Novel photocatalytic reactor development for removal of hydrocarbons from water

Hydrocarbons contamination of the marine environment generated by the offshore oil and gas industry is generated from a number of sources including oil contaminated drill cuttings and produced waters. The removal of hydrocarbons from both these sources is one of the most significant challenges facing this sector as it moves towards zero emissions. The application of a number of techniques which have been used to successfully destroy hydrocarbons in produced water and waste water effluents has previously been reported. This paper reports the application of semiconductor photocatalysis as a final polishing step for the removal of hydrocarbons from two waste effluent sources. Two reactor concepts were considered: a simple flat plate immobilised film unit, and a new rotating drum photocatalytic reactor. Both units proved to be effective in removing residual hydrocarbons from the effluent with the drum reactor reducing the hydrocarbon content by 90% under 10 minutes. 

Análise da resistência à fadiga de tubos de aço API 5CT N80 Tipo Q soldados via processo de indução magnética de alta frequência (HFIW)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Sedimentology and stratigraphy of the Lower Silurian Grimsby formation, in subsurface, Lake Erie and Southwestern Ontario

Since the first offshore Lake Erie well was drilled in 1941, the Grimsby and Thorold formations of the Cataract Group have been economically important to the oil and gas industry of Ontario. The Cataract Group provides a significant amount of Ontario's gas production primarily from wells located on Lake Erie. The Grimsby - Thorold formations are the result of nearshore estuarine processes influenced by tides on a prograding shelf and are composed of subtidal channel complexes, discrete tidal channels, mud flats and non-marine deposits. Deposition was related to a regressive - transgressive cycle associated with eustatic sea level changes caused by the melting and resurgence of continental glaciation centred in Africa in the Late Ordovician/Early Silurian. Grimsby deposition began during a regression with the deposition of subtidal channel complexes incised into the marine deposits of the Cabot Head Formation. The presence of mud drapes and mud couplets suggest that these deposits were influenced by tides. These deposits dominate the lower half of the Grimsby. Deposition continued with a change from these subtidal channel complexes to laterally migrating, discrete, shallow tidal channels and mud flats. These were in turn overlain by the non-marine deposits of the Thorold Formation. Grimsby - Thorold deposition ended with a major transgression replacing siliciclastic deposition with primarily carbonate deposition. Sediment was sourced from the east and southeast and associated with a continuation of the Taconic Orogeny into the Early Silurian. The fluvial head of the estuary prograded from a shoreline that was located in western New York and western Pennsylvania running NNE-SSW and then turning NW-SE and paralleling the present day Lake Erie shoreline. iii The facies attributed to the Grimsby - Thorold formations can be ascribed to the three zones within the tripartite zonation suggested by Dalrymple et ale (1992) for estuaries, that is, a marine-dominated facies, a mixed energy facies, and a facies that is dominated by fluvial processes. Also, sediments within the Grimsby - Thorold are commonly fining upwards sequences which are common in estuarine settings whereas deltaic deposits are normally composed of coarsening upwards sequences in a vertical wedge shape with coarser material near the head. The only coarsening observed was in the Thorold Formation and attributed to non-marine deposition by palynological evidence. The presence of a lag deposit at the base of the sediments of the Grimsby Thorold formations suggests that they were incised into the Cabot Head Formation. Further, the thickness of Early Silurian sediments located between the top of the Queenston Formation, where Early Silurian sedimentation began, to the top of the Reynales - Irondequoit formation are constant whether the Grimsby - Thorold formations are present or not. Also, cross-sections using a sand body located in the Cabot Head Formation for correlation further imply that the Grimsby Formation has been incised into the previous deposits of the Cabot Head.

Análisis del sistema de gestión ambiental de Occidental de Colombia Inc

El sector de Energía y Gas, del cuál hace parte Occidental de Colombia, ha sido uno de los pioneros en el desarrollo de Sistemas de Gestión Ambiental propios en nuestro país, mediante los cuales cumplen con la legislación ambiental

Natural resources, redistribution and Human capital formation

How do resource booms affect human capital accumulation? We exploit time and spatial variation generated by the commodity boom across local governments in Peru to measure the effect of natural resources on human capital formation. We explore the effect of both mining production and tax revenues on test scores, finding a substantial and statistically significant effect for the latter. Transfers to local governments from mining tax revenues are linked to an increase in math test scores of around 0.23 standard deviations. We find that the hiring of permanent teachers as well as the increases in parental employment and improvements in health outcomes of adults and children are plausible mechanisms for such large effect on learning. These findings suggest that redistributive policies could facilitate the accumulation of human capital in resource abundant developing countries as a way to avoid the natural resources curse.

Framing fracking: which frames are heard in English planning and environmental policy and practice?

Fracking in England has been the subject of significant controversy and has sparked not only public protest but also an associated framing war with differing social constructions of the technology adopted by different sides. This article explores the frames and counter-frames which have been employed by both the anti-fracking movement and by government and the oil and gas industry. It then considers the way in which the English planning and regulatory permitting systems have provided space for these frames within the relevant machinery for public participation. The article thus enables one to see which frames have been allowed a voice and which have been excluded.

Australia and East Timor : elitism, pragmatism and the national interest

For over two decades the issue of East Timor's right to self-determination has been a ‘prickly’ issue in Australian foreign policy. The invasion by Indonesian forces in 1975 was expected, as Australian policy-makers had been well informed of the events leading up to the punitive action being taken. Indeed, prior discussions involving the future of the territory were held between the Australian Prime Minister and the Indonesian President in 1974. In response to the events unfolding in the territory the Australian Labor Government at the time was presented with two policy options for dealing with the issue. The Department of Defence recommended the recognition of an independent East Timor; whereas the Department of Foreign Affairs proposed that Australia disengage itself as far as possible from the issue. The decision had ramifications for future policy considerations especially with changes in government. With the Department of Foreign Affairs option being the prevailing policy what were the essential ingredients that give explanation for the government's choice? It is important to note the existence of the continuity and cyclical nature of attitudes by Labor governments toward Indonesia before and after the invasion. To do so requires an analysis of the influence ‘Doc’ Evatt had in shaping any possible Labor tradition in foreign policy articulation. The support given by Evatt for the decolonisation of the Netherlands East Indies (Indonesia) gave rise to the development of a special relationship-so defined. Evidence of the effect Evatt had on future Labor governments may be found in the opinions of Gough Whitlam. In 1975 when he was Prime Minister, Whitlam felt the East Timor issue was merely the finalisation of Indonesia's decolonisation honouring Evatt's long held anti-colonialist tradition existing in the Australian Labor Party. The early predisposition toward Indonesia's cohesiveness surfaced again in the Hawke and Keating Labor governments of later years. It did not vary a great deal with changes in government The on-going commitment to preserving and strengthening the bilateral relationship meant Indonesia's territorial integrity became the focus of the Australian political elites’ regional foreign policy determinations. The actions taken by policy-makers served to promote the desire for a stable region ahead of independence claims of the East Timorese. From a realist perspective, the security dilemma for Australian policy-makers was how to best promote regional order and stability in the South East Asian region. The desire for regional cohesiveness and stability continues to drive Australian political elites to promote policies that gives a priority to the territorial integrity of regional states. Indonesia, in spite of its diversity, was only ever thought of as a cohesive unitary state and changes to its construct have rarely been countenanced. Australia's political elite justifications for this stance vacillate between strategic and economic considerations, ideological (anti-colonialism) to one of being a pragmatic response to international politics. The political elite argues the projection of power into the region is in Australia’s national interest. The policies from one government to the next necessarily see the national interest as being an apparent fixed feature of foreign policy. The persistent fear of invasion from the north traditionally motivated Australia's political elite to adopt a strategic realist policy that sought to ‘shore up’ the stability, strength and unity of Indonesia. The national interest was deemed to be at risk if support for East Timorese independence was given. The national interest though can involve more than just the security issue, and the political elite when dealing with East Timor assumed that they were acting in the common good. Questions that need to be addressed include determining what is the national interest in this context? What is the effect of a government invoking the national interest in debates over issues in foreign policy? And, who should participate in the debate? In an effort to answer these questions an analysis of how the ex-foreign affairs mandarin Richard Woolcott defines the national interest becomes crucial. Clearly, conflict in East Timor did have implications for the national interest. The invasion of East Timor by Indonesia had the potential to damage the relationship, but equally communist successes in 1975 in Indo-China raised Australia's regional security concerns. During the Cold War, the linking of communism to nationalism was driving the decision-making processes of the Australian policy-makers striving to come to grips with the strategic realities of a changing region. Because of this, did the constraints of world politics dominated by Cold War realities combined with domestic political disruption have anything to do with Australia's response? Certainly, Australia itself was experiencing a constitutional crisis in late 1975. The Senate had blocked supply and the Labor Government did not have the funds to govern. The Governor-General by dismissing the Labor Government finally resolved the impasse. What were the reactions of the two men charged with the responsibility of forming the caretaker government toward Indonesia's military action? And, could the crisis have prevented the Australian government from making a different response to the invasion? Importantly, and in terms of economic security, did the knowledge of oil and gas deposits thought to exist in the Timor Sea influence Australia's foreign policy? The search for oil and gas requires a stable political environment in which to operate. Therefore for exploration to continue in the Timor Sea Australia must have had a preferred political option and thoughts of with whom they preferred to negotiate. What was the extent of each government's cooperation and intervention in the oil and gas industry and could any involvement have influenced the Australian political elites’ attitude toward the prospect of an independent East Timor? Australia's subsequent de jure recognition that East Timor was part of Indonesia paved the way for the Timor Gap (Zone of Cooperation) Treaty signing in 1989. The signing underpinned Australia's acceptance of Indonesian sovereignty over East Timor. The outcome of the analysis of the issues that shaped Australia's foreign policy toward East Timor showed that the political elite became locked into an integration model, which was defended by successive governments. Moreover, they formed an almost reflexive defence of Indonesia both at the domestic and international level.

Carbon dioxide corrosion inhibition : an overview of recent research on new inhibitor development

Since the introduction of inhibitors to the oil and gas industry in the 1940’s, corrosion inhibition has played a key role in carbon dioxide (CO2) corrosion control. Major inhibitor discoveries occurred from the late 1940's to the late 1960's, followed by the refinement of formulations and the development of improved application methods. Over the past two to three decades, although some new derivatives of existing inhibitors such as amide, amine and imidazoline have been reported, there have been few if any discoveries of new CO2 corrosion inhibitors. In recent years, the development of environmentally friendly inhibitors and the inhibition of localised corrosion have become driving forces behind new advances in corrosion inhibitor technology. Recently a rare earth metal organic compound, lanthanum 4-hydroxy cinnamate has been found to be an efficient corrosion inhibitor for mild steel in CO2 containing aqueous media. A resorcinarene acid has been found to provide effective localised corrosion inhibition by promoting a random distribution of insignificant anodic currents. The advent of advanced scanning probe techniques and an electrochemical integrated multi-electrode array have facilitated the discovery of corrosion inhibitors. This paper provides a brief overview of recent progress in this field.

Studying the cathodic disbondment of coatings using electrochemical impedance spectroscopy

The disbondment of protective organic coatings is a widely reported pipeline coating failure mode in the oil and gas industry. Traditional methods of evaluating cathodic disbondment of pipeline coatings are based on visual inspection of pipeline conditions, and laboratory testing of cathodic disbondment resistance (CDR) using standard methods such as ASTM G8. Although some other laboratory-based techniques, such as scanning kelvin probe and scanning acoustic microscopy have been used to study the cathodic disbondment (CD) of coatings, these are often difficult to apply in practical testing. Over the past decade, electrochemical impedance spectroscopy (EIS) has been employed as a potential method for measuring CD. This paper reports preliminary results from an EIS study designed to characterise CD behaviour of epoxy coatings under excessive cathodic protection. EIS data correlated well with the area of disbonded coating. Analysis of EIS data can provide valuable information on the initiation and rates of CD.

Aspectos sócio-econômicos dos códigos de conduta de responsabilidade social (CRS) do setor de gás e petróleo

A presença de uma empresa internacionalmente significa também a disseminação mundial de seu Código de Conduta de Responsabilidade Social (Código de CRS). É portanto necessário um certo controle do conteúdo desses Códigos. As regras e padrões internacionais podem desempenhar este papel. O setor de gás e petróleo causa grande impacto nas comunidades em que as empresas exercem suas atividades. O mesmo se pode afirmar em relação aos seus Códigos de CRS. Este estudo examina, então, duas vertentes distintas mas convergentes. De um lado, o estudo comparativo de como os Códigos de CRS das empresas do setor de gás e petróleo tratam dos aspectos sócio-econômicos. De outro, examina-se a conformidade ou falta de conformidade dos Códigos de CRS com os tratados, convenções, normas e padrões internacionais. Estratégias podem então ser propostas ao setor de gás e petróleo, para a melhoria dos padrões sócio-econômicos de seus Códigos de CRS. Com isso atende-se às necessidades das comunidades envolvidas e, também, cria-se valor para as empresas do setor de gás e petróleo.

Aspectos sociais: códigos de conduta do setor de gás e petróleo

A presença de uma empresa internacionalmente significa também a disseminação mundial de seu Código de Conduta de Responsabilidade Social (Código de CRS). É portanto necessário um certo controle do conteúdo desses Códigos. As regras e padrões internacionais podem desempenhar este papel. O setor de gás e petróleo causa grande impacto nas comunidades em que as empresas exercem suas atividades. O mesmo se pode afirmar em relação aos seus Códigos de CRS. Este estudo examina, então, duas vertentes distintas mas convergentes. De um lado, o estudo comparativo de como os Códigos de CRS das empresas do setor de gás e petróleo tratam dos aspectos sociais. De outro, examina-se a conformidade ou falta de conformidade dos Códigos de CRS com os tratados, convenções, normas e padrões internacionais. Estratégias podem então ser propostas ao setor de gás e petróleo, para a melhoria dos padrões sociais de seus Códigos de CRS. Com isso atende-se às necessidades das comunidades envolvidas e, também, cria-se valor para as empresas do setor de gás e petróleo.

Opções reais: exemplo de aplicação para avaliação de reservas petrolíferas

Este trabalho teve como objetivo incluir flexibilidades gerenciais (tais como técnicas de injeção de gás e água) na avaliação de reservatórios. Concluimos que esta técnicas podem aumentar o valor dos reservatórios em até 25% segundo a teoria de opções reais. A principal vantagem da metodologia de teoria de opções face a tradicional técnica de fluxo de caixa descontado é levar em conta as questões operacionais da indústria do petróleo. Utilizamos dois modelos clássicos para a precificação de reservatórios de petróleo, e aplicamos uma análise de sensibilidade para determinarmos quais fatores são mais relevantes no seu valor econômico. Como era de se esperar em ambos os modelos, o tempo de concessão, bem como a taxa de convenience e/ou dividend yield foram os fatores mais importantes.

Aspectos humanos e trabalhistas: códigos de conduta do setor de gás e petróleo

A presença de uma empresa internacionalmente significa também a disseminação mundial de seu Código de Conduta de Responsabilidade Social (Código de CRS). É portanto necessário um certo controle do conteúdo desses Códigos. As regras e padrões internacionais podem desempenhar este papel. O setor de gás e petróleo causa grande impacto nas comunidades em que as empresas exercem suas atividades. O mesmo se pode afirmar em relação aos seus Códigos de CRS. Este estudo examina, então, duas vertentes distintas mas convergentes. De um lado, o estudo comparativo de como os Códigos de CRS das empresas do setor de gás e petróleo tratam dos humanos e trabalhistas. De outro, examina-se a conformidade ou falta de conformidade dos Códigos de CRS com os tratados, convenções, normas e padrões internacionais. Estratégias podem então ser propostas ao setor de gás e petróleo, para a melhoria dos direitos humanos e trabalhistas de seus Códigos de CRS. Com isso atende-se às necessidades das comunidades envolvidas e, também, cria-se valor para as empresas do setor de gás e petróleo.

Oficiais da Marinha Mercante: um estudo sobre os fatores contribuintes para a evasão nos anos iniciais da carreira embarcada

A indústria de transporte marítimo brasileira passa por um momento de forte expansão decorrente, entre outros fatores, de políticas governamentais que incentivam a construção, nos estaleiros nacionais, de navios para serem utilizados em apoio às atividades da indústria de óleo e gás. Ao mesmo tempo, para complementar a frota brasileira, as empresas petroleiras demandam a contratação de grande quantidade de navios estrangeiros para apoiar as suas operações. Este quadro de crescimento da frota, observado, particularmente, nos últimos 10 anos, contrasta com a escassez de mão de obra qualificada para tripular as embarcações, de modo especial dos Oficiais da Marinha Mercante (OMM). Acentuando o contraste, o Conselho Nacional de Imigração editou a Resolução Normativa n° 72/2006, determinando às empresas de navegação, que operam barcos de bandeira estrangeira, a contratação de proporções mínimas de tripulantes brasileiros, após 90 dias contínuos de operação no país. Além disso, estudos encomendados pelo Sindicato dos Armadores, SYNDARMA, apontam que a taxa de evasão dos OMM, nos anos iniciais da carreira embarcada, é de cerca de trinta por cento. Assim, o presente estudo, a partir de uma revisão bibliográfica acerca da história da Marinha Mercante brasileira, da cultura brasileira, da motivação, dos conflitos família-trabalho, do trabalho em espaço confinado e da rotatividade, se desenvolveu em uma pesquisa exploratória e de campo, por meio de entrevistas pessoais, analisadas à luz da técnica da análise de conteúdo, com profissionais de reconhecida experiência com o tema, além de OMM, com o objetivo de identificar os fatores contribuintes para a evasão dos OMM nos anos iniciais da carreira embarcada. Como resultado, o estudo mostrou que os agentes motivadores intrínsecos e extrínsecos agem continuamente direcionando o comportamento dos OMM para a permanência ou saída da carreira embarcada. Nessa alternância de forças psicológicas e comportamentais, associadas à motivação, influenciam no processo decisório as alternativas existentes representadas pelas oportunidades de emprego oferecidas aos OMM, os conflitos trabalho-família e a dificuldade de adaptação ao trabalho em ambiente confinado. No caso dos OMM, do gênero feminino, a situação é ainda mais sensível, pois enfrentam dificuldades para conciliar a vida embarcada com o papel de mãe e esposa. Portanto, a motivação para a permanência ou saída da carreira embarcada está fortemente relacionada à busca pela realização das expectativas pessoais e ao desejo de equilibrar vida pessoal com a profissional.