Langmuir turbulence and surface heating in the ocean surface boundary layer

This study uses large-eddy simulation to investigate the structure of the ocean surface boundary layer (OSBL) in the presence of Langmuir turbulence and stabilizing surface heat fluxes. The OSBL consists of a weakly stratified layer, despite a surface heat flux, above a stratified thermocline. The weakly stratified (mixed) layer is maintained by a combination of a turbulent heat flux produced by the wave-driven Stokes drift and downgradient turbulent diffusion. The scaling of turbulence statistics, such as dissipation and vertical velocity variance, is only affected by the surface heat flux through changes in the mixed layer depth. Diagnostic models are proposed for the equilibrium boundary layer and mixed layer depths in the presence of surface heating. The models are a function of the initial mixed layer depth before heating is imposed and the Langmuir stability length. In the presence of radiative heating, the models are extended to account for the depth profile of the heating.

O mercado de futuros no Brasil: teoria, organização, produtos e práticas operacionais

Nada mais atrativo no mundo empresarial do que fazer dinheiro. Mas nada mais custoso nesse universo do que desconhecer a importância econômica dos derivativos. Os instrumentos financeiros desse mercado possibilitam aos responsáveis pela administração dos riscos comercial e monetário de instituições financeiras e as empresas de produção de bens reais transferirem as incertezas de resultados futuros àqueles que desejam especular com essa possibilidade. O mercado de derivativos consiste na negociação de contratos baseados no resultado de ativos reais ou financeiros, bem como nas taxas de juro, câmbio e índices. Como as relações negociais dos derivativos estão baseadas em contratos, as partes - comprador e vendedor - têm compromissos entre si. O fator que os motiva a realizar uma negociação de derivativos é a divergência de expectativas quanto ao comportamento do preço do ativo objeto num determinado tempo. Esse é o elemento de risco, o qual pode ser transferido para o mercado de derivativos. Um hedging de compra ou de venda tem o objetivo de garantir um determinado preço futuro do ativo objeto. O mercado de derivativos têm vários tipos de contratos: futuros, a termo, de opções e de swaps. A ênfase maior de trabalho deste projeto foi focalizar às modalidades operacionais dos principais instrumentos de futuros, bem como a sua estrutura organizacional no mercado brasileiro. Procuramos tratar esse assunto de forma simples e didática, tornando-o acessível àqueles pouco familiarizados com os conceitos e as modalidades operacionais existentes no mercado futuro.

Evaluation of yeast cell wall on the performance of broiles fed diets with or without mycotoxins

This experiment aimed at evaluating the effects of the interactions between aflatoxin (500 or 250 ppb) and ochratoxin (500 or 250 ppb), and the possible benefits of adding yeast cell wall to prevent the effects of these mycotoxins in broiler chickens. Relative organ weight gain and live performance were evaluated at 21 and 42 days of age. Results indicated that at the levels of mycotoxins included in the experimental diets, ochratoxin reduced feed intake and body weight gain, and aflatoxin only affect feed intake of 21-day-old birds. No interaction was observed between aflatoxin and ochratoxin at the levels used in experimental study. Yeast cell wall did not significantly reduced the deleterious effects of ochratoxins. No significant differences were observed in relative organ weight gain. Yeast cell wall improved feed conversion ratio when birds were fed either contaminated or non-contaminated feeds.

A new species of Tetragonopterus Cuvier, 1816 (Characiformes, Characidae, Tetragonopterinae) from the upper rio Araguaia, Central Brazil

A new characid, Tetragonopterus anostomus, is described from the upper rio Araguaia, Central Brazil. The new species is distinguished from its congeners (T. argenteus, T. carvalhoi, T. chalceus e T. rarus) by traits related to the position of the mouth, number of premaxillary teeth, number of predorsal scales, overall color pattern, and number of gill rakers. A brief discussion on its putative ecomorphological adaptations is provided.

Correlation among order-disorder, electronic levels, and photoluminescence in amorphous CT : Sm

Ca0.95Sm0.05TiO3 (CT:Sm) powder was prepared by the polymeric precursor method (PPM). Order-disorder at short and long range has been investigated by means of Raman spectroscopy, X-ray diffraction (XRD), and photoluminescence emission (PL) experimental techniques. The broad PL band and the Sm emission spectrum measured at room temperature indicate the increase of structural order with annealing temperature. The measured PL emission reveals that the PL intensity changes with the degree of disorder in the CT: Sm. The electronic structures were performed by the ab initio periodic method in the DFT level with the hybrid nonlocal B3LYP approximation. Theoretical results are analyzed in terms of DOS, charge densities, and Mulliken charges. Localized levels into the band gap of the CT: Sm material favor the creation of the electron-hole pair, supporting the observed room-temperature PL phenomenon.

Application of on-line C30 RP-HPLC-NMR for the analysis of flavonoids from leaf extract of Maytenus aquifolium

The application of on-line C30-reversed-phase high-pressure liquid chromatography-nuclear magnetic resonance spectroscopy is described for the analysis of tetraglycosylated flavonoids in aqueous and hydroalcoholic extracts of the leaves of Maytenus aquifolium (Celastraceae). Triacontyl stationary phases showed adequate separation for on-line 1H-NMR measurements at 600 MHz and allowed the characterisation of these flavonoids by detection of both aromatic and anomeric proton signals. Copyright (C) 2000 John Wiley and Sons, Ltd.

Full-color phosphors from amine-functionalized crosslinked hybrids lacking metal activator ions

Sol-gel derived hybrids that contain OCH2CH2 (polyethylene glycol, PEG) repeat units grafted onto a siliceous backbone by urea, -NHC(=O)NH-, or urethane, -NHC(=O)O-, bridges have been prepared. It is demonstrated that the white light PL of these materials results from an unusual convolution of a longer lived emission that originates in the NH groups of the urea/urethane bridges with shorter lived electron-hole recombinations occurring in the nanometer-sized siliceous domains. The PL efficiencies reported here (maximum quantum yields at room temperature of ≈ 0.20 ± 0.02 at a 400 nm excitation wavelength) are in the same range as those for tetramethoxysilane-formic acid, and APTES-acetic acid, sol-gel derived phosphors. The high quantum yields combined with the possibility of tuning the emission to colors across the chromaticity diagram present a wide range of potential applications for these hybrid materials.

Descomposición del coeficiente de Gini por fuentes de ingreso: evidencia empírica para América Latina 1999-2005

Incluye Bibliografía

A ação pedagógica de professores ribeirinhos da Amazônia e sua relação com a concepção freireana de educação: um estudo do Projeto Escola Açaí em Igarapé-Miri/PA

O presente estudo investigou a maneira como os professores ribeirinhos que atuam no Projeto Escola Açaí, em Igarapé-Miri/PA, realizam sua ação pedagógica, e se tais práticas estão relacionadas aos pressupostos freireanos da educação. A opção metodológica do estudo se fundamenta na pesquisa qualitativa, configurada em um estudo de caso com a aplicação de questionário, análise de documentos e entrevistas para a coleta de dados com professores ribeirinhos. No estudo, foram utilizadas produções teóricas que focalizam a prática pedagógica a partir dos ideais de Paulo Freire concomitante a outros referenciais que investigam o contexto amazônico/ribeirinho em relação aos aspectos socioeducacionais e culturais. Os resultados do estudo apontaram que a ação pedagógica realizada pelos professores da Escola Açaí está fundamentada nas concepções freireanas, de tal modo que estas ações estão próximas e adequadas à realidade ribeirinha, privilegiando os saberes, a cultura e as experiências destas populações, resgatando e afirmando os valores culturais destes sujeitos que vivem na Amazônia. Constatou-se, também, que a ação pedagógica viabiliza a inclusão socioeducacional de famílias de alunos ribeirinhos em vários projetos de empoderamento comunitário, através de elementos culturais pertinentes ao contexto ribeirinho amazônico.

Um exemplo de negação do conceito de elemento na filosofia natural

The focus of this work is to present an example of refutation of the concept of element inside the seventeenth-century scientific revolution, mainly through Robert Boyle’s The Sceptical Chymist. On the first section of this paper the notion of element as considered by the ancient Greeks in Aristotle’s Physics and modern chemists in Paracelsus will be briefly presented. After that in the second section Boyle’s deconstruction of the idea of element will be exposed considering his argumentation of why this notion is prejudicial to the study of nature. Finally, in the third section follows the constructive stage in which a new hypothesis is presented (the corpuscular hypothesis) as the best option to replace the notion of element.

História e ensino de Matemática: construção e uso de instrumentos de medida do século XVI

Entre as diversas iniciativas que procuram aproximar a História da Matemática do ensino da Matemática, o uso de fontes primárias tem sido muito promissor. Seguindo de perto esta tendência, propomos abaixo três atividades baseadas em excertos retirados de uma obra publicada no século XVI

Heats of mixing using an isothermal titration calorimeter: Associated thermal effects

[EN] The correct determination of the energy generated or absorbed in the sample cell of an Isothermal Titration Calorimeter (ITC) requires a thorough analysis of the calorimetric signal. This means the identification and quantification of any thermal effect inherent to the working method. In this work, it is carried out a review on several thermal effects, studied by us in previous work, and which appear when an ITC is used for measuring the heats of mixing of liquids in a continuous mode. These effects are due to: (i) the difference between the temperature of the injected liquid and the temperature of the mixture during the mixing process, (ii) the increase of the liquid volume located in the mixing cell and (iii) the stirring velocity. Besides, methods for the identification and quantification of the mentioned effects are suggested.