984 resultados para Amine, Sam


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The proximate composition of the high temperature processed fish sausage was found to be 14.56% protein, 4.65% fat, 69.14% moisture, 2.12% ash and 8.12% carbohydrate. The quality of the product during storage was assessed on the basis of the changes observed in the physical, chemical and microbiological parameters. The results of the different tests such as pH, volatile base nitrogen (VBN), trimethyl amine nitrogen (TMA-N) and jelly strength are summarized and discussed. The total bacterial load increased gradually during storage but was not proportional to the initial load.

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某些蛋白翻译水平的激活和抑制对胚胎发育过程中基因表达起到重要的时空调节作用.在果蝇中,Bicaudal-c(dBic-C)基因产物被认为是一种能与RNA结合的蛋白质分子,并对转录后水平具有重要的调节作用.dBic-C基因的突变会导致果蝇缺失头部结构和重复的尾部结构,故而命名为双尾-C基因.后来又在多个不同物种(如线虫、爪蟾、小鼠)中发现dBic-C的同源基因,并且这些同源基因的蛋白质产物高度保守.小鼠的Bicaudal-C基因(Biccl)定位于10号染色体的C1区域,其蛋白质N端含有KH结构域,用于介导蛋白质与RNA的相瓦作用;C端的SAM结构域则在蛋白质与蛋白质相互结合中发挥作用.目前已发现3种与Biccl基因相关的小鼠突变体模型jcpk、bpk和67Gso,这些小鼠突变体中Biccl基因在不同位点发生突变,产生异常的蛋白质产物,结果导致小鼠肾脏发生胞囊化,并且影响身体其他器官的正常形态及功能,病理表型特征与人类的多囊肾病(polycystic kidney disease,PKD)极为相似.本文通过总结和同顾Bicaudal-C基因研究的成果和进展,揭示该基因在生物体发育和器官形成中的作用,为深入研究这一基因的生物学功能奠定基础.

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Eight Black-necked Cranes(Grus nigricollis)were banded with satellite transmitters in the spring of 2005 and 2006 at Dashanbao in Yunnan and Caohai in Guizhou.Six of the banded cranes completed at least one migration between their wintering and breeding grounds.Townships where these birds stopped over include:Wusihe,Henan,Nimei,Liyuan,Yidong,Sanjiaoping,and Huangmu in Hanyuan County,and Liuhong,Yiguojie,Nongzuo,Lamuajue,Bingtu,Wagu,Equgulongmen,and Niha in Meigu County.We surveyed stop-over sites in Hanyuan...

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The purpose of inlake herbicide trials was to assess on the aquatic environment and resources, of in-lake of weeder 64 (2,4-0 amine) and Rodio (Glyphosate) water hyacinth the effects application to control water hyacinth. The experiments reported here specifically studied the effects of the herbicides on the diversity and abundance of aquatic macrofauna associated with the water weed. Results from this and similar experiments which assessed herbicide efficacy on water hyacinth; dissipation in water, impact on water quality, algal biomass and on diversity and abundance of zooplankton and macrofauna were all to be evaluated as input into the environmental impact assessment exercise required to facilitate decisions on the use of herbicides to control water hyacinth in Uganda.

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Passive mode locking of a solid-state Nd:GdVO4 laser is demonstrated. The laser is mode locked by use of a semiconductor absorber mirror (SAM). A low Nd3+ doped Nd:GdVO4 crystal is used to mitigate the thermal lens effect of the laser crystal at a high pump power. The maximum average output power is up to 6.5 W, and the pulse duration is as short as 6.2 ps. The optic-to-optic conversion efficiency is 32.5% and the repetition rate is about 110 MHz.

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A high-power continuous wave (cw) mode-locked Nd:YVO4 solid-state laser was demonstrated by use of a semiconductor absorber mirror (SAM). The maximum average output power was 8.1 W and the optic-to-optic conversion efficiency was about 41 %. At the maximum incident pump power, the pulse width was about 8.6 ps and the repetition rate was 130 MHz. Experimental results indicated that this absorber was suitable for high power mode-locked solid-state lasers. (C) 2006 Elsevier Ltd. All rights reserved.

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本论文共合成了两种类型12个稀土金属配合物和一个硅化合物,分别对它们进行了红外、核磁等表征,对其中的9个配合物进行了晶体结构的测定。考察了配体结构和反应条件对所生成的配合物结构的影响,研究了稀土单烷基配合物的反应性,以及稀土双烷基配合物在烷基铝和有机硼盐的共同作用下对丁二烯聚合的催化活性和选择性。主要工作内容和结论如下: (1) 合成了噻吩苯胺配体(HL1),该配体与(Lu,Y)稀土三烷基化合物反应,通过C–H活化和烷基消除反应制备了稀土(Lu,Y)单烷基配合物1和2,配体以少见的C,N模式配位,S原子并不参与配位。配体(HL1)与Sc三烷基化合物反应制备了配体分别以C, N和N, S配位的双配的Sc配合物5。 (2) 通过改变反应时间和溶剂体系,HL1与稀土钇三烷基化合物反应可得到罕见的由稀土烷基化物和胺化物两部分组成的配合物3,它们通过噻吩环上活化的C原子连接在一起。HL1和Lu(CH2SiMe3)2(THF)2LiCH2SiMe3在甲苯和正己烷溶剂中反应可得到以L12Lu(CH2SiMe3)2为阴离子,Li(THF)4为阳离子的离子对4。 (3) 研究配合物1和2的反应性。1和2与过量的PhSiH3反应得到中心金属与Si元素交换的Si化合物。 (4) 合成了噻吩苯基膦胺配体(HL2-4)和苯基膦胺配体(HL5)配体。HL2-5与稀土(Y, Lu和Sc)三烷基化合物反应制备了稀土双烷基配合物6,7,8,9,10,11和12。进一步研究了稀土金属双烷基配合物6–12对丁二烯的催化特性,发现该系列催化剂具有独特的催化性质,能够催化丁二烯高反1,4-聚合(91.3%),得到的聚合物分子量在1到2万之间,分子量分布较窄(1.4–1.6)。 (5) 研究了金属钇(Y),镥(Lu),钪(Sc)三种中心金属对丁二烯聚合活性和反式1,4选择性的影响,发现催化剂对丁二烯聚合活性和反1,4选择性取决于配合物的中心金属原子,其中选择性最高为钪配合物,催化活性最佳的为钇配合物。 (6) 研究了配体HL2-4的N-芳环上的取代基分别为甲基,乙基,异丙基时催化体系对丁二烯反式1,4聚合活性和选择性的影响,发现随着N-芳环上取代基空间位阻的增大,催化剂活性逐渐下降,选择性逐渐增加,但当其取代基为异丙基时,过大的空间位阻导致活性和选择性同时有明显的下降。我们通过改变噻吩基为苯基,比较了相同聚合条件下含噻吩基的稀土双烷基配合物和含苯基的稀土双烷基配合物对丁二烯聚合活性和选择性的影响,发现噻吩环的存在对催化剂的活性和选择性有较大的影响。 (7) 在相同催化剂条件下,研究了不同聚合条件(不同类型的AlR3,不同类型的Borate,Al/Ln比等)对丁二烯反1,4聚合活性和选择性的影响。 我们发现,在AlR3和Borate这两种影响因素中,以烷基铝的类型对催化剂催化活性和选择性的影响最大,而有机硼盐的影响则比较轻微,其中以烷基铝为AliBu3,Borate为[B(C6F5)4][Me2NHPh]时,反1,4选择性为最佳。Al/Ln增大并不能够显著增加催化剂的活性,对选择性的影响也并不明显,相反,随着铝比的增加,聚合过程中的链转移增加,导致分子量下降,对于该系列稀土烷基催化剂,最佳Ln/Al 为10。