Oxygen potentials and phase equilibria in the system Ca-Co-O and thermodynamic properties of Ca3Co2O6 and Ca3Co4O9.163

Oxygen potentials established by the equilibrium between three condensed phases, CaOss+CoOss+ Ca3Co2O6 and CoOss+Ca3Co2O6+Ca3CO3.93+O-alpha(9.36-delta), are measured as a function of temperature using solid-state electrochemical cells incorporating yttria-stabilized zirconia as the electrolyte and pure oxygen as the reference electrode. Cation non-stoichiometry and oxygen non-stoichiometry in Ca3Co3.93+alpha O9.36-delta are determined using different techniques under defined conditions. Decomposition temperatures and thermodynamic properties of Ca3Co2O6 and Ca3Co4O9.163 are calculated from the results. The standard entropy and enthalpy of formation of Ca3Co2O6 at 298.15 K are evaluated. Using thermodynamic data from this study and auxiliary information from the literature, phase diagram for the ternary system Ca-Co-O is computed. Isothermal sections at representative temperatures are displayed to demonstrate the evolution of phase relations with temperature. (C) 2014 Elsevier Inc. All rights reserved.

Study of structures, energies and vibrational frequencies of (O-2)(n)(+) (n=2-5) clusters by GGA and meta-GGA density functional methods

Using Generalized Gradient Approximation (GGA) and meta-GGA density functional methods, structures, binding energies and harmonic vibrational frequencies for the clusters O-4(+), O-6(+), O-8(+) and O-10(+) have been calculated. The stable structures of O-4(+), O-6(+), O-8(+) and O-10(+) have point groups D-2h, D-3h, D-4h, and D-5h optimized on the quartet, sextet, octet and dectet potential energy surfaces, respectively. Rectangular (D-2h) O-4(+) has been found to be more stable compared to trans-planar (C-2h) on the quartet potential energy surface. Cyclic structure (D-3h) of CA cluster ion has been calculated to be more stable than other structures. Binding energy (B.E.) of the cyclic O-6(+) is in good agreement with experimental measurement. The zero-point corrected B.E. of O-8(+) with D4h symmetry on the octet potential energy surface and zero-point corrected B.E. of O-10(+) with D-5h symmetry on the dectet potential energy surface are also in good agreement with experimental values. The B.E. value for O-4(+) is close to the experimental value when single point energy is calculated by Brueckner coupled-cluster method, BD(T). (C) 2014 Elsevier B.V. All rights reserved.

Timing Recovery Algorithms and Architectures for 2-D Magnetic Recording Systems

We investigate the problem of timing recovery for 2-D magnetic recording (TDMR) channels. We develop a timing error model for TDMR channel considering the phase and frequency offsets with noise. We propose a 2-D data-aided phase-locked loop (PLL) architecture for tracking variations in the position and movement of the read head in the down-track and cross-track directions and analyze the convergence of the algorithm under non-separable timing errors. We further develop a 2-D interpolation-based timing recovery scheme that works in conjunction with the 2-D PLL. We quantify the efficiency of our proposed algorithms by simulations over a 2-D magnetic recording channel with timing errors.

Contrasting Electronic Requirements for C-H Binding and C-H Activation in d(6) Half-Sandwich Complexes of Rhenium and Tungsten

A computational study of the interaction half-sandwich metal fragments (metal=Re/W, electron count=d(6)), containing linear nitrosyl (NO+), carbon monoxide (CO), trifluorophosphine (PF3), N-heterocyclic carbene (NHC) ligands with alkanes are conducted using density functional theory employing the hybrid meta-GGA functional (M06). Electron deficiency on the metal increases with the ligand in the order NHC < CO < PF3 < NO+. Electron-withdrawing ligands like NO+ lead to more stable alkane complexes than NHC, a strong electron donor. Energy decomposition analysis shows that stabilization is due to orbital interaction involving charge transfer from the alkane to the metal. Reactivity and dynamics of the alkane fragment are facilitated by electron donors on the metal. These results match most of the experimental results known for CO and PF3 complexes. The study suggests activation of alkane in metal complexes to be facile with strong donor ligands like NHC. (C) 2015 Wiley Periodicals, Inc.

Inclusión de harina de hoja de Marango (Moringa oleifera) en la alimentación de conejos de engorde y su efecto en el comportamiento productivo

El objetivo del presente trabajo fue evaluar el efecto de la inclusión de harina de Marango (Moringa oleifera) en dietas para conejos de engorde y su efecto en el comportamiento productivo. Se utilizaron 36 conejos de camadas homogéneas con 37 d de edad, de las razas Neozelandés (18) y California (18) con pesos iniciales promedio de 554 g (133.8), los cuales fueron distribuidos en igual proporción de razas y sexos, en un Diseño Completamente al Azar con tres tratamientos: Tl: Concentrado Comercial, T2: Concentrado Isométrico, T3: Concentrado lsoprotéico. Las variables estudiadas fueron: consumo de alimento diario (CAD), ganancia media diaria (GMD), índice de conversión alimenticia (!CA), digestibilidad aparente de la materia seca (DMS), peso final (PF). Se realizó análisis de varianza y comparaciones de medias con la Prueba de Tukey utilizando el paquete estadístico MINITAB~:Ver. 12.0. Los resultados indican que para el CAD no se encontró diferencia significativa (P>0.05) siendo los valores promedio de 11 1.73g d"1 respectivamente. Sin embargo, para la GMD y la DMS se encontró diferencias (Pdo un promedio de !8.63g d" 1 para la GMD y para DMS la dieta isoprotéica obtuvo el mayor valor (70.79%), así mismo para ICA y PF se observó diferencia (P<0.05) 5.541 para la T3 vs 5.964 y 7.336 para TI y T2. El peso final fue en promedio de 2247g. No se encontraron diferencias (P>0.05) para el efecto de raza y sexo. El análisis financiero favorece a la dieta isoprotéica, presentando un valor de USA$ 0.98 por encima de la dieta comercial. En conclusión la harina de Marango puede ser utilizada como sustituto parcial o total de la proteína en dietas para conejos de engorde sin causar efectos negativos en los parámetros productivos.

Les crimes des empereurs d'Allemagne, depuis Lothaire I jusqu'Ã Leopold II, avec cinq gravures

Louis Marie Prudhomm nasceu em Lyon em 1752 e morreu em Paris em 1830. Entre os anos de 1787 e 1789, morando em Paris, publicou um número incalculável de panfletos revolucionários, entre os quais destaca-se ‘Résume des cahiers de doléances des bailliages pour les deputés des trois ordres aux etats géneraux’, em 1789. Pouco antes da queda da Bastilha, publicou ‘Las Revoluciones de Paris’. Em 1799, tornou-se impressor e livreiro. Entre suas inúmeras obras se encontram ‘Les crimes des reines de France’; ‘Les crimes des rois de France’; ‘Les crimes des Papes’; ‘Les crimes des empereurs d'Allemagne’, todas publicadas em 1793; ‘Histoire impartiale des révolutions de France depuis la mort de Louis XV’, publicada entre 1824 e 1825; e ‘Repertoire universel, historique, biographique des femmes célebres’, publicada entre 1826 e 1827. De acordo com a ‘Enciclopédia Universal Ilustrada’, há dúvidas quanto à autoria da obra ‘Les crimes des empereurs d'Allemagne’ aventando-se a possibilidade de o literato e político francês, Louis de La Vicomtérie de Saint-Samson ser seu autor

A study of the intertidal sea anemones of the Monterey Bay region

This is a student paper done for a University of California Berkeley Zoology class. Since UCB didn't have its own marine lab at the time, it rented space at Hopkins Marine Station where this work was done. Cadet Hand earned his Ph.D. from Berkeley and went on to become Director of the Bodega Marine Laboratory. (PDF contains 36 pages)

Voyage dans le district des Diamans et sur le littoral du Brésil : suivi de notes sur quelques plantes caracteristiques et d'un precis de l'histoire des revolutions de l'empire bresilien, depuis le commencement du regne de Jean vi jusqu'a l'abdication de D. Pedro

As Voyages... são estudos completos, abrangendo todos os aspectos das regiões percorridas; servem de subsídio ao estudo das condições de vida no Brasil no século passado. "Fonte primordial de informações sobre os prédios coloniais do Rio de Janeiro, Minas Gerais, São Paulo, Santa Catarina e Goiás. Poucas obras no gênero atingem o valor de Saint-Hilarire. São clássicas e indispensáveis para o estudo do sul do Brasil, antes da Independência" segundo Borba de Moraes

Relatório apresentado a S. Ex. o Sr. Ministro da Industria, Viação e Obras Públicas =Rapport présenté a Son Ex. M. le Ministre de l'Industrie, de la Voirie et des Travaux Publics /por L. Cruls. --Relatório da Comissão Exploradora do Planalto Central do Brazil = Rapport de la Commission d'Exploration du Plateau Central du Brésil

Documento com duas páginas-de-rosto, em português e francês. Título em francês : Rapport présenté a Son Ex. M. le Ministre de l'Industrie, de la Voirie et des Travaux Publics

Palmerino d'Inghilterra : figliuolo del Re Don Duardo, que si contano gli fran fatti in arme che egli fece per amore della infanta Polinarda, figliuola di Primalcone, doue acquisto mortal fama, et di Floriano dal Deserto suo fratello, con alcuni gloriosi fatti del Prencipe Florendo, figliuolo di Primaleone

Nuouamente tradotto di spagnuolo in italiano

Codigo Philippino, ou, Ordenações e leis do Reino de Portugal : recopiladas por mandado d'El-Rey D. Philippe I

As Ordenações Filipinas resultaram da reforma feita por Felipe II da Espanha (Felipe I de Portugal), ao Código Manuelino, durante o período da União Ibérica. Continuou vigindo em Portugal ao final da União, por confirmação de D. João IV. Até a promulgação do primeiro Código Civil brasileiro, em 1916, estiveram também vigentes no Brasil. Blake informa que esta é a primeira edição brasileira deste código.

Brain type II calcium and calmodulin-dependent protein kinase: characterization of a brain-region specific isozyme and regulation by autophosphorylation

A variety of molecular approaches have been used to investigate the structural and enzymatic properties of rat brain type ll Ca^(2+) and calmodulin-dependent protein kinase (type ll CaM kinase). This thesis describes the isolation and biochemical characterization of a brain-region specific isozyme of the kinase and also the regulation the kinase activity by autophosphorylation.

The cerebellar isozyme of the type ll CaM kinase was purified and its biochemical properties were compared to the forebrain isozyme. The cerebellar isozyme is a large (500-kDa) multimeric enzyme composed of multiple copies of 50-kDa α subunits and 60/58-kDa β/β’ subunits. The holoenzyme contains approximately 2 α subunits and 8 β subunits. This contrasts to the forebrain isozyme, which is also composed of and β/β'subunits, but they are assembled into a holoenzyme of approximately 9 α subunits and 3 β/β ' subunits. The biochemical and enzymatic properties of the two isozymes are similar. The two isozymes differ in their association with subcellular structures. Approximately 85% of the cerebellar isozyme, but only 50% of the forebrain isozyme, remains associated with the particulate fraction after homogenization under standard conditions. Postsynaptic densities purified from forebrain contain the forebrain isozyme, and the kinase subunits make up about 16% of their total protein. Postsynaptic densities purified from cerebellum contain the cerebellar isozyme, but the kinase subunits make up only 1-2% of their total protein.

The enzymatic activity of both isozymes of the type II CaM kinase is regulated by autophosphorylation in a complex manner. The kinase is initially completely dependent on Ca^(2+)/calmodulin for phosphorylation of exogenous substrates as well as for autophosphorylation. Kinase activity becomes partially Ca^(2+) independent after autophosphorylation in the presence of Ca^(2+)/calmodulin. Phosphorylation of only a few subunits in the dodecameric holoenzyme is sufficient to cause this change, suggesting an allosteric interaction between subunits. At the same time, autophosphorylation itself becomes independent of Ca^(2+) These observations suggest that the kinase may be able to exist in at least two stable states, which differ in their requirements for Ca^(2+)/calmodulin.

The autophosphorylation sites that are involved in the regulation of kinase activity have been identified within the primary structure of the α and β subunits. We used the method of reverse phase-HPLC tryptic phosphopeptide mapping to isolate individual phosphorylation sites. The phosphopeptides were then sequenced by gas phase microsequencing. Phosphorylation of a single homologous threonine residue in the α and β subunits is correlated with the production of the Ca^(2+) -independent activity state of the kinase. In addition we have identified several sites that are phosphorylated only during autophosphorylation in the absence of Ca^(2+)/ calmodulin.

Indentification and characterization of a novel CA^(2+)-binding protein in avian erythrocytes

A novel Ca^(2+)-binding protein with Mr of 23 K (designated p23) has been identified in avian erythrocytes and thrombocytes. p23 localizes to the marginal bands (MBs), centrosomes and discrete sites around the nuclear membrane in mature avian erythrocytes. p23 appears to bind Ca^(2+) directly and its interaction with subcellular organelles seems to be modulated by intracellular [Ca^(2+)]. However, its unique protein sequence lacks any known Ca^(2+)-binding motif. Developmental analysis reveals that p23 association to its target structures occurs only at very late stages of bone marrow definitive erythropoeisis. In primitive erythroid cells, p23 distributes diffusely in the cytoplasm and lacks any distinct localization. It is postulated that p23 association to subcellular structures may be induced in part by decreased intracellular [Ca^(2+)]. In vitro and in vivo experiments indicate that p23 does not appear to act as a classical microtubule-associated protein (MAP) but p23 homologues appear to be expressed in MB-containing cells of a variety of species from different vertebrate classes. It has been hypothesized that p23 may play a regulatory role in MB stabilization in a Ca^(2+)-dependent manner.

Binucleated (bnbn) turkey erythrocytes were found to express a truncated p23 variant (designated p21) with identical subcellular localization as p23 except immunostaining reveals the presence of multi-centrosomes in bnbn cells. The p21 sequence has a 62 amino acid deletion at the C-terminus and must therefore have an additional ~40 amino acids at the N-terminus. In addition, p21 seems to have lost the ability to bind Ca^(2+) and its supramolecular interactions are not modulated by intracellular [Ca^(2+)]. These apparent differences between p23 and p21 raised the possibility that the p23/p21 allelism could be the Bn/bn genotype. However, genetic analysis suggested that p23/p21 allelism had no absolute correlation with the Bn/bn genotype.

Phytotoxicité du glyphosate sur la Jacinthe d'eau (Eichhornia crassipes, Solms)

The toxicity of the herbicide glyphosate was tested on water hyacinth (Eichhornia crassipes) samples cultivated in glass aquariums. The lowest dose (0.09 g.m-2) leads to an increasing plant growth rate. This growth rate decreases with intermediate doses (0.18 and 0.36 g.m-2), the consequence of which is to increase stolons (vegetative reproduction). On the other hand, the dose of 0.72 g.m-2 leads to a total and irreversible destruction of plants.