Microcalorimetric and IR spectroscopic studies of CO adsorption on molybdenum nitride catalysts

The adsorption of CO on both nitrided and reduced passivated Mo(2)N catalysts in either alumina supported or unsupported forms was studied by adsorption microcalorimetry and infrared (IR) spectroscopy. The CO is adsorbed on nitrided Mo(2)N catalysts on three different surface sites: 4-fold vacancies, Mo(delta+) ( 0 < delta < 2) and N sites, with differential heats of CO adsorption decreasing in the same order. The presence of the alumina-support affects the energetic distribution of the adsorption sites on the nitrided Mo(2)N, i.e. weakens the CO adsorption strength on the different sites and changes the fraction of sites adsorbing CO in a specific form, revealing that the alumina supported Mo(2)N phase shows lower electron density than pure Mo(2)N. On reduced passivated Mo(2)N catalysts the CO was found to adsorb mainly on Mo(4+) sites, although some slightly different surface Mo(delta+) d (0 < delta < 2) sites are also detected. The nature, density and distribution of surface sites of reduced passivated Mo(2)N/gAl(2)O(3) were similar to those on reduced MoO(3)/gamma-Al(2)O(3).

对改善环境的经济动力的探讨

对改善环境的经济动力的探讨李法云，范志平中科院沈阳应用生态研究所由于人口的增加、工业生产的发展，资源消耗在加快，我们正面临着环境污染蔓延和生态环境恶化这一环境问题的挑战。我国目前的环境状况不容乐观，森林面积仍在减少，水土流失面积也在增大，河流污染现状...

模拟酸雨对荔枝果园土壤磷素等温吸附与解吸特性的影响

采用等温吸附试验方法研究了模拟酸雨对荔枝果园土壤磷的吸附与解吸特性的影响。试验结果表明,不同处理间土壤对磷的最大吸附量(Xm)为pH2.5>pH4.5>CK=pH6.5,其中pH2.5的酸雨淋溶处理对磷的最大吸附量(Xm)与其它处理间差异显著;土壤吸附磷的解吸量(Xd)分别与相应的吸附量(X)和原平衡溶液浓度(C)呈显著的指数相关和线性相关,随着土壤对吸附量的增加,土壤磷的解吸量呈指数增长。

中国东北植被生态学研究中的焦点问题

中国东北植被经过半个多世纪的系统研究 ,但有关植被生态学一些争论性问题尚未统一 .本文仅就作者近年来研究工作涉及到的内容和关注的问题 ,提出一些看法 :1)中国东北植被地带性分布规律可用Kira的温暖指数 (WI)、寒冷指数 (CI)和作者的湿度指数 (HI)进行定量解释 .2 )大兴安岭北部山地 ,在海拔14 0 0m以上存在冻原植被 ,是作者于 196 3年首次发现的我国第三块冻原植被 ,其WI <15℃·月 .3)大小兴安岭植被分界线是我国植被区划中第一级分区界线 ,其位置在爱辉 -果松沟 -嫩江以南附近 ,WI为 4 5℃·月 .4 )大兴安岭植被地带性分异显著 ,南段、中段为典型草原地带和森林草原地带 ,北段为针叶林地带 ,HI值分别为 3 5～ 5 5、5 5～ 7 5、>7 5mm/℃·月 .大兴安岭东麓阔叶林是森林草原带上的森林植被类型 .5 )东北东部山地岳桦林是山地植被垂直带谱重要组成部分之一 ,是山地森林垂直分布林线 ,WI为 2 0～ 15℃·月为地带性植被类型 ,而WI>2 0℃·月为非地带性植被类型 .6 )内蒙古浑善达克沙地云杉林是陆地上非常罕见的森林生态系统类型 ,但这种云杉林究竟是哪一树种组成 ,在中国植物分类上一直是个争论性问题 ,作者通过核型分析和同工酶实验进一步证明是一个新种即沙地云杉Piceamongolica(H .Q .Wu)W .D .

Preparation and characterization of a novel solid solution of aluminum in tungsten carbide by mechanically activated high-temperature reaction

In this work, a novel substitutional solid solution (W0.8Al0.2)C was synthesized by mechanically activated high-temperature reaction. X-ray diffraction was used for phase identification during the whole reaction process. Environment scanning electronic microscopy-field emission gun and energy dispersive x-ray were used to investigate the microstructure and the quantitative material composition of the specimen. (W(0.8)A(10.2))C was found to crystallize in the WC-type, and the cell parameters were a = 2.907(1) angstrom and c = 2.837(1) angstrom. The hardness of (W0.8Al0.2)C was tested to be 19.3 +/- 1 GPa, and the density was 13.19 +/- 0.05 g cm(-3).

Anderson-Grneisen参数、热膨胀系数与压强的普遍关系

本文首先从理论上导出A derson-Gruneisen参数与体积弹性模量对压强的一阶导数之间及体积弹性模量与压强之间的普遍关系。然后在此基础上进一步导出Anderson-Gruneisen参数、热膨胀系数与压强之间的普遍关系。

Improving Ship Detection with Polarimetric SAR based on Convolution between Co-polarization Channels

The convolution between co-polarization amplitude only data is studied to improve ship detection performance. The different statistical behaviors of ships and surrounding ocean are characterized a by two-dimensional convolution function (2D-CF) between different polarization channels. The convolution value of the ocean decreases relative to initial data, while that of ships increases. Therefore the contrast of ships to ocean is increased. The opposite variation trend of ocean and ships can distinguish the high intensity ocean clutter from ships' signatures. The new criterion can generally avoid mistaken detection by a constant false alarm rate detector. Our new ship detector is compared with other polarimetric approaches, and the results confirm the robustness of the proposed method.

甘肃棘豆属一新变种

Oxytropis xinglongshanica C. W. Chang var. obesusi-corollata Y. H. Wu, var. nov. A var. xinglongshanica recedit corollis obesis, vexillis c. 15 mm longis, c. 10 mm latis, limbis late ovatis, unguibus c. 6 mm longis; alis c. 14 mm longis, c. 4.5 mm latis, limbis anguste obovatis.

一种基于工艺特征的制造单元划分方法

在现代生产中,单元化生产是提高制造系统生产效率的一个重要手段。对于一个给定的制造系统,其中制造单元的划分并不是唯一的,人们提出了各种制造单元划分方法。这些方法的不足是只采用0和1两值来表示系统中的相似关系。本文提出了相似系数和隶属度的概念,进一步发展了一种完善的制造单元划分方法,最后以一个数值例子进行了验证。

高温实验中重金属钼在硅酸盐熔体中的含量研究

This dissertation discusses current status of high temperature and high pressure and focuses on analyzing systematically the solubility of heavy metals in the silicate magma in HTHP experiments. The high temperature study on the content of heavy metal molybdenum in the silicate melts in this dissertation, which is granted, based on the geology mineralization model and the theory of HTHP experiments and combined with mineralization grade and geochemical nature of Mo, discusses the difference of mineralization between mantle plume and aqueous fluids and comes to the conclusions, which are as follows: (1) The content of Mo in the silicate melts is much greater than Mo mineralization grade. The molybdenum ore has the exploitation value when the industrial grade is higher than 0.06%. Mo content in different silicate melts varies because of the concentration of SiO2, that is, Mo content in the granodiorite is greater. (2) The content of Mo, which varies with reaction time, arises first and drops down in the alkali basalt melts, while variation is not too obvious in the granodiorite melts on the whole. (3) According to the picture of sample, the conclusion is not reached very well on some issues, such as the volatility and characteristic of molybdenum oxide and dependence on the geology environment.

中东亚地区土地退化早期阶段关键营养元素C、N的差异流失作用

土地退化是导致土地生产力下降的过程之一,也是造成土地资源日益减少的主要原因.在气候变化的大背景下,人类对土地资源的过度利用正使得土地退化成为世界性难题.

Exercise training can induce cardiac autophagy at end-stage chronic conditions: Insights from a graft-versus-host-disease mouse model

Chronic graft-versus-host disease (cGVHD) is a frequent cause of morbimortality after allogeneic hematopoietic stem cell transplantation (allo-HSCT), and severely compromises patients' physical capacity. Despite the aggressive nature of the disease, aerobic exercise training can positively impact survival as well as clinical and functional parameters. We analyzed potential mechanisms underlying the recently reported cardiac function improvement in an exercise-trained cGVHD murine model receiving lethal total body irradiation and immunosuppressant treatment (Fiuza-Luces et al., 2013. Med Sci Sports Exerc 45, 1703-1711). We hypothesized that a cellular quality-control mechanism that is receiving growing attention in biomedicine, autophagy, was involved in such improvement. Our results suggest that exercise training elicits a positive autophagic adaptation in the myocardium that may help preserve cardiac function even at the end-stage of a devastating disease like cGVHD. These preliminary findings might provide new insights into the cardiac exercise benefits in chronic/debilitating conditions.

Letter: To Ebenezer Blackwell from John Wesley, July 3, 1751

Digitized from a letter in the Drew University Methodist Collection. 1 item (4 p.); 19.5 x 32 cm.