Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand

The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.

Green revelations in a country of drought, flood and fire : a case study of Abrahamic faith communities and sustainability

This paper reports research into the levels of awareness and engagement of Abrahamic communities regarding environmental sustainability in the State of Victoria, Australia. Seventeen faith groups were targeted for study at 22 locations throughout Victoria and metropolitan Melbourne; with 15 in-depth interviews completed. The study suggests that personal awareness does not always translate well into group action, resulting in conflicting positions within denominations on how to respond to environmental issues. Some denominations have funding and human resources to support environmental programs. Smaller groups struggle to maintain numbers, are trying to expand, or do not participate because of fundamentally different worldviews.

Production of green nanomaterials

While our awareness towards sustainable society and environment grows, the importance of ‘green’ materials and manufacturing is gaining significant recognition. We have demonstrated that naturally-occurring fibers as renewable raw materials can be converted into nanoparticles and nano fibers using simple top-down methods without introducing hazardous chemicals. This new class of green nanomaterials will have a wide range of environmental and biomedical applications owing to the inherent biocompatible, biodegradable and carbon-neutral nature.

Green planning heritage/industrial nature : the park lands or 'regeneration reserves' of Broken Hill

Freestone (1989+) has extensively surveyed town planning visions and model communities for Australia, but one settlement has been forgotten. The significant mining settlement of Broken Hill in far western New South Wales does not figure in his thematic and historical analyses yet its park lands are so integral to its physical cultural legacy and human health that it warrants enhanced standing. In the last 2 years the Commonwealth has been considering the potential nomination of the municipality of Broken Hill for inclusion onto the National Heritage List principally due to its mining, social and economic contributions to Australia’s heritage and identity. A component in their deliberations is the Park Lands, or ‘Regeneration Reserves’, that encompass this urban settlement and its mine leaseholds. Within these Regeneration Reserves, international arid zone ecological restoration theory and practice was pioneered by Albert and Margaret Morris in the 1930s that serves as the method for all mining revegetation practice in Australia today. This paper reviews the theory and evolution of the Broken Hill Regeneration Reserves, having regard to the Adelaide Park Lands and Garden City discourses of the 1920s-30s, arguing that the Broken Hill Regeneration Reserves have a valid and instrumental position in the planning and landscape architectural histories of Australia.

Predicting changes in lifestyle and clinical outcomes in preventing diabetes : The Greater Green Triangle Diabetes Prevention Project

Objectives : To analyse how psychosocial determinants of lifestyle changes targeted in the Greater Green Triangle Diabetes Prevention Project conducted in Southeast Australia in 2004–2006 predict changes in dietary behaviour and clinical risk factors.

Methods : A longitudinal pre-test and post-test study design was used. The group program was completed by 237 people at high risk of type 2 diabetes. Associations between changes in the variables were examined by structural equation modelling using a path model in which changes in psychological determinants for lifestyle predicted changes in dietary behaviours (fat and fibre intake), which subsequently predicted changes in waist circumference and other clinical outcomes. Standardised regression weights are presented, with β = ± 0.1 and β = ± 0.3 representing small and medium associations, respectively.

Results : Improvements in coping self-efficacy and planning predicted improvements in fat (β = − 0.15, p < 0.05 and β = − 0.32, p < 0.001, respectively) and fibre intake (β = 0.15, p < 0.05 and β = 0.23, p < 0.001, respectively) which in turn predicted improvements in waist circumference (β = 0.18, p < 0.01 and β = − 0.16, p < 0.05, respectively). Improvements in waist circumference predicted improvements in diastolic blood pressure (β = 0.13, p < 0.05), HDL (β = − 0.16, p < 0.05), triglycerides (β = 0.17, p < 0.01), and fasting glucose (β = 0.15, p < 0.05).

Conclusions : Psychological changes predicted behaviour changes, resulting in 12-month biophysical changes. The findings support the theoretical basis of the interventions.

Changing green subjectivities in outdoor and environmental education : a qualitative study

This article draws on a longitudinal qualitative study of Australian tertiary students studying Outdoor and Environmental Education. It draws on the work of Foucault and Darier to consider how ‘environmental governmentality’ shapes the conduct, desires and attitudes of these students over time. Attention is drawn to normalising and disciplinary effects of mainstream environmental discourse alongside an exploration of some of the inconsistencies and ruptures in how participants interact with discourses of environmentalism.

New 'green' corrosion inhibitors based on rare earth compounds

A series of rare earth organic compounds pioneered by our group have been shown to provide a viable alternative to theuse of chromates as corrosion inhibitors for some steel and aluminium applications. For example we have shown thatthe lanthanum 4-hydroxy cinnamate offers excellent corrosion mitigation for mild steel in aqueous environments whilerare earth diphenyl phosphates offer the best protection in the case of aluminium alloys. In both cases the protectionappears to be related to the formation of a nanometre thick interphase occurring on the surface that reduces theelectrochemical processes leading to metal loss or pitting. Very recent work has indicated that we may even be able toaddress the challenging issue of stress corrosion cracking of high strength steels. Furthermore, filiform corrosion can besuppressed when selected rare earth inhibitor compounds are added as pigments to a polymer coating. There is little doubtfrom the work thus far that a synergy exists between the rare earth and organic inhibitor components in these novelcompounds. This paper reviews some of the published research conducted by the senior author and colleagues over the past10 years in this developing field of green corrosion inhibitors