Age and isotopes in bottom sediments from Core VER-99-1-St2, Baikal Lake

A simple, reliable, and efficient method has been elaborated for direct determination of isotopic composition of authigenic uranium in siliceous lacustrine sediments. The method is based on studying kinetics of selective extraction of authigenic uranium from sediments by weak solutions of ammonium hydrocarbonate followed by ICP-MS analysis of nuclides. To estimate contamination of authigenic uranium by terrigenous one contents of 232Th and some other clastogenic elements in the extracts were measured simultaneously. Selectivity of extraction of authigenic uranium from the sediments treated with 1% NH4HCO3 solution appeared to be no worse than 99%. The method was applied to analysis of isotopic composition of authigenic uranium at several key horizons of the earlier dated core from the Baikal Lake. Measurements directly show that 234U/238U values in Baikal water varied depending on climate, which contradicts existing hypotheses. Measured 234U/238U ratios in water of the paleo-Baikal match corresponding values reconstructed from isotopic data for total uranium in the sediments on supposition that U/Th ratio is constant in terrigenous fraction of the sediments. Direct experimental determination of total and authigenic nuclides in sediments enhances potentiality of the method for 234U-230Th dating of non-carbonate lacustrine sediments including those from the Baikal Lake within intervals corresponding to periods of glaciation, when sediments were rich in terrigenous components. Portions of terrigenous and authigenic uranium are well separated and we can study variability of sources of terrigenous matter and refine the earlier model for reconstructing climate humidity in the East Siberia.

Description of lithofacies associations and their interpreted settings from sequences of sediment core CRP-1 (Table 2)

Cape Roberts Project drillcore 1 was obtained from Roberts Ridge, a sea-floor high located at 77°S, 16 km offshore from Cape Roberts in western McMurdo Sound, Antarctica. The recovered core is about 147 m long with the upper 43.15 metres below the sea floor (revised figure) being dated as Quarternary and the older part of the sequence being Miocene. The core includes nine facies: sandy diamict, muddy diamict, gravel/conglomerate, mud(stone), clay(stone) and carbonate. These facies occure in associations that are repeated in particulare sequences throughout the core, and are interpreted as representing different depositional environments through time. Seven lithofacies associations are interpreted as representing offshore shelf, ice protected/below wave-base; prodeltaic/offshore shelf; delta front/sandy shelf; ice system; subglacial till/rainout diamict/debris flow diamicts singly or in combination; and a carbonate-rich shelf bank. The facies associations are used to infer that the Quaternary section represents deposition on a polar shelf with perhaps two or three glacial fluctuations. The Quaternary carbonate unit indicates a period of ice sheet retreat, but local glacial activity may have increased with an increase in costal precipitation. The Miocene section represents polythermal glacial systems. The older Miocene section is glacially dominated whereas the younger section is much less so. The glacially dominated section may provide evidence for a major glacial advance thar resulted un a low stand of global eustatic sea level at that time. After the low stand, eustatic sea level was gradually rising during deposition of the younger section dominated more by non-glacial processes.

Organic and inorganic geochemical measurements of sediment core GeoB7702-3

It has long been known that extreme changes in North African hydroclimate occurred during the late Pleistocene yet many discrepancies exist between sites regarding the timing, duration and abruptness of events such as Heinrich Stadial (HS) 1 and the African Humid Period (AHP). The hydroclimate history of the Nile River is of particular interest due to its lengthy human occupation history yet there are presently few continuous archives from the Nile River corridor, and pre-Holocene studies are rare. Here we present new organic and inorganic geochemical records of Nile Basin hydroclimate from an eastern Mediterranean (EM) Sea sediment core spanning the past 28 ka BP. Our multi-proxy records reflect the fluctuating inputs of Blue Nile versus White Nile material to the EM Sea in response to gradual changes in local insolation and also capture abrupt hydroclimate events driven by remote climate forcings, such as HS1. We find strong evidence for extreme aridity within the Nile Basin evolving in two distinct phases during HS1, from 17.5 to 16 ka BP and from 16 to 14.5 ka BP, whereas peak wet conditions during the AHP are observed from 9 to 7 ka BP. We find that zonal movements of the Congo Air Boundary (CAB), and associated shifts in the dominant moisture source (Atlantic versus Indian Ocean moisture) to the Nile Basin, likely contributed to abrupt hydroclimate variability in northern East Africa during HS1 and the AHP as well as to non-linear behavior of hydroclimate proxies. We note that different proxies show variable gradual and abrupt responses to individual hydroclimate events, and thus might have different inherent sensitivities, which may be a factor contributing to the controversy surrounding the abruptness of past events such as the AHP. During the Late Pleistocene the Nile Basin experienced extreme hydroclimate fluctuations, which presumably impacted Paleolithic cultures residing along the Nile corridor.