a 4-point scale at 1, 24, 72, and 120 h after extubation and assessed thoracic pain at 24 h after extubation and quantified the level of pain by a 10-point scale. RESULTS: the volume-time curve group presented significantly lower cuff pressure (30.9 +/- 2.8 vs 37.7 +/- 3.4 cm H2O), less incidence and intensity of sore throat (1 h, 23.7 vs 51.4%; and 24 h, 18.9 vs 40.5%, P < .001), cough (1 h, 19.3 vs 48.6%; and 24 h, 18.4 vs 42.3%, P < .001), thoracic pain (5.2 +/- 1.8 vs 7.1 +/- 1.7), better preservation of FVC (49.5 +/- 9.9 vs 41.8 +/- 12.9%, P = .005), and FEV1, (46.6 +/- 1.8 vs 38.6 +/- 1.4%, P = .005) compared with the MOV group. CONCLUSIONS: the subjects who received the volume-time curve technique for ETT cuff management presented a significantly lower incidence and severity of sore throat and cough, less thoracic pain, and minimally impaired pulmonary function than those subjects who received the MOV technique during the first 24 h after coronary artery bypass grafting.

Special Educational Needs in Wales

Special Educational Needs in Wales (with K Williams and B Rainey), (2004) 3 Wales Journal of Law and Policy 17-33. RAE2008

Islamic Dress, Institutions of Education and Freedom of Religion under the ECHR: A UK perspective

Sherlock, A. and Williams, K. (2005). Islamic Dress, Institutions of Education and Freedom of Religion under the ECHR: A UK Perspective. Wales Journal of Law and Policy. 4, pp. 214-230. RAE2008

Seguridad y violencia de género en Navarra

A lo largo de este estudio se pretende reflexionar acerca del concepto de seguridad en general, para posteriormente abordar la violencia de género como un tipo de violencia más propio de nuestra época. Con la finalidad de construir un plan de protección, basándome en las necesidades escasamente cubiertas por parte de los cuerpos de seguridad en Navarra y las distintas instituciones que participan en el protocolo de actuación. Hasta el momento la mayoría de estudios de relevancia sobre el tema se han centrado en definir cuál es el problema y a quienes afecta, pero siguen haciendo falta tanto medidas de prevención que disminuyan considerablemente este tipo de delitos, como de protección para las víctimas y el entorno que les rodea, con el fin de sentirse respaldadas y protegidas por parte de la sociedad y de las instituciones.

Annales del Reyno de Navarra

Signaturas: *6, A-F4, G2, H-Z4, 2A-2Z4, 3A-3Z4, 4A-4Z4, 5A-5D4, 5E2, 5F4 ; *5, A-Z4, 2A-2Z4, 3A-3Y4, Z2, 4A4 ; *5, A-Z4, 2A-2Z4, 3A-3Z4, 4A-4N4, 4O5 ; *5, A-Z4, 2A-2Z4, 3A-3Z4, 4A-4O4, 4P2, 4Q1, 4R4 ; *5, A-Z4, 2A-2Z4, 3A-3M4, *2, A-S4.

Sinalização das dificuldades de aprendizagem e/ou deficiência mental em crianças da pré-escola e do 1º ciclo, através de dois instrumentos de Victória de la Cruz

Dissertação apresentada à Universidade Fernando Pessoa como parte dos requisitos para obtenção do grau de Mestre em Psicologia Clínica e da Saúde.

Cuadernos de diseño para la artesanía. Diversificación del calado.

40 hojas : Dibujos técnicos.

How does TCP generate Pseudo-self-similarity?

Long-range dependence has been observed in many recent Internet traffic measurements. In addition, some recent studies have shown that under certain network conditions, TCP itself can produce traffic that exhibits dependence over limited timescales, even in the absence of higher-level variability. In this paper, we use a simple Markovian model to argue that when the loss rate is relatively high, TCP's adaptive congestion control mechanism indeed generates traffic with OFF periods exhibiting power-law shape over several timescales and thus introduces pseudo-long-range dependence into the overall traffic. Moreover, we observe that more variable initial retransmission timeout values for different packets introduces more variable packet inter-arrival times, which increases the burstiness of the overall traffic. We can thus explain why a single TCP connection can produce a time-series that can be misidentified as self-similar using standard tests.