Microscopic Mechanism and Kinetics of Ice Formation at Complex Interfaces: Zooming in on Kaolinite

Most ice in nature forms because of impurities which boost the exceedingly low nucleation rate of pure supercooled water. However, the microscopic details of ice nucleation on these substances remain largely unknown. Here, we have unraveled the molecular mechanism and the kinetics of ice formation on kaolinite, a clay mineral playing a key role in climate science. We find that the formation of ice at strong supercooling in the presence of this clay is about 20 orders of magnitude faster than homogeneous freezing. The critical nucleus is substantially smaller than that found for homogeneous nucleation and, in contrast to the predictions of classical nucleation theory (CNT), it has a strong two-dimensional character. Nonetheless, we show that CNT describes correctly the formation of ice at this complex interface. Kaolinite also promotes the exclusive nucleation of hexagonal ice, as opposed to homogeneous freezing where a mixture of cubic and hexagonal polytypes is observed.

Ultrafast charge-transfer in organic photovoltaic interfaces: geometrical and functionalization effects

Understanding the microscopic mechanisms of electronic excitation in organic photovoltaic cells is a challenging problem in the design of efficient devices capable of performing sunlight harvesting. Here we develop and apply an ab initio approach based on time-dependent density functional theory and Ehrenfest dynamics to investigate photoinduced charge transfer in small organic molecules. Our calculations include mixed quantum–classical dynamics with ions moving classically and electrons quantum mechanically, where no experimental external parameter other than the material geometry is required. We show that the behavior of photocarriers in zinc phthalocyanine (ZnPc) and C60 systems, an effective prototype system for organic solar cells, is sensitive to the atomic orientation of the donor and the acceptor units as well as the functionalization of covalent molecules at the interface. In particular, configurations with the ZnPc molecules facing on C60 facilitate charge transfer between substrate and molecules that occurs within 200 fs. In contrast, configurations where ZnPc is tilted above C60 present extremely low carrier injection efficiency even at longer times as an effect of the larger interfacial potential level offset and higher energetic barrier between the donor and acceptor molecules. An enhancement of charge injection into C60 at shorter times is observed as binding groups connect ZnPc and C60 in a dyad system. Our results demonstrate a promising way of designing and controlling photoinduced charge transfer on the atomic level in organic devices that would lead to efficient carrier separation and maximize device performance.

Face description for perceptual user interfaces

[EN]We investigate mechanisms which can endow the computer with the ability of describing a human face by means of computer vision techniques. This is a necessary requirement in order to develop HCI approaches which make the user feel himself/herself perceived. This paper describes our experiences considering gender, race and the presence of moustache and glasses. This is accomplished comparing, on a set of 6000 facial images, two di erent face representation approaches: Principal Components Analysis (PCA) and Gabor lters. The results achieved using a Support Vector Machine (SVM) based classi er are promising and particularly better for the second representation approach.

Multiple face detection at different resolutions for perceptual user interfaces

[EN]This paper describes in detail a real-time multiple face detection system for video streams. The system adds to the good performance provided by a window shift approach, the combination of different cues available in video streams due to temporal coherence. The results achieved by this combined solution outperform the basic face detector obtaining a 98% success rate for around 27000 images, providing additionally eye detection and a relation between the successive detections in time by means of detection threads.

Hand pose detection for vision-based gesture interfaces

[EN]Vision-based applications designed for humanmachine interaction require fast and accurate hand detection. However, previous works on this field assume different constraints, like a limitation in the number of detected gestures, because hands are highly complex objects to locate. This paper presents an approach which changes the detection target without limiting the number of detected gestures. Using a cascade classifier we detect hands based on their wrists. With this approach, we introduce two main contributions: (1) a reliable segmentation, independently of the gesture being made and (2) a training phase faster than previous cascade classifier based methods. The paper includes experimental evaluations with different video streams that illustrate the efficiency and suitability for perceptual interfaces.

Desenho e implementação de uma plataforma integrada para monitorização e gestão de uma rede de um departamento da UMa

A área da gestão de sistemas e redes tem vindo a alcançar um papel crucial em todas as áreas das Tecnologias de Informação (TI). Com o constante desenvolvimento das redes, em dimensão, inovação tecnológica ou em heterogeneidade, o processo de gestão e monitorização destes sistemas tornou-se cada vez mais exigente e complexo, forçando diversas organizações a investir na implementação ou aquisição de algum software de apoio para os gestores de redes. Com o presente trabalho, pretende-se implementar uma solução integrada para permitir uma gestão preventiva e correctiva dos sistemas da rede informática de um dos departamentos da Universidade da Madeira, denominado por Centro de Competências de Ciências Exactas e da Engenharia (CCCEE). A abordagem a essa solução começa por dar a conhecer alguns dos princípios mais importantes das tradicionais arquitecturas de gestão de redes, e por apresentar um modelo de referência que disponibiliza um conjunto de boas práticas para a gestão de TI. O trabalho continua com o estudo das características da rede informática existente nas instalações do CCCEE, identificando-se não só as reais necessidades na área da gestão e monitorização das TI, como também os principais problemas que a nova solução deveria intervir. A partir destes dados e através de uma análise a um conjunto de ferramentas de gestão e monitorização de redes, selecionou-se a que mais se adequava à realidade do CCCEE. Este trabalho terminou com a monitorização e gestão, contínua e eficiente, das tecnologias de informação do CCCEE, através da implementação da arquitectura de uma solução integrada, de acordo com requisitos e políticas do CCCEE.

Contributo para o Estudo das Propriedades Psicométricas: Teste do Desenho do Relógio numa Amostra da População Portuguesa

Objetivo: Estudar as propriedades psicométricas do Teste do Desenho do Relógio numa amostra da população portuguesa. Método: A amostra é constituída por 749 pessoas (345 homens e 404 mulheres), com idades compreendidas entre os 18 e os 94 anos. Todos os participantes preencheram uma declaração de consentimento informado e uma bateria de testes neuropsicológicos. Resultados: A média no Teste do Desenho do Relógio foi de 4,10 (DP = 1,25). Os resultados demonstraram que as variáveis sociodemográficas (idade, escolaridade, profissão, regiões e tipologia de áreas urbanas) apresentaram ter influência significativa nas pontuações do Teste do Desenho do Relógio. A confiabilidade e a estabilidade temporal revelaram-se adequadas. Conclusão: Os dados do nosso estudo indicam que o Teste do Desenho do Relógio pode ser utilizado pela população portuguesa. / Purpose: To study the psychometric properties of the Clock Drawing Test in a Portuguese sample. Method: The sample consists of 749 people (345 men and 404 women), aged between 18 and 94 years. All participants filled an informed consent form and a battery of neuropsychological tests. Results: The average in Clock Drawing Test was 4.10 (SD = 1.25). The results showed that the sociodemographic variables (age, education, profession, region, and typology of urban areas) showed significant influence on Clock Drawing Test scores. The reliability and temporal stability of Clock Drawing Test proved appropriate. Conclusion: The data from our study indicate that the Clock Drawing Test may be used by the Portuguese population.

Cooperação e competição entre políticas no Brasil: os custos da governabilidade no presidencialismo de coalizão

Public policies have been studied in the various fields of humanities and social sciences, from different theoretical and technical aspects. However, there is still a lack of studies that incorporate the dimension that encompasses the political action and its interference in such actions, also recognizing the importance of the institutional setting of the Brazilian presidential model in implementing these policies. This fragmented and multiparty system has led to power heterogeneous sets of political parties. Thus, the ministerial offices, more than assisting the President´s government project, manage particularized agendas, which are party biased and have the influence of interest groups in hegemonic themes addressed by government agencies. When these agendas operate in sectoral and specialized policies, the friction level is apparently low. However, when this occurs in intersectoral actions, such as in regional development, there is evidence of strong signs of competition among government agencies, which in theory, should operate in an integrated manner. Although this is not a specific feature of Luiz Inacio Lula da Silva´s government- the period to be studied- there was similar behavior in Fernando Henrique Cardoso´s presidency, one realizes that the expansion of coalition on behalf of governance is increasingly interfering in the outcome of intersectoral public policies, due to these multiple arguments in action. In order to understand these processes, this study focused on the Sustainable and Integrated Development Programme for Differentiated Meso-Regions (PROMESO), part of the National Policy for Regional Development (NPRD). The program provides interface with various government agencies and their public policies in a clear intersectoral design. The research sought to identify and analyze the relationships between government agencies and their programs with interest groups, whether political parties or other segments of civil society, highlighting the logic of favoritism, which poses in second place the integration of actions in the intersectoral policies. Therefore, besides the theoretical debate that incorporates several categories of political science, public administration, public policy, geography and economics, the study focused on secondary sources, using different government agencies databases in order to raise information. It was observed that the interference of partisan politics has been disastrous for some public policies. Thus, the research confirms that cooperative character is fragile within government agencies, often limited to official documents, and that there is indeed, a striking feature of competition, especially when it comes to transversalized policies

Stochastic Modeling of Reversible Biochemical Reaction-Diffusion Systems and High-Resolution Shock-Capturing Methods for Fluid Interfaces

Thesis (Ph.D.)--University of Washington, 2016-08

Desenho do real : análise, representação e consciência crítica

O presente relatório reflete sobre o processo de representação pelo desenho de uma forma tridimensional num suporte bidimensional. A intenção deste relatório é analisar e compreender a relação entre o que é analisado pelo cérebro, o que é representado no papel e a consciência crítica do erro praticado no desenho de observação, bem como conhecer como poderá ser desenvolvida esta triangulação (análise, representação e consciência crítica do erro) de modo a melhorar a qualidade da representação do real. A investigação empírica foi realizada na disciplina de Desenho A, no ano letivo de 2012/2013, com duas turmas do 11º ano do Curso de Design de Produto na Escola Artística Soares dos Reis, no Porto. Os resultados obtidos sugerem que a perspetiva, enquanto estratégia, poderá melhorar significativamente a qualidade da representação do real. Todavia, relativamente ao estímulo da consciência crítica do erro através das estratégias abordadas dentro de sala de aula, não ficou comprovada relevância na qualidade das representações.

Ordering induced by chemical, thermal and mechanical constraints at solid interfaces

We know that classical thermodynamics even out of equilibrium always leads to stable situation which means degradation and consequently d sorder. Many experimental evidences in different fields show that gradation and order (symmetry breaking) during time and space evolution may appear when maintaining the system far from equilibrium. Order through fluctuations, stochastic processes which occur around critical points and dissipative structures are the fundamental background of the Prigogine-Glansdorff and Nicolis theory. The thermodynamics of macroscopic fluctuations to stochastic approach as well as the kinetic deterministic laws allow a better understanding of the peculiar fascinating behavior of organized matter. The reason for the occurence of this situation is directly related to intrinsic non linearities of the different mechanisms responsible for the evolution of the system. Moreover, when dealing with interfaces separating two immiscible phases (liquid - gas, liquid -liquid, liquid - solid, solid - solid), the situation is rather more complicated. Indeed coupling terms playing the major role in the conditions of instability arise from the peculiar singular static and dynamic properties of the surface and of its vicinity. In other words, the non linearities are not only intrinsic to classical steps involving feedbacks, but they may be imbedded with the non-autonomous character of the surface properties. In order to illustrate our goal we discuss three examples of ordering in far from equilibrium conditions: i) formation of chemical structures during the oxidation of metals and alloys; ii) formation of mechanical structures during the oxidation of metals iii) formation of patterns at a solid-liquid moving interface due to supercooling condition in a melt of alloy. © 1984, Walter de Gruyter. All rights reserved.

A integração e compreensão do desenho na modelação 3D : enquadramento académico

Na medida em que os produtos e os processos de criação são cada vez mais mediados digitalmente, existe uma reflexão recente acerca da relação entre as imagens e as ferramentas usadas para a sua produção. A relação natural e estreita entre a dimensão conceptual e a dimensão física abre a discussão ao nível da semântica e dos processos da projetação e manipulação das imagens, nas quais estão naturalmente incluídas as ferramentas CAD. Tendo o desenho um papel inequívoco e fundamental no exercício da projetação e da modelação 3D é pertinente perceber a relação e a articulação entre estas duas ferramentas. Reconhecendo o desenho como uma ferramenta de domínio físico capaz de expressar o pensamento que opera a transformação de concepções abstratas em concepções concretas, reconhecê-lo refletido na dimensão virtual através de um software CAD 3D não é trivial, já que este, na generalidade, é processado através de um pensamento cujo contexto é distante da materialidade. Metodologicamente, abordaremos esta questão procurando a verificação da hipótese através de uma proposta de exercício prático que procura avaliar o efeito que as imagens analógicas poderão ter sobre o reconhecimento e operatividade da ferramenta Blender num enquadramento académico. Pretende-se, pois, perceber como o desenho analógico pode integrar o processo de modelação 3D e qual a relação que mantém com quem elas opera. A articulação do desenho com as ferramentas de produção de design, especificamente CAD 3D, permitirá compreender na especialidade a articulação entre ferramentas de diferentes naturezas tanto no processo da projetação quanto na criação de artefactos visuais. Assim como poderá lançar a discussão acerca das estratégias pedagógicas de ensino do desenho e do 3D num curso de Design.

Diffusion de représentations d’itinéraires adaptées aux personnes à mobilité réduite selon les interfaces multimodales des appareils mobiles

L’accessibilité universelle est de nos jours très importante pour nos villes, car elle permet à toute personne, ayant des incapacités physiques ou non, de mener à bien ses activités socio-professionnelles. À travers le monde, plusieurs projets ont vu le jour comme AXS Map à New York ou AccesSIG en France. Au Canada, un projet multidisciplinaire nommé MobiliSIG ayant pour lieu d’expérimentation la ville de Québec a vu le jour en 2013. L’objectif du projet MobiliSIG est de concevoir et développer une application multimodale d’assistance au déplacement des personnes à mobilité réduite. Ce projet se concentre principalement sur la constitution d’une base de données d’accessibilité se référant au modèle PPH (Processus de Production du Handicap). Nos travaux visent à définir la diffusion d’itinéraires adaptés, adaptables et adaptatifs liés à des contextes multi-utilisateurs, multiplateformes, multimodaux (interfaces et transports) et multi-environnements. Après une revue de littérature et afin d’identifier et définir les besoins liés à cette diffusion des données de navigation, nous nous sommes attelés à la description de plusieurs scénarios pour mieux comprendre les besoins des utilisateurs : planification d’un déplacement et navigation dans le milieu urbain ; parcours multimodal ; recherche d’un point d’intérêt (toilettes accessibles). Cette démarche nous a permis également d’identifier les modes de communication et représentations souhaitées de l’itinéraire (carte, texte, image, parole, …) et de proposer une approche basée sur la transformation de l’itinéraire reçu de la base de données d’accessibilité. Cette transformation est effectuée en tenant compte des préférences de l’utilisateur, de son appareil et de son environnement. La diffusion de l’itinéraire se fait ensuite par un service web de diffusion conçu selon le standard du W3C sur les architectures multimodales (MMI) en combinaison avec le concept de la plasticité des interfaces. Le prototype développé a permis d’avoir comme résultat un système qui diffuse de façon générique l’information de navigation adaptée, adaptable et adaptative à l’utilisateur, à son appareil et à son environnement.

A produção do mobiliário urbano nos espaços públicos :o desenho do mobiliário urbano nos projetos de reordenamento das orlas do Rio Grande do Norte

This work aims to analyze and evaluate the Urban furniture designed to public areas according to the Revitalization planning for Rio Grande do Norte coastland, defining visual relations among urban elements in the landscape of revitalized public urban areas with cultural, paisagistic and touristic values and the design process used for developing urban furniture to those areas, observing the incoming consequences use to that process in a specific urban context which alters use, functions, cultural images as well as social values attributed to each particular place. Environmental perceptions, legibility of local cultural references and their representation through the design of urban elements, act in a positive or negative manner over the inhabitants cognition process of some particular revitalized area, determining new use and attributions to those areas. Designs for coastal urban interventions try excessively to standardize technical media, construction materials and planning configurations, creating artificial sceneries that segregates users, imposing new structures and usage, generating, consequently, the so called non-places and burlesque regionalism. The research is divided into 4 chapters: 1) Theoretical support (Industrial design; Urban furniture; Public urban spaces; Urban image and environmental perception; Urban occupation and interventions in coastland areas); 2) Methodological procedures and data collection; 3) Analysis of Rio Grande do Norte coastal areas and their urban interventions; 4) Final considerations and Industrial Design contributions to the subject