Análisis de las diferentes tecnologías de centrales termosolares.

[ES]En este proyecto se recoge un análisis de las diferentes tecnologías de centrales termosolares. Las energías renovables tienen un papel fundamental en el abastecimiento energético futuro, ya que son una fuente inagotable con un impacto medioambiental mínimo. Dentro de las renovables, la energía termosolar es una de las más destacables en España, que se ha situado como el país líder en termosolar. Existen cuatro tecnologías diferentes para este tipo de centrales, por lo que el objetivo de este trabajo es profundizar en su conocimiento y proporcionar un criterio objetivo que permita seleccionar la más adecuada en futuras instalaciones. Para ello, se considerarán tanto aspectos técnicos como económicos, con el fin de estudiar las principales ventajas y desventajas de cada tipo.

Gestión Energética. Estimación de necesidades de potencia eólica.

[ES]Este trabajo de fin de grado (TFG) pretende analizar la evolución de la demanda en el sistema eléctrico peninsular y la potencia disponible para decidir si, en el medio plazo, será necesario incorporar nueva potencia o prescindir de alguna de las centrales existentes. El estudio considerará tanto fuentes de energía renovables como no renovables, centrándose en la necesidad, o no, de incorporar nueva potencia eólica. El TFG considerará los siguientes aspectos: el contexto energético de la península española, el análisis de la situación actual y previsiones. Este TFG responde a la necesidad de realizar una buena gestión energética con el objetivo reducir las emisiones de CO2 mejorando el uso de la energía eólica y optimizando el mix energético.

Aporte adicional de energía renovable geotérmica a instalación con cogeneración en hospital existente.

[ES]Este proyecto tiene como objetivo apoyar a la generación de energía por cogeneración mediante una fuente de energía renovable. Se pretende plantear una solución que satisfaga parte de las necesidades básicas del Hospital Universitario de Álava, en su sede del Hospital de Santiago, de una forma económicamente rentable. Este proyecto se enmarca dentro de los esfuerzos en la promoción de energías renovables que comenzaron con el protocolo Kioto, al que le siguieron los objetivos Europa 20/20/20. Se realizará un acercamiento a la utilización de la energía renovable geotérmica como fuente de energía que disminuye el impacto ambiental. El edificio hospitalario considerado ya cuenta con un sistema de generación energética con cogeneración, considerada dentro del régimen especial, por la utilización de energía residual para procesos que de otra manera hubieran requerido consumo de combustible. Se plantearán diferentes alternativas para la generación de energía térmica con geotermia, que al ser de origen renovable, es una fuente de energía de combustibles no fósiles, y se demostraran sus beneficios analizando cómo mejora la huella de carbono del hospital con la propuesta. Finalmente, para valorar si se trata de un proyecto viable se planteará el estudio económico analizando el presupuesto y análisis de rentabilidad.

Diseño y montaje de un identificador y conmutador para carga de baterías en serie

[ES]El objetivo de este proyecto es diseñar y construir un circuito identificador y conmutador para carga de baterías en serie autónomo. La funcionalidad de este dispositivo es determinar cual es la batería menos cargada de un banco de baterías de ácido plomo que alimenta un coche al estándar de 48 voltios(conformado por cuatro baterías de 12 voltios). Una vez determinado cual es la batería menos cargada debe re-­‐ direccionar la corriente dada por una placa solar a dicha batería. Todo esto debe hacerlo de forma autónoma, a través de un programa específico, implementado en un microcontrolador. En las diferentes fases del proyecto se ha diseñado el software, se ha diseñado y montado el hardware y se ha verificado su correcto funcionamiento. Además se presentan los costes y la viabilidad de una propuesta de fabricación estandarizada a partir de los planos resultantes del proyecto. Este proyecto surge como respuesta a la actual necesidad de aumentar la limitada autonomía de los coches eléctricos y hacerlos más eficientes. El proyecto se ha llevado a cabo en el laboratorio de electrónica de la ETSI de Bilbao y pretende promover el uso de los coches eléctricos y energías renovables.

El vehículo eléctrico en el ámbito de las microrredes eléctricas.

[ES]En este trabajo se propone el diseño técnico de una microrred eléctrica para la recarga domestica del vehículo eléctrico a partir de energías renovables. Para ello se realizará un estudio del emplazamiento de la instalación y con los datos obtenidos se decidirá la fuente de generación renovable más adecuada para satisfacer el requerimiento de energía para la recarga. A continuación se elegirán los componentes que completen la instalación.

Intense frequency upconversion luminescence in Yb3+/Tm3+-codoped oxychloride germanate glasses

Yb3+/Tm3+-codoped oxychloride germanate glasses for developing potential upconversion lasers have been fabricated and characterized. Structural properties were obtained based on the Raman spectra analysis, indicating that PbCl2 plays an important role in the formation of glass network and has an important influence on the maximum phonon energies of host glasses. Intense blue and weak red emissions centered at 477 and 650 nm, corresponding to the transitions (1)G(4) -> H-3(6) and (1)G(4) -> H-3(4), respectively, were observed at room temperature. With increasing PbCl2 content, the intensity of blue (477 nm) emission increases significantly, while the red (650 nm) emission increases slowly. The results indicate that PbCl2 has more influence on the blue emissions than the red emission in oxychloride germanate glasses. The possible upconversion mechanisms are discussed and estimated. Intense blue upconversion luminescence indicates that these oxychloride germanate glasses can be used as potential host material for upconversion lasers. C (c) 2005 Springer Science + Business Media, Inc.

Upconversion luminescence of Tm3+/Yb3+-codoped oxyhalide tellurite glasses

Thermal stability, Raman spectra and blue upconversion luminescence properties of Tm-3divided by /Yb-3divided by -codoped halide modified tellurite glasses have been Studied. The results showed that the mixed halide modified tellurite glass (TFCB) has the best thermal stability, the lowest phonon energies and the strongest upconversion emissions. The effect of halide on upconversion intensity is observed and discussed and possible upconversion mechanisms are evaluated. The intense blue upconversion luminescence of Tin (3+) in TFCB Glass may be a potentially useful material for developing upconversion optical devices.. (C) 2004 Elsevier Ltd. All rights reserved.

Gain Scheduling Control of an Islanded Microgrid Voltage

The aim of this research study has been to design a gain scheduling (GS) digital controller in order to control the voltage of an islanded microgrid in the presence of fast varying loads (FVLs), and to compare it to a robust controller. The inverter which feeds the microgrid is connected to it through an inductance-capacitor-inductance (LCL) filter. The oscillatory and nonlinear behaviour of the plant is analyzed in the whole operating zone. Afterwards, the design of the controllers which contain two loops in cascade are described. The first loop concerns the current control, while the second is linked to the voltage regulation. Two controllers, one defined as Robust and another one as GS controller, are designed for the two loops, emphasizing in their robustness and their ability to damp the oscillatory plant behaviour. To finish, some simulations are carried out to study and compare the two kinds of controllers in different operating points. The results show that both controllers damp the oscillatory behaviour of the plant in closed loop (CL), and that the GS controller ensures a better rejection of current disturbances from FVLs.

Effect of lithium-sodium mixed-alkali on phase transformation kinetics in Er3+/Yb3+ co-doped aluminophosphate glasses

Er3+ doped aluminophosphate glasses with various Na2O/Li2O ratios were prepared at 1250 degrees C using a silica crucible to study mixed alkali effect (MAE). The effect of relative alkali content on glass transition temperature, crystallization temperature and thermal stability were investigated using differential scanning calorimetry (DSC). In addition, apparent activation energies for crystallization, E, were determined employing the Kissinger equation. The effect of Al2O3 content on the magnitude of MAE was also discussed. No mixed-alkali effect is observed on crystallization temperature. (c) 2006 Elsevier B.V. All rights reserved.

Pitch Based Wind Turbine Intelligent Speed Setpoint Adjustment Algorithms

This work is aimed at optimizing the wind turbine rotor speed setpoint algorithm. Several intelligent adjustment strategies have been investigated in order to improve a reward function that takes into account the power captured from the wind and the turbine speed error. After different approaches including Reinforcement Learning, the best results were obtained using a Particle Swarm Optimization (PSO)-based wind turbine speed setpoint algorithm. A reward improvement of up to 10.67% has been achieved using PSO compared to a constant approach and 0.48% compared to a conventional approach. We conclude that the pitch angle is the most adequate input variable for the turbine speed setpoint algorithm compared to others such as rotor speed, or rotor angular acceleration.

Avaliação da remoção do íon cádmio em solução aquosa utilizando processos de osmose inversa e nanofiltração

Os efluentes contendo cádmio podem ser gerados dos por várias indústrias. A aplicação de ambas as tecnologias osmose inversa (OI) e nanofiltração (NF) para o tratamento de efluentes contendo o íon cádmio para reduzir a degradação ambiental foram estudadas no presente trabalho. Amostras sintéticas contendo o íon cádmio em várias concentrações foram preparadas e submetidas aos tratamentos por OI e NF em escala laboratorial. Assim, dividiu-se o processo de remoção em três etapas: 1- analisou-se os processos de osmose inversa e nanofiltração em termos da rejeição do íon cádmio, onde se correlacionou e avaliou os principais parâmetros de processos (concentração da solução alimentação, fluxo de permeado e pressão) e comparou-se os sistemas entre si. Nas etapas 2 e 3 avaliou-se os efeitos da salinidade utilizando os contra-íons zinco e sódio respectivamente, sobre a rejeição do íon cádmio no sistema de osmose inversa em soluções aquosas contendo misturas de sulfato de cádmio e sulfato de zinco, e sulfato de cádmio e sulfato de sódio. Mediu-se as concentrações de cádmio e zinco por espectroscopia de absorção atômica e as concentrações de sulfato e sódio por cromatografia de íons. Os resultados obtidos na primeira etapa dos experimentos mostram que a osmose inversa e nanofiltração são eficientes na remoção de cádmio, onde se obteve as taxas médias de rejeição de 92,4% e 96,6% respectivamente, sendo esses valores iguais em magnitude, tendo em vista os valores da incerteza padrão relativa associada a esses resultados. Em ambos os sitemas, os fluxos de permeado e as rejeições não sofreram influência do aumento da concentração de cádmio na solução alimentação.Na etapa 2, os resultados mostraram a diminuição da rejeição de cádmio com o aumento da concentração de sulfato de zinco na alimentação, sendo esse fenômeno atribuído a semelhança existente entre os íons Cd2+ e Zn2+ associados aos seus raios iônicos de hidratação e as energias de hidratação. Foram observadas as quedas do fluxo de permeado e das rejeições com o aumento da concentração de alimentação provavelmente devido ao efeito da polarização. Na etapa 3, a rejeição do íon cádmio não foi afetada pelo aumento da concentração de sulfato de sódio na alimentação, assim como os fluxos de permeado. Outro aspecto relacionado à rejeição é que a difusão do sódio através da membrana é favorecida frente à difusão do cádmio, sendo atribuído ao menor raio de hidratação do sódio

Modeling Innovative Power Take-Off Based on Double-Acting Hydraulic Cylinders Array for Wave Energy Conversion

One of the key systems of a Wave Energy Converter for extraction of wave energy is the Power Take-Off (PTO) device. This device transforms the mechanical energy of a moving body into electrical energy. This paper describes the model of an innovative PTO based on independently activated double-acting hydraulic cylinders array. The model has been developed using a simulation tool, based on a port-based approach to model hydraulics systems. The components and subsystems used in the model have been parameterized as real components and their values experimentally obtained from an existing prototype. In fact, the model takes into account most of the hydraulic losses of each component. The simulations show the flexibility to apply different restraining torques to the input movement depending on the geometrical configuration and the hydraulic cylinders on duty, easily modified by a control law. The combination of these two actions allows suitable flexibility to adapt the device to different sea states whilst optimizing the energy extraction. The model has been validated using a real test bench showing good correlations between simulation and experimental tests.

Evolución y transcendencia del sector de las energias renovables en España

Nowadays the energies that still prevail on a global scale as a source of generation of electricity are those that come from fossil resources. Nevertheless, in a few years the future of energy will center on renewable energies. Those countries that are not involved in their development will be at a clear disadvantage at economic level, since the electrical power is the base for the development of human society and the renewable energies are essential for its production. The present work has as a target to show, in a clear and concise form, the current situation of the sector of renewable energies in Spain. In addition, we present in a brief and summarised form, an aspect that has been essential in the development of the renewable energies in Spain is tackled. This is, the legislation on the matter as well as the development plans that Spain has carried out for its promotion. Finally, the study considers the compared situation of the sector of the renewable energies and of the energy sector in general in Spain in the context of the EU. IDIOMA: Ingles

Evaluating boundary dependent errors in QM/MM simulations.

Hybrid quantum mechanics/molecular mechanics (QM/MM) simulations provide a powerful tool for studying chemical reactions, especially in complex biochemical systems. In most works to date, the quantum region is kept fixed throughout the simulation and is defined in an ad hoc way based on chemical intuition and available computational resources. The simulation errors associated with a given choice of the quantum region are, however, rarely assessed in a systematic manner. Here we study the dependence of two relevant quantities on the QM region size: the force error at the center of the QM region and the free energy of a proton transfer reaction. Taking lysozyme as our model system, we find that in an apolar region the average force error rapidly decreases with increasing QM region size. In contrast, the average force error at the polar active site is considerably higher, exhibits large oscillations and decreases more slowly, and may not fall below acceptable limits even for a quantum region radius of 9.0 A. Although computation of free energies could only be afforded until 6.0 A, results were found to change considerably within these limits. These errors demonstrate that the results of QM/MM calculations are heavily affected by the definition of the QM region (not only its size), and a convergence test is proposed to be a part of setting up QM/MM simulations.

Valuation of Wind Energy Projects: A Real Options Approach

We address the valuation of an operating wind farm and the finite-lived option to invest in it under different reward/support schemes: a constant feed-in tariff, a premium on top of the electricity market price (either a fixed premium or a variable subsidy such as a renewable obligation certificate or ROC), and a transitory subsidy, among others. Futures contracts on electricity with ever longer maturities enable market-based valuations to be undertaken. The model considers up to three sources of uncertainty: the electricity price, the level of wind generation, and the certificate (ROC) price where appropriate. When analytical solutions are lacking, we resort to a trinomial lattice combined with Monte Carlo simulation; we also use a two-dimensional binomial lattice when uncertainty in the ROC price is considered. Our data set refers to the UK. The numerical results show the impact of several factors involved in the decision to invest: the subsidy per MWh generated, the initial lump-sum subsidy, the maturity of the investment option, and electricity price volatility. Different combinations of variables can help bring forward investments in wind generation. One-off policies, e.g., a transitory initial subsidy, seem to have a stronger effect than a fixed premium per MWh produced.