949 resultados para Ttt Diagram


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We present the experimental phase diagram of LiHoxEr1-xF4, a dilution series of dipolar-coupled model magnets. The phase diagram was determined using a combination of ac susceptibility and neutron scattering. Three unique phases in addition to the Ising ferromagnet LiHoF4 and the XY antiferromagnet LiErF4 have been identified. Below x = 0.86, an embedded spin-glass phase is observed, where a spin glass exists within the ferromagnetic structure. Below x = 0.57, an Ising spin glass is observed consisting of frozen needlelike clusters. For x ∼ 0.3–0.1, an antiferromagnetically coupled spin glass occurs. A reduction of TC(x) for the ferromagnet is observed which disobeys the mean-field predictions that worked for LiHoxY1-xF4.

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In 1937 the "Meteor" performed the cruises of the first part of the "Deutsche Nordatlantische Expedition". This publication treats seven stations of three-day-anchoring occupied during that time, five of which are located on the shelf, one on the continental slope and one on a ridge between the Capverde islands. The Bohnecke current meter, an instrument developed for the expedition, is described briefly and it's accuracy studied by comparing the measurements of two instruments which operated simultaneously at the same depth. It is shown that it is very sensitive for movements of the anchored ship because of the very short measuring intervall (2 minutes). The influence of the ship's movements could not be eliminated completely, the mode of using the instrument at different depths being unsuitable for this. Considering the stratification the accuracy of it's representation by the mean temperature and salinity distributionis studied. It is shown that under certain conditions a distribution estimated from observed values gives more exact results. This especially applies to the TS-diagram. Station Meteor336, located on the shelf near Cape Juby, shows temperatures 4 °C less than the open ocean and so belongs to the area of upwelling. During the observation period, however, internal tides are prominent. The diurnal component is of considerable influence, the distinction from inertial oscillations (25.5 hours) not being possible, however. Station Meteor341, on the shelf off Spanish-Sahara, gives an excellent example of the movements in the centre of the area of upwelling. Changing it's direction by 45° at the beginning of the measurements, the wind causes a change of current direction at all depths which, after some inertial oscillations (period 28.3 hours), settles down to a final value. At the beginning and the end of the observations the current at the upper depths is directed off-shore, the angle between current and wind being 22°, while at the lower depths it is orientated towards the shore. The depth of the upper homogenous layer gives the origin of the water transported upwards When during the inertial oscillations the current goes offshore at all depths temporarily, a sudden disturbance occurs in the temperature measurements. Station Meteor311 is located similar to station Meteor341 but was occupied one month earlier. At that time the wind situation was unnormal, the usual wind direction of 45° occuring at the end of the station. Therefore an unnormally high vertical shear of current speed and direction has been observed, the current vector being directed off-shore at the surface and near the bottom, towards the coast inbetween. The TS-diagram shows that the bottom water is replaced first so that upwelling does not occur during observation time. The state reached at the end of the station does not seem to be stable. Station Meteor369, on the continental slope, is governed by internal waves. Besides the internal tide of 12.4 hours a wave of 6.5 hour period is observed, being possibly amplified by the large bottom slope. In 40 - 60 m depth, where the thermocline is located, a wave with 3.3 hour period is observed which is argued to be an internal boundary wave. Station Meteor334 is located on the shelf NW of the mouth of the Senegal river. A marked temperature stratification, associated with large disturbances, and nearly constant salinity have been found there. The current was going slowly towards S or SW in the upper 20 - 30 m, towards N underneath. At the boundary of the current systems intense turbulence developed,including as it seems a water type of less salinity which is transported from the Senegal river by the lower current. Station Meteor327, located at 100 m depth between two of the Capverde islands, shows oceanic characteristics. The semidiurnal tide is found mainly, the diurnal component having considerable influence. Furtheron an internal wave of 6 hour period is seen the maximum amplitude of which is moving slowly downwards. Two possibilities of explaining it are discussed. Station Meteor366 is found in the area of ceasing winds off the coast of upper Guinea. The temperature there depends strongly on the depth, the salinity being nearly constant. The currents are divided into an upper and a lower system with large variations in both of them. A change of wind direction of nearly 90° is supposed to be the reason. The variations in salinity accordingly are interpreted as the influence of fresh water outflow from land which is felt in a different way at different wind directions. In the last section the daily changes in air and water temperature are studied. The upwelling having large influence on these, a centre of the area of upwelling can be located at about 100 miles north of Cape Blanc (Station Meteor311). The semidiurnal tidal component is compared with previous results for the Atlantic Ocean yielding considerable differences for the direction and time of occurence of the current maximum which might be due to the topographical influences around the shelf.

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Let S be a set of n + m sites, of which n are red and have weight wR, and m are blue and weigh wB. The objective of this paper is to calculate the minimum value of wR such that the union of the red Voronoi cells in the weighted Voronoi diagram of S is a connected set. The problem is solved for the multiplicatively-weighted Voronoi diagram in O((n+m)^2 log(nm)) time and for the additively-weighted Voronoi diagram in O(nmlog(nm)) time.

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he composition, strain and surface morphology of (0001)InGaN layers are investigated as a function of growth temperature (460–645 °C) and impinging In flux. Three different growth regimes: nitrogen-rich, metal-rich and intermediate metal-rich, are clearly identified and found to be in correlation with surface morphology and strain relaxation. Best epilayers’ quality is obtained when growing under intermediate metal-rich conditions, with 1–2 monolayers thick In ad-coverage. For a given In flux, the In incorporation decreases with increasing growth temperature due to InN thermal decomposition that follows an Arrhenius behavior with 1.84±0.12 eV activation energy.

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The structural state and static and dynamic magnetic properties of TbCu2 nanoparticles are reported produced by mechanical milling under inert atmosphere. The core magnetic structure retains the bulk antiferromagnetic arrangement. The overall interpretation is based on a superantiferromagnetic behavior which at low temperatures coexists with a canting of surface moments and mismatch of antiferromagnetic sublattices of the nanoparticles.

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Single-molecule force spectroscopy reveals unfolding of domains in titin on stretching. We provide a theoretical framework for these experiments by computing the phase diagrams for force-induced unfolding of single-domain proteins using lattice models. The results show that two-state folders (at zero force) unravel cooperatively, whereas stretching of non-two-state folders occurs through intermediates. The stretching rates of individual molecules show great variations reflecting the heterogeneity of force-induced unfolding pathways. The approach to the stretched state occurs in a stepwise “quantized” manner. Unfolding dynamics and forces required to stretch proteins depend sensitively on topology. The unfolding rates increase exponentially with force f till an optimum value, which is determined by the barrier to unfolding when f = 0. A mapping of these results to proteins shows qualitative agreement with force-induced unfolding of Ig-like domains in titin. We show that single-molecule force spectroscopy can be used to map the folding free energy landscape of proteins in the absence of denaturants.

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The phase diagram of soft spheres with size dispersion is studied by means of an optimized Monte Carlo algorithm which allows us to equilibrate below the kinetic glass transition for all size distributions. The system ubiquitously undergoes a first-order freezing transition. While for a small size dispersion the frozen phase has a crystalline structure, large density inhomogeneities appear in the highly disperse systems. Studying the interplay between the equilibrium phase diagram and the kinetic glass transition, we argue that the experimentally found terminal polydispersity of colloids is a purely kinetic phenomenon.

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Glass, Roman; 9 29/64 in. x 6 31/32 in.